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Effects of Sunlight on the Trichloronitromethane Formation Potential of Wastewater Effluents: Dependence on Nitrite Concentration.

Jiale Xu,Zachary T. Kralles,Ning Dai

Published 2019 in Environmental Science and Technology

ABSTRACT

This study examined the effects of sunlight irradiation on the trichloronitromethane formation potential (TCNM-FP) of wastewater effluents and the roles of nitrite and nitrate in this process. Using disinfected secondary effluents from four treatment plants, we observed that sunlight irradiation (320 W/m2) for 8 h attenuated the TCNM-FP by 17-47% for 9 of 14 samples but increased the TCNM-FP for two of the other samples. A longer irradiation time (≤36 h) further reduced the TCNM-FP in a non-nitrified effluent with low nitrite and nitrate concentrations but increased the TCNM-FP in two nitrified effluents by 2-3-fold. When nitrite (0.1-2 mg N/L) was spiked into effluent samples, an increase in the TCNM-FP after irradiation was observed. The higher the nitrite concentration, the greater the increase in the TCNM-FP. In the presence of ∼1 mg N/L of nitrite, sunlight irradiation for 8 h increased the TCNM-FP of four wastewater samples by 0.3-3.6 μg/mg C. In contrast, the spike of nitrate up to 20 mg N/L had no effect. The nitrite-sunlight effect was also observed for four model precursors (humic acid, tryptophan, tyrosine, and phenol). Humic acid and tryptophan featured larger increases in the TCNM-FP compared to those of tyrosine and phenol after sunlight irradiation.

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