Desorption Kinetics of Carbon Dioxide from a Graphene-Covered Pt(111) Surface.

The interaction of carbon dioxide (CO2) with a graphene-covered Pt(111) surface was investigated using temperature-programmed desorption (TPD) and reflection absorption infrared spectroscopy (RAIRS). The TPD spectra show monolayer and multilayer desorption peaks; however, the multilayer peak is not well-separated from the monolayer peak. The TPD spectra for submonolayer and multilayer coverages align on separate common leading edges. This alignment is a signature of zero-order desorption kinetics. The RAIRS spectra for submonolayer coverages have a relatively sharp peak at ∼2350 cm-1, which is assigned to the ν3 asymmetric stretch. The peak is observed at the onset of CO2 adsorption, and the area of the peak increases linearly with coverage. This suggests that CO2 does not lie flat on the surface but instead has a component of its bond axis perpendicular to the graphene surface.

• Publication year

  2019

• Venue

  Journal of Physical Chemistry A

• Publication date

  2019-03-26

• Fields of study

  Medicine, Materials Science, Chemistry

• Identifiers
  DOI 10.1021/acs.jpca.9b00674PMID 30913386
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Desorption of Benzene, 1,3,5-Trifluorobenzene, and Hexafluorobenzene from a Graphene Surface: The Effect of Lateral Interactions on the Desorption Kinetics.

  2018cited by this paper
• Adsorption of H 2 O, H 2 , O 2 , CO, NO, and CO 2 on graphene/g-C 3 N 4 nanocomposite investigated by density functional theory

  2018cited by this paper
• Enhanced CO 2 capture on graphene via N, S dual-doping

  2017cited by this paper
• Adsorption of CO2 on Graphene: A Combined TPD, XPS, and vdW-DF Study

  2017cited by this paper
• Desorption Kinetics of Benzene and Cyclohexane from a Graphene Surface.

  2017cited by this paper
• Ab-initio investigation of adsorption of CO and CO 2 molecules on graphene: Role of intrinsic defects on gas sensing

  2017cited by this paper
• Adsorption Kinetics and Dynamics of CO2 on Ru(0001) Supported Graphene Oxide

  2016cited by this paper
• Graphene-based porous materials with tunable surface area and CO2 adsorption properties synthesized by fluorine displacement reaction with various diamines.

  2016cited by this paper
• Desorption Kinetics of Ar, Kr, Xe, N2, O2, CO, Methane, Ethane, and Propane from Graphene and Amorphous Solid Water Surfaces.

  2016cited by this paper
• A multi-technique study of CO2 adsorption on Fe3O4 magnetite.

  2016cited by this paper
• Multiscale textured, ultralight graphene monoliths for enhanced CO2 and SO2 adsorption capacity

  2016cited by this paper
• Density functional study of Al-doped graphene nanostructure towards adsorption of CO, CO2 and H2O

  2015cited by this paper
• Graphene-Based Photocatalysts for CO2 Reduction to Solar Fuel.

  2015cited by this paper
• Adsorption, Desorption, and Displacement Kinetics of H2O and CO2 on Forsterite, Mg2SiO4(011)

  2014cited by this paper
• Surface chemistry of CO2 – Adsorption of carbon dioxide on clean surfaces at ultrahigh vacuum

  2014cited by this paper
• Desorption kinetics of methanol, ethanol, and water from graphene.

  2014cited by this paper
• Adsorption, desorption, and displacement kinetics of H2O and CO2 on TiO2(110).

  2014cited by this paper
• Highly resolved infrared spectra of pure CO 2 ice (15-75 K)

  2013cited by this paper
• Crystallization of CO2 ice and the absence of amorphous CO2 ice in space

  2013cited by this paper
• Surface Science Studies of Carbon Dioxide Chemistry

  2013cited by this paper
• Theoretical Investigation of CO 2 Adsorption on Graphene

  2013cited by this paper
• Structure and dynamics of CO2 on rutile TiO2(110)- 1×1

  2012cited by this paper
• CO2 adsorption on carbon models of organic constituents of gas shale and coal.

  2011cited by this paper
• Carbon dioxide adsorption in graphene sheets

  2011cited by this paper
• Study of polycyclic aromatic hydrocarbons adsorbed on graphene using density functional theory with empirical dispersion correction.

  2010cited by this paper
• First-principles study on the structural and electronic properties of graphene upon benzene and naphthalene adsorption

  2010cited by this paper
• Adsorption of Aromatic and Anti-Aromatic Systems on Graphene through π−π Stacking

  2010cited by this paper
• Surface science perspective of carbon dioxide chemistry—Adsorption kinetics and dynamics of CO2 on selected model surfaces

  2009cited by this paper
• Adsorption and reactivity of CO(2) on defective graphene sheets.

  2009cited by this paper
• No confinement needed: observation of a metastable hydrophobic wetting two-layer ice on graphene.

  2009cited by this paper
• The effect of the incident collision energy on the porosity of vapor-deposited amorphous solid water films.

  2009cited by this paper
• Adsorption, desorption, and diffusion of nitrogen in a model nanoporous material. I. Surface limited desorption kinetics in amorphous solid water.

  2007cited by this paper
• Molecules, ices and astronomy

  2007cited by this paper
• Dipole active vibrations and dipole moments of N2 and O2 physisorbed on a metal surface.

  2006cited by this paper
• Quantum chemical prediction of reaction pathways and rate constants for dissociative adsorption of CO(x) and NO(x) on the graphite (0001) surface.

  2006cited by this paper
• Thermal desorption of gases and solvents from graphite and carbon nanotube surfaces

  2006cited by this paper
• Application of van der Waals density functional to an extended system: adsorption of benzene and naphthalene on graphite.

  2006cited by this paper
• Infrared spectroscopy of physisorbed and chemisorbed O2 on Pt(111).

  2004cited by this paper
• Adsorption, desorption, and clustering of H2O on Pt111.

  2004cited by this paper
• Temperature independent physisorption kinetics and adsorbate layer compression for Ar adsorbed on Pt(111)

  2003cited by this paper
• Techniques for attainment, control, and calibration of cryogenic temperatures at small single‐crystal samples under ultrahigh vacuum

  1993cited by this paper
• Bonding, structure, and magnetism of physisorbed and chemisorbed O2 on Pt(111).

  1990cited by this paper
• Time‐resolved electron energy loss spectroscopy study of water desorption from Ag(011)

  1989cited by this paper
• Reflection Absorption Infrared Spectroscopy

  1987cited by this paper
• Coordination of acetonitrile (CH3CN) to platinum (111): Evidence for an η2(C, N) species

  1983cited by this paper
• Sublimation rates and vapor pressures of water, carbon dioxide, nitrous oxide, and xenon

  1974cited by this paper

• Interaction strength of carbon dioxide on graphene from periodic quantum diffusion Monte Carlo.

  2025cites this paper
• Two-Dimensional Confinement Effects on the Dynamical Aspects of CO Oxidation over Pt(111)

  2025cites this paper
• Energy-Dependent Sticking Probabilities of Carbon Dioxide Isotopologues under Non-Equilibrium Gas-Surface Collision Conditions

  2025cites this paper
• Selective Adsorption of CO2 over N2 on Graphene: Insights from First-Principles Calculations

  2025cites this paper
• Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics

  2024cites this paper
• CO2 on Graphene: Benchmarking Computational Approaches to Noncovalent Interactions

  2023cites this paper
• Insights into Acetic Acid Binding and Ketene Formation on Anatase TiO_2(101)

  2023cites this paper
• Desorption of N2, CO, CH4, and CO2 from interstellar carbonaceous dust analogues

  2019cites this paper
• Exploring structure dependencies of gas-surface interactions with curved single crystals

  year unknowncites this paper
• Assessing in Silico Models and Methods for Non-Covalent Interactions between Graphene and Small Molecules

  year unknowncites this paper