Light-Driven Molecular Dynamics in Perylenes with Medium-Controlled Emission.

Highly fluorescent light emitters with medium-tunable clear colors were obtained from the skeleton of perylenedicarboximide by the attachment of donor-substituted aryl groups at the peri-position. The 4-methoxynaphthyl derivative 3a is preferred because of its strong solvatochromism in fluorescence where a mechanism of incomplete PLICT is made responsible both for the large Stokes' shift and the strong medium influence on fluorescence, allowing the fine tuning of color.

• Publication year

  2019

• Venue

  Journal of Organic Chemistry

• Publication date

  2019-03-29

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1021/acs.joc.9b00409PMID 30924342
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

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