Nanoparticle Charge in Fluid from Atomic Force Microscopy Forces within the Nonlinear Poisson-Boltzmann Equation

F. Zypman

Published 2018 in Journal of Applied Mathematics and Physics

ABSTRACT

We consider the problem of measuring the electric charge of nanoparticles immersed in a fluid electrolyte. We develop a mathematical framework based on the solution of the nonlinear Poisson-Boltzmann equation to obtain interaction forces between nanoparticles immersed in a fluid electrolyte and an Atomic Force Microscopy micro spherical probe. This force-separation information is shown explicitly to depend on the charge of the nanoparticle.  This method overcomes the statistical nature of extant methods and renders a charge value for an individual single nanoparticle.

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