The E' center is a paradigmatic radiation-induced defect in SiO2 whose peculiar EPR and hyperfine activity has been known for over 40 years. This center has been traditionally identified with a distorted, positively charged oxygen vacancy V(+)O. However, no direct proof of the stability of this defect has ever been provided, so that its identification is still largely incomplete. Here we prove directly that distorted V(+)O is metastable and that it satisfies the key requirements for its identification as E', such as thermal and optical response, and activation-deactivation mechanisms.
Proof of the thermodynamical stability of the E' center in SiO2.
C. M. Carbonaro,Vincenzo Fiorentini,Fabio Bernardini
Published 2000 in Physical Review Letters
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- Publication year
2000
- Venue
Physical Review Letters
- Publication date
2000-09-29
- Fields of study
Materials Science, Physics, Chemistry, Medicine
- Identifiers
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- Source metadata
Semantic Scholar, PubMed
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