Determining alpha-tocopherol distributions between the oil, water, and interfacial regions of macroemulsions: novel applications of electroanalytical chemistry and the pseudophase kinetic model.

No abstract is available for this paper.

• Publication year

  2006

• Venue

  Advances in Colloid and Interface Science

• Publication date

  2006-11-16

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1016/J.CIS.2006.05.007PMID 16859624
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Diffusion of alpha-tocopherol in membrane models: probing the kinetics of vitamin E antioxidant action by fluorescence in real time.

  2004cited by this paper
• Use of natural aroma compounds to improve shelf-life and safety of minimally processed fruits

  2004cited by this paper
• Determining partition constants of polar organic molecules between the oil/interfacial and water/interfacial regions in emulsions: a combined electrochemical and spectrometric method.

  2004cited by this paper
• Polarographic Detection of Arenediazonium Ions. Optimization of the Method and Application for Investigating Dediazoniation Mechanisms

  2003cited by this paper
• Effects of Sodium Dodecyl Sulfate, SDS, Micelles on the Electrochemical Behavior of a Model Arenediazonium Ion. 2. Estimation of the Association Constant of the Electrochemically Generated Aryl Radicals with SDS Micelles

  2002cited by this paper
• Kinetic method for determining antioxidant distributions in model food emulsions: distribution constants of t-butylhydroquinone in mixtures of octane, water, and a nonionic emulsifier.

  2002cited by this paper
• Electrochemical monitoring of the thermal decomposition of arenediazonium ions with time in acidic MeOH/H2O mixtures: dediazotization rate constant

  2001cited by this paper
• Effects of Ascorbic Acid on Arenediazonium Salts Reactivity: Kinetics and Mechanism of the Reaction

  2001cited by this paper
• Reactions And Synthesis In Surfactant Systems

  2001cited by this paper
• Arenediazonium Salts: New Probes of the Compositions of Association Colloids. 7. Average Hydration Numbers and Cl- Concentrations in the Surfactant Film of Nonionic C12E5/Octane/Water Macroemulsions: Temperature and NaCl Concentration Effects†

  2000cited by this paper
• The problems of using one-dimensional methods to evaluate multifunctional food and biological antioxidants

  2000cited by this paper
• The influence of various emulsifiers on the partitioning and antioxidant activity of hydroxybenzoic acids and their derivatives in oil-in-water emulsions

  2000cited by this paper
• Lipid Oxidation in Oil‐in‐Water Emulsions: Impact of Molecular Environment on Chemical Reactions in Heterogeneous Food Systems

  2000cited by this paper
• Antioxidant activity and partitioning of phenolic acids in bulk and emulsified methyl linoleate.

  1999cited by this paper
• PARTITIONING OF LOW MOLECULAR WEIGHT COMPOUNDS IN OIL-IN-WATER EMULSIONS

  1999cited by this paper
• Partitioning of selected antioxidants in mayonnaise.

  1999cited by this paper
• Partition of selected antioxidants in corn oil-water model systems

  1997cited by this paper
• The Chemistry of Double-Bonded Functional Groups

  1997cited by this paper
• Micellar catalysis, a useful misnomer

  1997cited by this paper
• Antioxidants in lipid foods and their impact on food quality

  1996cited by this paper
• Effect of pH on Antioxidant Activity of α-Tocopherol and Trolox in Oil-in-Water Emulsions

  1996cited by this paper
• Lipid oxidation in food emulsions

  1996cited by this paper
• Micellar solutions as reaction media

  1996cited by this paper
• Diazo Chemistry I. Aromatic and Heteroaromatic Compounds

  1995cited by this paper
• The characterization of antioxidants.

  1995cited by this paper
• Arenediazonium salts: new probes of the interfacial compositions of association colloids. 1. Basic approach, methods, and illustrative applications

  1993cited by this paper
• Electrochemistry in Colloids and Dispersions

  1992cited by this paper
• Application of the pseudophase ion-exchange model to kinetics in microemulsions of anionic detergents

  1990cited by this paper
• Partitioning of para-phenylenediamines in oil-in-water emulsions☆

  1987cited by this paper
• In situ voltammetric determinations of solute distribution coefficients in emulsions

  1986cited by this paper
• Interactions of neutral molecules with ionic micelles.

  1986cited by this paper
• Alkyl nitrite-metal halide deamination reactions. 6. Direct synthesis of arenediazonium tetrafluoroborate salts from aromatic amines, tert-butyl nitrite, and boron trifluoride etherate in anhydrous media

  1979cited by this paper

• Mixed surfactants as emulsifiers for interfacial modification of o/w emulsions: A case study of TBHQ partitioning and oxidative stability of castor oil using interfacial chemical kinetic method

  2025cites this paper
• Synergystic effects of binary mixtures of δ-tocopherol and gallic acid derivatives on peroxidation of soybean oil-in-water emulsions

  2024cites this paper
• Efficiency of δ-Tocopherol in Inhibiting Lipid Oxidation in Emulsions: Effects of Surfactant Charge and of Surfactant Concentration

  2023cites this paper
• Underlying mechanisms of synergistic antioxidant interactions during lipid oxidation

  2023cites this paper
• Advances in the control of lipid peroxidation in oil-in-water emulsions: kinetic approaches†

  2022cites this paper
• Control of Lipid Oxidation in Oil-in Water Emulsions: Effects of Antioxidant Partitioning and Surfactant Concentration

  2022cites this paper
• Determining Antioxidant Distributions in Intact Emulsions by Kinetic Methods: Application of Pseudophase Models

  2022cites this paper
• Effects of Surfactant Volume Fraction on the Antioxidant Efficiency and on The Interfacial Concentrations of Octyl and Tetradecyl p-Coumarates in Corn Oil-in-Water Emulsions

  2021cites this paper
• pH Changes in the Micelle–Water Interface of Surface-Active Ionic Liquids Dictate the Stability of Encapsulated Curcumin: An Insight Through a Unique Interfacial Reaction between Arenediazonium Ions and t-Butyl Hydroquinone

  2021cites this paper
• Effects of the Reactive Moiety of Phenolipids on Their Antioxidant Efficiency in Model Emulsified Systems

  2021cites this paper
• Modeling Chemical Reactivity at the Interfaces of Emulsions: Effects of Partitioning and Temperature

  2021cites this paper
• Concentration of resveratrol at the oil–water interface of corn oil-in-water emulsions

  2019cites this paper
• Mapping the location of DATEM in multi-phase systems: Synthesis and characterization of spin-label probe analogues.

  2019cites this paper
• Enhancement of the antioxidant efficiency of gallic acid derivatives in intact fish oil-in-water emulsions through optimization of their interfacial concentrations.

  2018cites this paper
• α-Tocopherol/AOT/alkane/water system

  2018cites this paper
• Effect of α-tocopherol on the properties of microemulsions stabilized by the ionic surfactants

  2017cites this paper
• Kinetic evidence for the formation of diazo ethers in the course of reactions between arenediazonium ions and antioxidants

  2017cites this paper
• A novel combined chemical kinetic and trapping method for probing the relationships between chemical reactivity and interfacial H2O, Br- and H+ ion molarities in CTAB/C12E6 mixed micelles.

  2017cites this paper
• Food-grade micro-encapsulation systems that may induce satiety via delayed lipolysis: A review

  2017cites this paper
• Chemical Kinetic and Chemical Trapping methods: Unique approaches for determining respectively the antioxidant distributions and interfacial molarities of water, counter-anions, and other weakly basic nucleophiles in association colloids

  2017cites this paper
• Kinetics and mechanism of the reaction between 3-methylbenzenediazonium ions and catechol†

  2016cites this paper
• Physicochemical properties and oxidative stability of fish oil nanoemulsions as affected by hydrophilic lipophilic balance, surfactant to oil ratio and storage temperature

  2016cites this paper
• Ionic Liquids in the Synthesis of Antioxidant Targeted Compounds

  2016cites this paper
• Partitioning of vanillic acid in oil-in-water emulsions: Impact of the Tween®40 emulsifier.

  2016cites this paper
• Amadori products formation in emulsified systems.

  2016cites this paper
• Interfacial kinetics in octane based emulsions. Effects of surfactant concentration on the reaction between 16-ArN2+ and octyl and lauryl gallates

  2015cites this paper
• Effect of lipophilization on the distribution and reactivity of ingredients in emulsions.

  2015cites this paper
• To Model Chemical Reactivity in Heterogeneous Emulsions, Think Homogeneous Microemulsions.

  2015cites this paper
• Distributions of phenolic acid antioxidants between the interfacial and aqueous regions of corn oil emulsions: Effects of pH and emulsifier concentration

  2015cites this paper
• Distributions and reactivities of phenolic antioxidants in various aggregation systems

  2015cites this paper
• Transfer of antioxidants at the interfaces of model food emulsions: distributions and thermodynamic parameters.

  2015cites this paper
• Influence of Temperature on the Distribution of Catechin in Corn Oil-in-Water Emulsions and Some Relevant Thermodynamic Parameters

  2014cites this paper
• Physical Approaches to Masking Bitter Taste: Lessons from Food and Pharmaceuticals

  2014cites this paper
• Lipid Oxidation in Oil‐in‐Water Emulsions: Involvement of the Interfacial Layer

  2014cites this paper
• Nano- and microencapsulation of vitamins

  2014cites this paper
• Distribution of catechol in emulsions

  2014cites this paper
• Distribution and Antioxidant Efficiency of Resveratrol in Stripped Corn Oil Emulsions

  2014cites this paper
• Influence of pH, metal chelator, free radical scavenger and interfacial characteristics on the oxidative stability of β-carotene in conjugated whey protein-pectin stabilised emulsion.

  2013cites this paper
• Effects of emulsifier hydrophile-lipophile balance and emulsifier concentration on the distributions of gallic acid, propyl gallate, and α-tocopherol in corn oil emulsions.

  2013cites this paper
• Modeling chemical reactivity in emulsions

  2013cites this paper
• Maxima in antioxidant distributions and efficiencies with increasing hydrophobicity of gallic acid and its alkyl esters. The pseudophase model interpretation of the "cutoff effect".

  2013cites this paper
• Effects of Acidity, Temperature and Emulsifier Concentration on the Distribution of Caffeic Acid in Stripped Corn and Olive Oil-in-Water Emulsions

  2013cites this paper
• Distribution of hydroxytyrosol and hydroxytyrosol acetate in olive oil emulsions and their antioxidant efficiency.

  2012cites this paper
• Strategies to Improve the Performance of Antioxidants in Oil-in-Water Emulsions

  2012cites this paper
• Temperature and emulsifier concentration effects on gallic acid distribution in a model food emulsion.

  2012cites this paper
• Effects of acidity and emulsifier concentration on the distribution of vitamin C in a model food emulsion

  2012cites this paper
• Micellar and Solvent Effects on Electrochemical Behaviour of Antioxidants

  2011cites this paper
• Distribution of Tert-Butylhydroquinone in a Corn Oil/C12E6/Water Based Emulsion. Application of the Pseudophase Kinetic Model

  2011cites this paper
• Mechanisms of lipid oxidation in food dispersions

  2011cites this paper
• Effects of Free Fatty Acids, Mono- and Diacylglycerols on Oxidative Stability of Soybean Oil-In-Water Emulsions

  2011cites this paper
• Lipid oxidation in emulsified food products.

  2010cites this paper
• Effects of temperature and emulsifier concentration on alpha-tocopherol distribution in a stirred, fluid, emulsion. Thermodynamics of alpha-tocopherol transfer between the oil and interfacial regions.

  2009cites this paper
• Reactivity of 3-Methylbenzenediazonium Ions with Gallic Acid. Kinetics and Mechanism of the Reaction

  2009cites this paper
• Quantitative determination of alpha-tocopherol distribution in a tributyrin/Brij 30/water model food emulsion.

  2008cites this paper
• Calorimetric study of the alpha-tocopherol solubility in reversed AOT micelles.

  2008cites this paper
• Dediazoniation of 1‐naphthalenediazonium tetrafluoroborate in aqueous acid and in micellar solutions

  2008cites this paper
• Kinetics and Mechanism of the Reaction between an Arenediazonium Ion and Methyl Gallate (=Methyl 3,4,5-Trihydroxybenzoate) in Aqueous Solution: Evidence for Diazo Ether Formation through an O-Coupling Reaction

  2007cites this paper
• Kinetics and mechanism of the reaction of an arenediazonium ion with hydrophilic aminocarboxylic acids in aqueous buffered solution

  2007cites this paper