Slow Magnetic Relaxation in Unprecedented Mono-Dimensional Coordination Polymer of Ytterbium Involving Tetrathiafulvalene-Dicarboxylate Linker

Anjara Belio Castro,Julie Jung,S. Golhen,B. L. Guennic,L. Ouahab,O. Cador,Fabrice Pointillart

Published 2016 in Magnetochemistry

ABSTRACT

A one-dimensional compound has been constructed through a YbIII ion and bridging redox-active deprotonated 4,5-bis(carboxylic)-4′,5′-methyldithiotetrathiafulvene. This polymer displays slow magnetic relaxation due to the planar magnetic anisotropy of the YbIII, which has been experimentally determined.

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