The complex kinetics of the ice VI to ice XV hydrogen ordering phase transition

Abstract The reversible phase transition from hydrochloric-acid-doped ice VI to its hydrogen-ordered counterpart ice XV is followed using differential scanning calorimetry. Upon cooling at ambient pressure fast hydrogen ordering is observed at first followed by a slower process which manifests as a tail to the initial sharp exotherm. The residual hydrogen disorder in H2O and D2O ice XV is determined as a function of the cooling rate. We conclude that it will be difficult to obtain fully hydrogen-ordered ice XV by cooling at ambient pressure. Our new experimental findings are discussed in the context of recent computational work on ice XV.

• Publication year

  2015

• Venue

  Chemical Physics Letters

• Publication date

  2015-07-09

• Fields of study

  Physics, Materials Science, Chemistry

• Identifiers
  DOI 10.1016/j.cplett.2015.07.064arXiv 1507.02665
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

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