THE ASYMMETRIC PAUSON-KHAND REACTION. A REVIEW

No abstract is available for this paper.

• Publication year

  1998

• Venue

  Organic Preparations and Procedures International

• Publication date

  1998-04-01

• Fields of study

  Chemistry

• Identifiers
  DOI 10.1080/00304949809355274
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Chiral auxiliary-induced stereocontrol in intramolecular Pauson-Khand reactions leading to angular triquinanes

  1996cited by this paper
• Solid phase synthesis of azabicyclo[4.3.0]nonen-8-one amino acid derivatives via intramolecular Pauson-Khand cyclization

  1996cited by this paper
• PALLADIUM-COBALT-MEDIATED DOUBLE ANNULATION PROCESS : A NEW STRATEGY TO CHIRAL AND POLYSUBSTITUTED BIS-CYCLOPENTANOIDS ON CARBOHYDRATE PRECURSORS

  1996cited by this paper
• Synthesis of cyclopentenones: The new catalytic cocyclization reaction of alkyne, alkene, and carbon monoxide employing catalytic Co(acac)2 and NaBH4

  1996cited by this paper
• Asymmetric Approach to (+)-β-Cuparenone by Intramolecular Pauson−Khand Reaction

  1996cited by this paper
• Synthesis of fused tricyclic β-lactams by the Pauson-Khand cyclization of enyne-2-azetidinones

  1996cited by this paper
• Development of modified Pauson-Khand reactions with ethylene and utilisation in the total synthesis of (+)-taylorione

  1996cited by this paper
• Photochemical Promotion of the Intramolecular Pauson−Khand Reaction. A New Experimental Protocol for Cobalt-Catalyzed [2 + 2 + 1] Cycloadditions

  1996cited by this paper
• Highly Enantioselective Catalytic Pauson−Khand Type Formation of Bicyclic Cyclopentenones

  1996cited by this paper
• Asymmetric Pauson-Khand Reaction. Cobalt-Mediated Cycloisomerization of 1,6-Enynes in Carbohydrate Templates: Synthesis of Bis-Heteroannulated Pyranosides.

  1996cited by this paper
• Pauson-Khand reaction with allenic compounds I: Synthesis of 4-alkylidene-2-cyclopentenones

  1995cited by this paper
• Stereoselective Pauson-Khand Reactions via the Chiral [(alkyne)Co2(CO)5{P(OMe)3}]

  1995cited by this paper
• Asymmetric Pauson-Khand Cyclization: A Formal Total Synthesis of Natural Brefeldin A

  1995cited by this paper
• 7.2 – Transition Metal Alkyne Complexes: Pauson–Khand Reaction

  1995cited by this paper
• Highly Efficient Enantioselective Pauson-Khand Reactions

  1995cited by this paper
• Comprehensive Organometallic Chemistry II

  1995cited by this paper
• A qualitative molecular mechanics approach to the stereoselectivity of intramolecular Pauson-Khand reactions

  1995cited by this paper
• A highly diastereoselective construction of optically active bicyclo[3.3.0]octenone derivatives from L-ascorbic acid via Pauson-Khand reaction

  1995cited by this paper
• A new allenic Pauson-Khand cycloaddition for the preparation of α-methylene cyclopentenones

  1995cited by this paper
• CATALYTIC VERSION OF THE INTRAMOLECULAR PAUSON-KHAND REACTION

  1994cited by this paper
• Synthesis of polyfunctionalized bis-annulated pyranosides: Useful intermediates for triquinane synthesis

  1994cited by this paper
• Practical asymmetric version of the intermolecular pauson-khand reaction

  1994cited by this paper
• Synthesis and characterisation of hexacarbonyldicobalt complexes derived from 2-propynyl and 3-butynyl 4,6-di-O-acetyl-2,3-dideoxy-α-d-erythro-hex-2-enopyranosides

  1994cited by this paper
• The pauson-khand reaction on carbohydrate templates.I. Synthesis of bis-heteroannulated-pyranosides

  1994cited by this paper
• First example of reversal of normal stereoselectivity in the intramolecular Pauson-Khand reaction

  1994cited by this paper
• Asymmetric synthesis of bicyclo[4.3.0]nonan-8-ones by intramolecular Pauson-Khand reaction

  1994cited by this paper
• A Dual-Function, Highly Efficient Chiral Controller for Stereoselective Intermolecular Pauson-Khand Reactions

  1994cited by this paper
• A Total Synthesis of (-)-.alpha.-Kainic Acid Involving a Pauson-Khand Reaction as the Key Step

  1994cited by this paper
• Promoters for the (alkyne) hexacarbonyldicobalt-based cyclopentenone synthesis

  1993cited by this paper
• A [W(CO)5·THF]-Mediated Pauson-Khand Reaction: Cyclizations of 1,6-Enynes via a Batch-Catalytic Protocol

  1993cited by this paper
• Synthesis of N-BOC-3-azabicyclo[3.3.0]octan-7-one via reductive pauson-khand cyclization and subsequent conversion to a novel diazatricyclic ring system

  1993cited by this paper
• Studies of the solid-phase Pauson-Khand reaction: Selective in-situ enone reduction to 3-azabicyclo[3.3.0]octanones

  1993cited by this paper
• Dicobaltoctacarbonyl-mediated cyclizations of electron-deficient alkynones

  1993cited by this paper
• A total synthesis of (-)-α-kainic acid by the Pauson-Khand reaction

  1993cited by this paper
• Pauson-Khand reaction with electron-deficient alkynes

  1992cited by this paper
• The Pauson-Khand reaction in triquinane synthesis: approaches to pentalenene, pentalenic acid, and silphinene

  1992cited by this paper
• A formal total synthesis of PGA2 using the directed Pauson-Khand reaction

  1992cited by this paper
• The sequence of a stepwise AdE reaction and intramolecular Pauson-Khand cycloaddition as an entry into the synthesis of polycyclic compounds

  1992cited by this paper
• Camphor-derived alcohols as chiral auxiliaries for asymmetric Pauson-Khand bicyclizations. Enantioselective synthesis of α-methoxyenones

  1992cited by this paper
• Acceleration of the thermal pauson-khand reaction by coordinating ligands

  1992cited by this paper
• The Pauson–Khand Reaction

  1991cited by this paper
• Intramolecular alkyne–alkyne and alkyne–alkene couplings promoted by iron carbonyls

  1991cited by this paper
• An efficient preparation of 3-azabicyclo [3.3.0]. Oct-5-en-7-ones from propargyl alcohol- cobalt complexes via nicholas reaction with amidic nitrogen nucleophiles followed by pauson-khand cyclization

  1991cited by this paper
• Asymmetric allylborations of 3-decynal dicobalt hexacarbonyl: cobalt induced reversal of enantioselectivity and applications to highly diastereoselective intramolecular pauson-khand reactions

  1991cited by this paper
• An efficient protocol for the synthesis of fenestrane derivatives

  1991cited by this paper
• The directed Pauson-Khand reaction

  1991cited by this paper
• Fischer Carbene Complexes Facilitate the Intramolecular Pauson‐Khand Reaction

  1991cited by this paper
• An unusual case of Khand-Pauson cyclization involving the participation of a conjugated double bond. A promising sequence for the assemblage of polycyclic framework

  1991cited by this paper
• Total Synthesis of (13Z)-Spata-13(15),17-diene, and the Formal Synthesis of Spatol

  1990cited by this paper
• Optically active transition-metal complexes. 1021. Enantioselective synthesis of 3-oxabicyclo[3.3.0]oct-7-en-7-phenyl-6-on via Khand-Pauson reaction

  1990cited by this paper
• N-oxide promoted pauson-khand cyclizations at room temperature

  1990cited by this paper
• The synthesis of nitrogen heterocycles via the intramolecular Khand reaction: formation of tetra- and hexa-hydrocyclopenta[c]pyrrol-5(1H)-ones and hexahydro-6H-2-pyrindin-6-ones

  1990cited by this paper
• 2‐Pentylcyclopent‐2‐en‐1‐one by Catalytic Pauson‐Khand Reaction

  1990cited by this paper
• Asymmetric induction studies in the intramolecular pauson-khand cyclization of 7-alkoxy-1-hepten-6-ynes

  1990cited by this paper
• Asymmetric approach to Pauson-Khand bicyclization. Enantioselective formal synthesis of hirsutene

  1990cited by this paper
• Methylenecyclopropane as an alkene component in the Khand-Pauson reaction

  1989cited by this paper
• Oxygen-atom-transfer reactions to metal carbonyls. Kinetics and mechanism of CO substitution of M(CO)5 (M = Fe, Ru, Os) in the presence of trimethylamine oxide

  1989cited by this paper
• Optisch aktive Übergangsmetall-Komplexe: XCX. Optisch reines 3a,4,5,6,7,7a-Hexahydro-2-phenyl-4,7-methano-1H-inden-1-on durch asymmetrische Khand-Reaktion

  1988cited by this paper
• Organometallics in Organic Synthesis: Aspects of a Modern Interdisciplinary Field

  1988cited by this paper
• Steric control in the pauson cycloaddition: Further support for the proposed mechanism

  1988cited by this paper
• The Khand reaction of some trisubstituted alkenes. Uses of the catalytic version of the reaction

  1988cited by this paper
• Formation and reactivity of trimethylsilylmethyl cyclopentenones

  1988cited by this paper
• The effect of ultrasound and of phosphine and phosphine-oxides on the Khand reaction

  1988cited by this paper
• Transition metal-mediated cycloaddition reactions of alkynes in organic synthesis

  1988cited by this paper
• Adsorption effects on the efficiency of cobalt-mediated cyclizations of allylpropargyl ethers into derivatives of 3-oxabicyclo[3.3.0]oct-5-en-7-one

  1986cited by this paper
• New route to the synthesis of polycyclic compounds based on a stepwise AdE-reaction of dicobalt hexacarbonyl complexes of conjugated enynes with a subsequent intramolecular Khand-Pauson type reaction.

  1986cited by this paper
• The khand reaction

  1985cited by this paper
• Synthesis of 11-oxatricyclo[5.3.1.02,6]undecane derivatives via organometallic cyclizations

  1985cited by this paper
• Comprehensive Organometallic Chemistry. The Synthesis, Reactions, and Structures of Organometallic Compounds

  1984cited by this paper
• Preparation of bicyclo[3.3.0]oct-1-en-3-one and bicyclo[4.3.0]non-1(9)-en-8-one via intramolecular cyclization of .alpha.,.omega.-enynes

  1981cited by this paper
• USES OF COBALT‐CARBONYL ACETYLENE COMPLEXES IN ORGANIC SYNTHESIS * †

  1977cited by this paper
• Organocobalt complexes. Part I. Arene complexes derived from dodecacarbonyltetracobalt

  1973cited by this paper

• Photoredox/Brønsted Acid-Catalyzed Asymmetric Difluoroalkylation/Rearrangement of Alkenylfurans.

  2025cites this paper
• Substrate-Controlled Divergent Synthesis of Multisubstituted Cyclopentenones and 1,4-Diketones.

  2025cites this paper
• Asymmetric Ketoalkylation/Rearrangement of Alkyenlfurans via Synergistic Photoredox/Brønsted Acid Catalysis.

  2022cites this paper
• Multicomponent Reactions in Medicinal Chemistry

  2021cites this paper
• Application of Pauson–Khand reaction in the total synthesis of terpenes

  2021cites this paper
• N-Heterocyclic Carbene-Catalyzed Asymmetric Synthesis of Cyclopentenones.

  2021cites this paper
• Formation of Aldehydes and Ketones by Carbonylation and Related Reactions

  2018cites this paper
• Total synthesis of the antibiotic 4-hydroxycyclopent-2-en-1-one acrylate derivative EA-2801

  2017cites this paper
• Palladium-catalyzed dearomatizative [2 + 2 + 1] carboannulation of 1,7-enynes with aryl diazonium salts and H2O: facile synthesis of spirocyclohexadienone-fused cyclopenta[c]quinolin-4(5H)-ones.

  2017cites this paper
• Intermolecular Pauson–Khand reactions of N-substituted maleimides

  2017cites this paper
• Applications in Catalysis

  2017cites this paper
• Exploring the Complexity‐Generating Features of the Pauson–Khand Reaction from a Synthetic Perspective

  2016cites this paper
• Synthesis of Chiral Cyclopentenones.

  2016cites this paper
• Ligand-controlled divergent formation of alkenyl- or allylboronates catalyzed by Pd, and synthetic applications.

  2014cites this paper
• Chiral metal nanoparticle-catalyzed asymmetric C-C bond formation reactions.

  2014cites this paper
• Nickel(0)-catalyzed enantioselective annulations of alkynes and arylenoates enabled by a chiral NHC ligand: efficient access to cyclopentenones.

  2014cites this paper
• Ruthenium-Catalyzed [2 + 2] Cycloadditions between Norbornene and Propargylic Alcohols or Their Derivatives

  2014cites this paper
• Sulfur incorporation: copper-catalyzed cascade cyclization of 1,7-enynes with metal sulfides toward thieno[3,4-c]quinolin-4(5H)-ones.

  2014cites this paper
• Enantioselective synthesis of 4-heterosubstituted cyclopentenones.

  2013cites this paper
• Synthesis of Bioactive Natural Products by Propargylic Carboxylic Ester Rearrangements

  2013cites this paper
• Preparation of allylboronates by Pd-catalysed borylative cyclisation of dienynes.

  2013cites this paper
• Pd-catalyzed borylative cyclisation of 1,7-enynes.

  2012cites this paper
• Stereoselective synthesis of optically active cyclopenta[c]pyridines and tetrahydropyridines

  2012cites this paper
• Rhodium(III)-catalyzed oxidative carbonylation of benzamides with carbon monoxide.

  2011cites this paper
• Five-Membered Carbocycles

  2010cites this paper
• Pauson–Khand Reaction of Allenic Hydrocarbons: Synthesis of 4-Alkylidenecyclopentenones

  2010cites this paper
• 2,2′‐Bis[bis(3,5‐di‐tert‐butyl‐4‐methoxyphenyl)phosphino]‐6,6′‐dimethoxy‐1,1′‐biphenyl in Intramolecular Rhodium(I)‐Catalyzed Asymmetric Pauson–Khand‐Type Reactions

  2010cites this paper
• Stereoselective synthesis of optically active cyclopenta[c]pyrans and cyclopenta[c]furans by the intramolecular Pauson–Khand reaction

  2010cites this paper
• Catalytic Pauson–Khand-type reactions and related carbonylative cycloaddition reactions

  2009cites this paper
• Synthesis of some cyclopentenones and crystal structure of 4-hydroxy-3,4-bis(4-methoxyphenyl)-5,5-dimethyl-2-cyclopenten-1-one

  2009cites this paper
• Solvent effects on the asymmetric Pauson–Khand-type reaction by rhodium

  2009cites this paper
• X-ray Crystallographic and NMR Spectroscopic Study of (η2-Alkene)(μ-alkyne)pentacarbonyldicobalt Complexes: Arrested Pauson−Khand Reaction Intermediates

  2009cites this paper
• Alkyne chemistry in crop protection.

  2009cites this paper
• Enantioselektive palladiumkatalysierte Trimethylenmethan‐[3+2]‐Cycloadditionen

  2008cites this paper
• Stereoselective synthesis of spirocyclic cyclopentapyrans by the Pauson–Khand reaction on camphor tethered enynes

  2008cites this paper
• Enantioselective palladium-catalyzed trimethylenemethane [3+2] cycloadditions.

  2008cites this paper
• Steric buttressing in the Pauson–Khand reactions of aryl enynes

  2007cites this paper
• Electronic and Steric Effects of Atropisomeric Ligands SYNPHOS® and DIFLUORPHOS®vs. BINAPs in Rh(I)-Catalyzed Asymmetric Pauson–Khand Reaction

  2007cites this paper
• The Intermolecular Pauson‐Khand Reaction of Sugar‐Derived Azaenynes: A Case of Total Diastereoselectivity

  2006cites this paper
• Straightforward synthesis of di-, tri- and tetracyclic lactams via catalytic Pauson–Khand and Alder–Ene reactions of MCR products

  2005cites this paper
• A Pauson-Khand approach to new carbocyclic nucleoside analogs

  2005cites this paper
• Stereoselective Construction of Quaternary Stereocenters

  2005cites this paper
• Rhodium-Catalyzed Asymmetric Pauson–Khand Reaction Using Monophosphoramidite Ligand SIPHOS

  2005cites this paper
• A facile and efficient synthesis of enyne-reaction precursors by multicomponent reactions

  2005cites this paper
• Rhodium-catalyzed asymmetric aqueous Pauson-Khand-type reaction.

  2005cites this paper
• Rhodium-BisbenzodioxanPhos complex-catalyzed homogeneous enantioselective pauson-khand-type cyclization in alcoholic solvents

  2005cites this paper
• Asymmetric Pauson–Khand reaction with chiral, electron-deficient mono- and bis-phosphine ligands

  2004cites this paper
• Vinyl sulfoxides as stereochemical controllers in intermolecular Pauson-Khand reactions: applications to the enantioselective synthesis of natural cyclopentanoids.

  2004cites this paper
• When the Pauson-Khand and Pauson-Khand type reactions go awry: a plethora of unexpected results

  2004cites this paper
• Stereoselectivity in the intermolecular Pauson-Khand reaction of electron-deficient terminal alkynes

  2004cites this paper
• New entry to the Pauson–Khand reaction: trimethylgermyl group at the triple bond terminus as a latent functional group

  2004cites this paper
• Catalytic asymmetric carbonylative silylcarbocyclization of enynes

  2004cites this paper
• Selective transformations of differently functionalized 4-ethynyl-octa-1,7-dienes and 5-ethynyl-nona-1,8-dienes via intramolecular Pauson–Khand reaction: preparation of new and useful building blocks for the synthesis of angularly fused triquinanes

  2002cites this paper
• STRATEGIES FOR THE SYNTHESIS OF ENANTIOMERICALLY PURE MEDIUM-SIZED CARBOCYCLES FROM CARBOHYDRATES

  2002cites this paper
• Cyclocarbonylation of silicon tethered enynes derived from propargylic alcohols and vinylsilanes: a new reductive Pauson–Khand reaction with a traceless tether

  2002cites this paper
• On the mechanism of the silicon-tethered reductive Pauson-Khand reaction

  2002cites this paper
• Alkaloid N-oxide promoted asymmetric cobalt-mediated Pauson–Khand reaction

  2002cites this paper
• Pauson−Khand Reactions of Electron-Deficient Alkenes

  2002cites this paper
• Endo-selective intramolecular Pauson-Khand reactions of gamma-oxygenated-alpha,beta-unsaturated phenylsulfones.

  2001cites this paper
• Regioselectivity in the Pauson–Khand reaction of allenic hydrocarbons

  2001cites this paper
• Silicon electronic effect in the Pauson–Khand reaction of alkynylsilanes with allenes

  2001cites this paper
• INTRAMOLECULAR PAUSON-KHAND REACTIONS OF AROMATIC ENYNES

  2001cites this paper
• Remote substituent effects on regioselectivity in the Pauson–Khand reaction of 2-substituted norbornenes

  2001cites this paper
• The Literature of Heterocyclic Chemistry, Part VII: 1997–1999

  2001cites this paper
• Advances in the Pauson-Khand reaction: development of reactive cobalt complexes.

  2001cites this paper
• Cobalt mediated cyclisations

  2000cites this paper
• The Phenylsulfonyl Group as anendo Stereochemical Controller in Intramolecular Pauson–Khand Reactions of 3-Oxygenated 1,6-Enynes

  2000cites this paper
• The brucine N -oxide promoted asymmetric Pauson-Khand reaction

  2000cites this paper
• Dodecacarbonyltetracobalt Catalysis in the Thermal Pauson-Khand Reaction This work was supported by the National Science Foundation and the donors to the Krafft Research Fund.

  2000cites this paper
• An Allenic [2+2+1] Cycloaddition

  2000cites this paper
• Recent Advances in the Pauson–Khand Reaction and Related [2+2+1] Cycloadditions

  2000cites this paper
• Pauson-Khand reaction of activated olefins

  1999cites this paper
• The Asymmetric Pauson—Khand Reaction

  1998cites this paper
• Theoretical Study of R u‐Catalysis

  year unknowncites this paper