Preparation of bis(tetrabutylammonium) octa(.mu.3-chloro)hexakis(trifluoromethanesulfonato)-octahedro-hexamolybdate(2-), (Bu4N)2[Mo6Cli8(CF3SO3)a6]: a versatile starting material for substituted molybdenum(II) clusters containing the [Mo6Cli8]4+ core

No abstract is available for this paper.

• Publication year

  1992

• Venue

  Inorganic Chemistry

• Publication date

  1992-05-01

• Fields of study

  Chemistry

• Identifiers
  DOI 10.1021/IC00036A028
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• No references are available for this paper.

• Recent developments on luminescent octahedral transition metal cluster complexes towards biological applications

  2023cites this paper
• Substitution of apical iodide ligands in octahedral molybdenum cluster complexes by N-donor molecules: Synthesis and investigation of [{Mo6I8}(L)I5]– and cis-[{Mo6I8}(L)2I4] (L = CH3CN or 1,2,4-triazole)

  2023cites this paper
• Proton-Switched Emission Behavior of Hexanuclear Molyb-denum(II) Clusters Bearing Terminal Pyridine Carboxylate Ligands

  2020cites this paper
• Exploring the Breadth of Terminal Ligands Coordinated in [Mo6X8]4+- and [Re6Q8]2+-Based Cluster Complexes

  2019cites this paper
• Luminescence Quenching of Ligand‐Substituted Molybdenum and Tungsten Halide Clusters by Oxygen and Their Oxidation Electrochemistry

  2017cites this paper
• Tosylate cluster complexes (Bu4N)2[М6I8(O3SC6H4CH3)6] (M = Mo, W)

  2017cites this paper
• Clustomesogens: Liquid Crystalline Hybrid Nanomaterials Containing Functional Metal Nanoclusters.

  2016cites this paper
• Complexes of {Mo6I8} with nitrophenolates: synthesis and luminescence

  2016cites this paper
• Octahedral molybdenum cluster complexes with aromatic sulfonate ligands.

  2016cites this paper
• Synthetic Tuning of Redox, Spectroscopic, and Photophysical Properties of {Mo6I8}(4+) Core Cluster Complexes by Terminal Carboxylate Ligands.

  2016cites this paper
• Quasi-One-Step Six-Electron Electrochemical Reduction of an Octahedral Hexanuclear Molybdenum(II) Cluster.

  2016cites this paper
• (W6I8)Cl4 – A Basic Model Compound for Photophysically Active [(W6I8)L6]2– Clusters?

  2016cites this paper
• From Mesomorphic Phosphine Oxide to Clustomesogens Containing Molybdenum and Tungsten Octahedral Cluster Cores.

  2015cites this paper
• Surface immobilization of Mo6I8 octahedral cluster cores on functionalized amorphous carbon using a pyridine complexation strategy

  2015cites this paper
• Clusters and Cluster Assemblies

  2013cites this paper
• Alkynyl complexes of high-valence clusters. synthesis and luminescence properties of [Mo6I8(C≡CC(O)OMe)6]2-, the first complex with exclusively organometallic outer ligands in the family of octahedral {M6X8} clusters.

  2013cites this paper
• The molybdenum and rhenium octahedral cluster chalcohalides in solid state chemistry: From condensed to discrete cluster units

  2012cites this paper
• Crystal structures of two solvates of molybdenum octahedral clusters: (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]·2CH3CN and (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]·2CH2Cl2

  2012cites this paper
• Hydroxyl-bridged lanthanide amino acid clusters and hexatantalum and hexatungsten chloride clusters: Synthesis, characterization, and relevance to biomedical imaging

  2011influential citation
• A new hexanuclear rhenium cluster complex with six terminal acetate ligands: Synthesis, structure, and properties of K4[Re6S8(CH3COO)6]·8H2O

  2010cites this paper
• Spectral Characteristics and Molecular Structure of Unsaturated Carboxylic Acid Salts

  2010cites this paper
• Divergent electronic structures of isoelectronic metalloclusters: tungsten(II) halides and rhenium(III) chalcogenide halides.

  2009cites this paper
• Experimental and Theoretical Evidence of π‐d Interactions in Supramolecular Assemblies Based on TTF‐CH=CH‐Py Ligands Tethered to Mo6Xi8 Octahedral Molybdenum Halide Cluster Cores

  2009cites this paper
• Synthesis and ligand-exchange kinetics of the solvated trigonal-prismatic clusters [W6CCl12L6]2+ (L=dmf, py).

  2007cites this paper
• Elaboration of Hybrid Nanocluster Materials by Solution Chemistry

  2007cites this paper
• A hybrid material based on [Mo6Br14]2− inorganic cluster units and [BEDO-TTF]+ organic monocationic radicals: Synthesis, structure and properties of (BEDO-TTF)2Mo6Br14(PhCN)4

  2006cites this paper
• Bis(tetra­phenyl­phospho­nium) octa‐μ3‐chloro‐hexa­kis(trifluoro­methane­sulfonato)‐octa­hedro‐hexa­molybdate dichloro­methane/diethyl ether solvate

  2006influential citation
• Mo6X8i Nanocluster cores (X = Br, I): From inorganic solid state compounds to hybrids

  2006cites this paper
• Synthesis and Characterization of Cs2Mo6X14 (X = Br or I) Hexamolybdenum Cluster Halides: Efficient Mo6 Cluster Precursors for Solution Chemistry Syntheses

  2005cites this paper
• The Simple Hexapyridine Cluster [Mo6Br8Py6][OSO2CF3]4 and Substituted Hexapyridine Clusters Including a Cluster-cored Polyolefin Dendrimer†

  2005cites this paper
• Mo6Br8-Cluster-cored organometallic stars and dendrimers

  2005cites this paper
• Synthesis, Structure, and Properties of New Hybrid Nanocomposites Containing the [Mo6(μ3-Cl)8]4+ Cluster

  2004cites this paper
• Synthesis of hexanuclear molybdenum clusters containing phosphine oxide ligands

  2002cites this paper
• Extended materials based on the [Mo6Cl8]4+ building block bridged by 4,4′-bipyridine

  2001cites this paper
• Octa(mu3-selenido)hexarhenium(III) complexes containing axial monodentate diphosphine or diphosphine-monoxide ligands.

  2001cites this paper
• Inertness of the [Re6Se5Cl3]5+ cluster core to substitution by OH− in organic solutions: synthesis, structural and liquid secondary ion mass spectroscopy characterization of K(H2O)2[Re6Se5Cl9] and (n-Bu4N)[Re6Se5Cl9] and the crystal structure of (n-Bu4N)2[Re6Se6Cl8]

  2001cites this paper
• Chemistry of hexanuclear rhenium chalcohalide clusters.

  2001cites this paper
• Synthesis and structure of the useful starting material [Bu4N]3[Nb6Cl12(OSO2CF3)6]

  2000cites this paper
• Preparation of [Bu4N]2[W6Cl8F6] and characterization of the clusters [Bu4N]2[W6Cl8X6] (X=F, Cl, Br, I, NCO, NCS, NCSe, or OSO2CF3) by 183W NMR spectroscopy

  2000cites this paper
• Hybrid organic–inorganic, hexa-arm dendrimers based on an Mo6Cl8 core

  1999cites this paper
• The Octahedral M 6Y 8 And M 6Y 12 Clusters of Group 4 and 5 Transition Metals

  1998cites this paper
• Preparation of tetrabutylammonium octa-μ3-bromohexa(trifluoromethanesulfonato)octahedro-hexamolybdate (2−), (Bu4N)2[Mo6Br8i(CF3SO3)6a] and other derivatives containing the Mo6Br84+ core

  1998cites this paper
• Polymer-immobilized nanoscale and cluster metal particles

  1997cites this paper
• π-Complexes of metalloporphyrins as model intermediates in hydrodementallation (HDM) catalysis

  1997cites this paper
• Synthesis and photophysical properties of polymer-bound hexanuclear molybdenum clusters

  1996cites this paper
• Structure and bonding in face- and edgebridged octahedral transition metal clusters

  1996cites this paper
• μ3‐Imidofunktionalisierte Molekülcluster vom Chevrel‐Sergent‐Typ, eine neue Klasse von anorganisch‐organischen Hybridverbindungen: Herstellung und Alkylierungsreaktionen

  1996cites this paper
• Monodisperse Metal Clusters 10 Angstroms in Diameter in a Polymeric Host: The "Monomer as Solvent' Approach

  1995cites this paper
• Synthesis and structural characterization of some anhydrous Ln(OTf)3 complexes (Ln=Sc, La, Nd, Sm, Gd and Er; OTf=CF3SO3)

  1994cites this paper
• Synthesis of heterometallic butterfly carbide clusters containing three different metals: (PPN)[Fe2CoM(dmpm)(CO)11C] (MMo or W)

  1993cites this paper
• Preparation and structural characterization of a hexanuclear molybdenum (II) cluster containing carboxylate ligands (Bu4N)2[Mo6(μ3-Cl)8(O2CMe)6]

  1993cites this paper