Highly enantioselective copper-catalyzed allylic alkylation with atropos phosphoramidites bearing a D2-symmetric biphenyl backbone

No abstract is available for this paper.

• Publication year

  2010

• Venue

  Tetrahedron

• Publication date

  2010-05-15

• Fields of study

  Chemistry

• Identifiers
  DOI 10.1016/J.TET.2010.03.031
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• From tropos to atropos: 5,5′-bridged 2,2′-bis(diphenylphosphino)biphenyls as chiral ligands for highly enantioselective palladium-catalyzed hydrogenation of α-phthalimide ketones

  2010cited by this paper
• Efficient bimetallic titanium catalyst for carbonyl-ene reaction

  2009cited by this paper
• Development of biisoquinoline-based chiral diaminocarbene ligands: enantioselective SN2' allylic alkylation catalyzed by copper-carbene complexes.

  2008cited by this paper
• Ir-catalyzed regio- and enantioselective Friedel-Crafts-type allylic alkylation of indoles.

  2008cited by this paper
• Metal-catalyzed enantioselective allylation in asymmetric synthesis.

  2008cited by this paper
• Highly site- and enantioselective Cu-catalyzed allylic alkylation reactions with easily accessible vinylaluminum reagents.

  2008cited by this paper
• Catalytic asymmetric conjugate addition and allylic alkylation with Grignard reagents.

  2008cited by this paper
• Enantioselective copper-catalyzed conjugate addition and allylic substitution reactions.

  2008cited by this paper
• Synthesis of optically active bifunctional building blocks through enantioselective copper-catalyzed allylic alkylation using Grignard reagents.

  2007cited by this paper
• First chiral phosphoroamidite-phosphite ligands for highly enantioselective and versatile Pd-catalyzed asymmetric allylic substitution reactions.

  2007cited by this paper
• The copper-catalyzed asymmetric allylic substitution

  2006cited by this paper
• Rhodium-catalyzed asymmetric synthesis of indanones: development of a new "axially chiral" bisphosphine ligand.

  2006cited by this paper
• A new class of versatile chiral-bridged atropisomeric diphosphine ligands: remarkably efficient ligand syntheses and their applications in highly enantioselective hydrogenation reactions.

  2006cited by this paper
• Phosphoramidite ligands in iridium-catalyzed allylic substitution.

  2006cited by this paper
• β‐Disubstituted Allylic Chlorides: Substrates for the Cu‐Catalyzed Asymmetric SN2′ Reaction

  2006cited by this paper
• Recent progress in asymmetric allylic substitutions catalyzed by chiral copper complexes.

  2005cited by this paper
• Asymmetrische allylische Substitution mit chiralen Kupferkomplexen als Katalysatoren

  2005cited by this paper
• Highly enantioselective copper-catalyzed allylic alkylation with phosphoramidite ligands

  2004cited by this paper
• A highly effective phosphoramidite ligand for asymmetric allylic substitution.

  2004cited by this paper
• Asymmetric allylic alkylation, an enabling methodology.

  2004cited by this paper
• Difluorphos, an electron-poor diphosphane: a good match between electronic and steric features.

  2004cited by this paper
• Copper catalyzed enantioselective allylic substitution by MeMgX

  2004cited by this paper
• Highly regioselective asymmetric copper-catalyzed allylic alkylation with dialkylzincs using monodentate chiral spiro phosphoramidite and phosphite ligands

  2003cited by this paper
• Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.

  2003cited by this paper
• Tandem copper-catalyzed enantioselective allylation-metathesis.

  2002cited by this paper
• New Chiral Diphosphine Ligands Designed to have a Narrow Dihedral Angle in the Biaryl Backbone

  2001cited by this paper
• Enantioselective Copper-Catalyzed SN2′ Substitution with Grignard Reagents

  2001cited by this paper
• Thiolates as Ligands in the Enantioselective Copper-Catalyzed Substitution of Allylic Acetates with Grignard Reagents

  2001cited by this paper
• Enantioselective copper-catalyzed allylic alkylation with dialkylzincs using phosphoramidite ligands.

  2001cited by this paper
• Asymmetric Induction in the Arenethiolatocopper(I)-Catalyzed Substitution Reaction of Grignard Reagents with Allylic Substrates

  2000cited by this paper
• Highly Effective Chiral Dipyridylphosphine Ligands: Synthesis, Structural Determination, and Applications in the Ru-Catalyzed Asymmetric Hydrogenation Reactions

  2000cited by this paper
• Highly Enantioselective Catalytic Conjugate Addition and Tandem Conjugate Addition–Aldol Reactions of Organozinc Reagents

  1997cited by this paper
• Asymmetric Transition Metal-Catalyzed Allylic Alkylations.

  1996cited by this paper
• Diastereoselective Synthesis of 1,1'-Binaphthyl-2,2'-diol

  1995cited by this paper
• Chiral arenethiolatocopper(I) catalyzed substitution reactions of acyclic allylic substrates with Grignard reagents

  1995cited by this paper
• Catalytic Asymmetric Synthesis

  1993cited by this paper
• Enantioselective synthesis of macrocyclic propargylic alcohols by [2,3] Wittig ring contraction. Synthesis of (+)-aristolactone and cembranoid precursors

  1988cited by this paper

• Organometallic Complexes of Copper

  2021cites this paper
• P-Chiral Monophosphorus Ligands for Asymmetric Copper-Catalyzed Allylic Alkylation

  2019cites this paper
• DFT Study of the Strong Solvent Effects in the Cu‐Catalyzed Asymmetric Conjugate Addition Reaction

  2018cites this paper
• Regio- and Enantioselective Copper-Catalyzed 1,4-Conjugate Addition of Trimethylaluminium to Linear α,β,γ,δ-Unsaturated Alkyl Ketones

  2016cites this paper
• Asymmetric Allylic Substitutions Using Organometallic Reagents

  2016cites this paper
• Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C–C Bonds

  2015cites this paper
• 3.04 Alkylations of Nonstabilized Carbanions

  2014cites this paper
• Asymmetric Allylic Alkylation

  2014cites this paper
• Copper-catalyzed asymmetric 1,4-conjugate addition of Grignard reagents to linear α,β,γ,δ-unsaturated ketones.

  2013cites this paper
• Copper-free asymmetric allylic alkylation with a Grignard reagent: design of the ligand and mechanistic studies.

  2013cites this paper
• Highly Enantioselective Hydrogenation of N-Unprotected Indoles Using (S)-C10—BridgePHOS as the Chiral Ligand.

  2013cites this paper
• 4. Phosphoramidite Ligands

  2012cites this paper
• Transition Metal Catalyzed Enantioselective Allylic Substitution in Organic Synthesis

  2012influential citation
• The effects of solvent on switchable stereoselectivity: copper-catalyzed asymmetric conjugate additions using D2-symmetric biphenyl phosphoramidite ligands.

  2012cites this paper
• Switchable Stereoselectivity: The Effects of Substituents on the D2‐Symmetric Biphenyl Backbone of Phosphoramidites in Copper‐Catalyzed Asymmetric Conjugate Addition Reactions with Triethylaluminium

  2012cites this paper
• Enantioselective synthesis of chiral γ-aryl α-keto ester by copper-catalyzed 1,4-conjugate addition using D2-symmetric biphenyl phosphoramidite ligand

  2011cites this paper
• Iridium-Catalyzed Asymmetric Allylic Substitution

  2010cites this paper