The origin of the configurational instability of 1-silyl-1-alkenyllithiums and related alkenylmetals

No abstract is available for this paper.

• Publication year

  1986

• Venue

  Journal of the American Chemical Society

• Publication date

  1986-06-01

• Fields of study

  Chemistry

• Identifiers
  DOI 10.1021/JA00272A040
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• No references are available for this paper.

• Intramolecular Anti ‐Carbolithiation of Alkynes: Stereo‐Directing Effect of Lithium‐Coordinating Substituents

  2022cites this paper
• Palladium-Catalyzed Regioselective C-H Iodination of Unactivated Alkenes.

  2019cites this paper
• Regio- and Diastereoselective Copper-Catalyzed Carbometalation of Cyclopropenylsilanes.

  2019cites this paper
• Enantioselective Synthesis of All-Carbon Quaternary Centers Structurally Related to Amaryllidaceae Alkaloids.

  2018cites this paper
• Total Synthesis of Disciformycin A and B: Unusually Exigent Targets of Biological Significance.

  2018cites this paper
• Computational Studies on the Reaction from Silyl 1,4-Dilithio 1,3-butadiene to Lithio Silole

  2016cites this paper
• Silylative coupling of olefins with vinylsilanes in the synthesis of functionalized alkenes

  2015cites this paper
• Organo-di-Lithio Reagents: Cooperative Effect and Synthetic Applications

  2013cites this paper
• I. Organoalkali Chemistry

  2013cites this paper
• 1,4-Dilithio-1,3-dienes: reaction and synthetic applications.

  2010cites this paper
• Formation of alpha-lithio siloles from silylated 1,4-dilithio-1,3-butadienes: mechanism and applications.

  2010cites this paper
• Silylative Coupling of Olefins with Vinylsilanes in the Synthesis of π‐Conjugated Double Bond Systems

  2010cites this paper
• Intramolecular Carbolithiation Reactions

  2009cites this paper
• Regio- and stereoselective generation of alkenylindium compounds from indium tribromide, alkynes, and ketene silyl acetals.

  2009cites this paper
• Cyclopropenylcarbinol derivatives as new versatile intermediates in organic synthesis: application to the formation of enantiomerically pure alkylidenecyclopropane derivatives.

  2009cites this paper
• Carbozincation of Alkenes and Alkynes

  2009cites this paper
• Chapter 7. Carbometallation Reactions

  2007cites this paper
• Diastereoselective reduction of cyclopropenylcarbinol: new access to anti-cyclopropylcarbinol derivatives.

  2004cites this paper
• Diversity-oriented synthesis of tamoxifen-type tetrasubstituted olefins.

  2003cites this paper
• 1‐(Trimethylsilyl)vinyllithium

  2001cites this paper
• Synthesis of thieno[2,3-b]quinoxalines from 2-haloquinoxalines

  2001cites this paper
• Novel synthesis of oxindoles from carbamoyl chlorides via palladium catalysed cyclisation–anion capture

  2000cites this paper
• A nickel-catalyzed carbozincation of aryl-substituted alkynes

  1998cites this paper
• Reaction of alkylidenedinitrosylmolybdenum complexes with vinyl trisubstituted silanes and substituted acetylenes

  1996cites this paper
• SYNTHESIS OF CHIRAL ALLENES BY PETERSON-TYPE OLEFINATIONS

  1996cites this paper
• 2.19 – Vinyl- and Arylmetals

  1995cites this paper
• 4.23 – Functions Containing at Least One Metalloid (Si, Ge or B) and No Halogen, Chalcogen or Group 15 Element; also Functions Containing Two Metals

  1995cites this paper
• 2.18 – Vinyl- and Arylsilicon, -germanium, and Boron Compounds

  1995cites this paper
• 4.18 – Functions Incorporating a Halogen or Another Group other than a Halogen or a Chalcogen

  1995cites this paper
• Organic Transformations Mediated by Group 13 Metal Compounds

  1994cites this paper
• Zirconium catalyzed CC bond formation reaction of conjugated diynes with EtMgBr

  1993cites this paper
• Intramolecular zinc-ene reactions of alkynes; preparation of 1,5-annulated 4-methylenecyclopentenes

  1992cites this paper
• 4.4 – Carbometallation of Alkenes and Alkynes

  1991cites this paper
• Carbocyclization of δ-acetylenic propargylic zinc reagents

  1991cites this paper
• Stereoselective cyclic carbolithiation of alkyne derivatives. A stereoselective synthesis of exocyclic alkenes

  1990cites this paper
• Synthesis and functionalisation of intermediates derived from allylmagnesiation of (E)-1-(trimethylsilyl)-but-1-en-3-ol

  1989cites this paper
• 1,5-Annelated 4-methylenecyclopentenes by intramolecular type I zinc-ene reactions followed by Pd(0)-catalyzed cyclization

  1989cites this paper
• Organosilicon survey 1986-the SiliconCarbon bond

  1989cites this paper
• Metathesis of silicon containing olefins: II. Synthesis of 1,2-bis(silyl)ethenes by metathesis of vinylsilanes☆

  1989cites this paper
• Metathesis of silicon-containing olefins. IV: Synthesis of 1-triethoxysilyl-1-alkenes by cross-metathesis of vinyltriethoxysilane with 1-alkenes

  1989cites this paper
• A highly stereoselective synthesis ofE-11-hexadecen-1-ol acetate: Puretrans pheromones from acylsilane/ylide chemistry

  1988cites this paper
• Allylmetalation of 1-silylalkynes by 2-bromozincmethyl-2-propenyl ethers followed by pd(0)-catalyzed cyclization: A one-pot synthesis of 4-methylenecyclopentenes

  1987cites this paper
• Controlled carbometalation as a new tool for carbon-carbon bond formation and its application to cyclization

  1987cites this paper
• (E)/(Z)-Isomerisierung von 1-Boryl-2-stannyl-1-alkenen

  1987cites this paper
• On the Origin of the Configurational Instability of (l-Silyl-1-alkenyl)lithiums and Related Alkenylmetals.

  1986cites this paper