Theory of Square-wave Voltammetry of Kinetically Controlled Two-step Electrode Reactions

An influence of electron transfer kinetics on square-wave voltammograms of two-step electrode reaction is investigated theoretically. A phenomenon of "kinetic burden" of potential inversion is de- scribed for the case of equal kinetic parameters. A linear relationship between standard rate constant and the difference between standard potentials of the second and the first charge transfers is demonstrated for the reactions with thermodynamically unstable intermediate. (doi: 10.5562/cca2126)

• Publication year

  2012

• Venue

  Croatica Chemica Acta

• Publication date

  2012-12-17

• Fields of study

  Chemistry

• Identifiers
  DOI 10.5562/CCA2126
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

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