The assignment of absolute configurations by NMR of arylmethoxyacetate derivatives: is this methodology being correctly used?

No abstract is available for this paper.

• Publication year

  2000

• Venue

  Tetrahedron-asymmetry

• Publication date

  2000-07-14

• Fields of study

  Chemistry

• Identifiers
  DOI 10.1016/S0957-4166(00)00228-7
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Assignment of the absolute configuration of alpha-chiral carboxylic acids by 1H NMR spectroscopy

  2000cited by this paper
• 9-Anthrylmethoxyacetic acid esterification shifts—Correlation with the absolute stereochemistry of secondary alcohols

  1999cited by this paper
• Boc-Phenylglycine: The Reagent of Choice for the Assignment of the Absolute Configuration of alpha-Chiral Primary Amines by (1)H NMR Spectroscopy.

  1999cited by this paper
• Chemical Study and Absolute Configuration of a New Marine Secospatane from the Brown Alga Dilophus okamurae.

  1999cited by this paper
• Complexation with Barium(II) Allows the Inference of the Absolute Configuration of Primary Amines by NMR

  1999cited by this paper
• ABSOLUTE STEREOCHEMISTRY OF SOULATTROLIDE AND ITS ANALOGUES

  1998cited by this paper
• Are Both the (R)- and the (S)-MPA Esters Really Needed for the Assignment of the Absolute Configuration of Secondary Alcohols by NMR? The Use of a Single Derivative

  1998cited by this paper
• Determination of Absolute Configurations of Carbinols of Annonaceous Acetogenins with 2-Naphthylmethoxyacetic Acid Esters

  1998cited by this paper
• Novel Acetogenins from the Leaves of Dasymaschalon sootepense

  1998cited by this paper
• Assignment of the Absolute Configuration of β-Chiral Primary Alcohols by NMR: Scope and Limitations

  1998cited by this paper
• 4-deoxyannomontacin and (2,4-cis and trans)-annomontacinone, new bioactive mono-tetrahydrofuran annonaceous acetogenins from Goniothalamus giganteus.

  1997cited by this paper
• Absolute Configuration of Some Marine Metabolites from Cystoseira spp.

  1997cited by this paper
• New Type of Mono-tetrahydrofuran Ring Acetogenins from Goniothalamus donnaiensis

  1997cited by this paper
• Determining factors in the assignment of the absolute configuration of alcohols by NMR. The use of anisotropic effects on remote positions

  1997cited by this paper
• Scanlonenyne, a novel halogenated C15 acetogenin from the red alga Laurencia obtusa in Irish waters

  1997cited by this paper
• THE USE OF ETHYL 2-(9-ANTHRYL)-2-HYDROXYACETATE FOR ASSIGNMENT OF THE ABSOLUTE CONFIGURATION OF CARBOXYLIC ACIDS BY 1H NMR

  1997cited by this paper
• MTPA vs MPA in the Determination of the Absolute Configuration of Chiral Alcohols by 1H NMR

  1996cited by this paper
• Kulolide: A cytotoxic depsipeptide from a cephalaspidean mollusk, Philinopsis speciosa

  1996cited by this paper
• Absolute stereochemistry of penaresidins A and B

  1996cited by this paper
• Conformational Structure and Dynamics of Arylmethoxyacetates: DNMR Spectroscopy and Aromatic Shielding Effect

  1995cited by this paper
• Constituents of cimicifugae rhizoma II. Isolation and structures of new cycloartenol triterpenoids and related compounds from Cimicifuga foetida L

  1995cited by this paper
• Absolute stereochemistry of non-adjacent bis-tetrahydrofuranic acetogenins

  1994cited by this paper
• Absolute stereostructures of altohyrtin A and its congeners, potent cytotoxic macrolides from the Okinawan marine sponge hyrtios altum

  1994cited by this paper
• Determination of Absolute Configuration of Stereogenic Carbinol Centers in Annonaceous Acetogenins by 1H- and 19F-NMR Analysis of Mosher Ester Derivatives

  1992cited by this paper
• A new aspect of the high-field NMR application of Mosher's method. The absolute configuration of marine triterpene sipholenol A

  1991cited by this paper
• Anomaly in the modified Mosher's method: Absolute configurations of some marine cembranolides

  1991cited by this paper
• High-field FT NMR application of Mosher's method. The absolute configurations of marine terpenoids

  1991cited by this paper
• On the use of the O-methylmandelate ester for establishment of absolute configuration of secondary alcohols

  1986cited by this paper
• Correlation of configuration and fluorine-19 chemical shifts of .alpha.-methoxy-.alpha.-trifluoromethylphenyl acetate derivatives

  1973cited by this paper

• Limitations of Trifluoromethylbenzoimidazolylbenzoic Acid as a Chiral Derivatizing Agent to Assign Absolute Configuration for β-Chiral Aminoalcohols

  2022cites this paper
• Determination of the Absolute Configurations of Chiral Alkanes – An Analysis of the Available Tools

  2020cites this paper
• REFERENCES

  2018cites this paper
• Synthesis and Explosion Hazards of 4-Azido-l-phenylalanine.

  2018cites this paper
• Inhibitory Effect of Phenanthrenes and Dihydrostilbenes from Dendrobium moniliforme on Protein Tyrosine Phosphatase 1B

  2018cites this paper
• Absolute Stereochemistry by NMR Spectroscopy

  2017cites this paper
• Lovastatin Analogues from the Soil-Derived Fungus Aspergillus sclerotiorum PSU-RSPG178.

  2016cites this paper
• Enantioselective Total Synthesis of (+)-Lyngbyabellin M

  2015cites this paper
• NMR Methods for the Assignment of Absolute Stereochemistry of Bioactive Compounds

  2015cites this paper
• Further study on Penares sp. from Vietnamese waters: minor lanostane and nor-lanostane triterpenes.

  2015cites this paper
• New arylalkanones from Horsfieldia macrobotrys, effective antidiabetic agents concomitantly inhibiting α-glucosidase and free radicals.

  2015cites this paper
• Simplified NMR Procedures for the Assignment of the Absolute Configuration

  2014cites this paper
• Total Synthesis of Eupomatilones 1, 2, and 5 by Enantioselective [2,3]-Wittig Rearrangement: Total Synthesis of Eupomatilones

  2013cites this paper
• NMR Methods for Stereochemical Assignments

  2012cites this paper
• Alnumycins A2 and A3: new inverse-epimeric pairs stereoisomeric to alnumycin A1

  2012cites this paper
• Total synthesis of (-)-goniotrionin.

  2012cites this paper
• Assignment of the absolute configuration of polyfunctional compounds by NMR using chiral derivatizing agents.

  2012cites this paper
• Total synthesis of the nominal didemnaketal A.

  2012cites this paper
• Total synthesis of (+)-eupomatilone 2 via asymmetric [2,3]-Wittig rearrangement of highly oxygenated biphenylmethyl ethers

  2011cites this paper
• NMR analysis of chiral alcohols and amines: development of an environmentally benign “in tube” procedure with high efficiency and improved detection limit

  2011cites this paper
• Confirmation by IR of the preferred conformations of CFTA esters in solution: a highly reliable criterion for the stereochemistry assignment of chiral alcohols.

  2010cites this paper
• Mechanism of the cobalt oxazoline palladacycle (COP)-catalyzed asymmetric synthesis of allylic esters.

  2010cites this paper
• Stereochemical studies of 5-methyl-3-(substituted phenyl)-5-[(substituted phenyl) hydroxy methyl]-2-thiooxazolidin-4-ones

  2010cites this paper
• A "shortcut" Mosher ester method to assign configurations of stereocenters in nearly symmetric environments. Fluorous mixture synthesis and structure assignment of petrocortyne A.

  2009cites this paper
• Determination of absolute configurations by X-ray crystallography and 1H NMR anisotropy.

  2008cites this paper
• α,β‐Unsaturated Aldehydes as Substrates for Asymmetric CC Bond Forming Reactions with Thiamin Diphosphate (ThDP)‐Dependent Enzymes

  2008cites this paper
• Challenging the absence of observable hydrogens in the assignment of absolute configurations by NMR: application to chiral primary alcohols.

  2007cites this paper
• Conformational Analysis of MαNP Esters, Powerful Chiral Resolution and 1H NMR Anisotropy Tools – Aromatic Geometry and Solvent Effects on Δδ Values

  2007cites this paper
• Preparation of various enantiomerically pure (benzotriazol-1-yl)- and (benzotriazol-2-yl)-alkan-2-ols

  2006cites this paper
• Novel chiral derivatizing agents powerful for enantioresolution and determination of absolute stereochemistry by X-ray crystallographic and 1H NMR anisotropy methods

  2006cites this paper
• The prediction of the absolute stereochemistry of primary and secondary 1,2-diols by 1H NMR spectroscopy: principles and applications.

  2005cites this paper
• The assignment of the absolute configuration of 1,2-diols by low-temperature NMR of a single MPA derivative.

  2005cites this paper
• Absolute configuration of amino alcohols by 1H-NMR.

  2005cites this paper
• Application of Mosher's method for absolute configuration assignment and resolution of 2-hydroxypyrrolizidinones.

  2005cites this paper
• MalphaNP acid, a powerful chiral molecular tool for preparation of enantiopure alcohols by resolution and determination of their absolute configurations by the (1)H NMR anisotropy method.

  2004cites this paper
• O-Acetylmandelic acid as a reliable chiral anisotropy reagent for the determination of absolute configuration of alcohols

  2004cites this paper
• Microbial metabolism. Part 5. Dihydrokawain.

  2004cites this paper
• Chiral homoallylic and allylic sulfoxides as models for the stereochemical analysis of sulfoxide thiaoleates

  2004cites this paper
• Total synthesis of (±) maculalactone A, maculalactone B and maculalactone C and the determination of the absolute configuration of natural (+) maculalactone A by asymmetric synthesis

  2004cites this paper
• Is O-acetylmandelic acid a reliable chiral anisotropy reagent?

  2004cites this paper
• A very reliable method for determination of absolute configuration of chiral secondary alcohols by 1H NMR spectroscopy.

  2004cites this paper
• An NMR method towards the routine chiral determination of natural products.

  2004cites this paper
• Chiral reagents for the determination of enantiomeric excess and absolute configuration using NMR spectroscopy.

  2003cites this paper
• Oncidinol-a novel diacylglycerol from Ornithophora radicans Barb. Rodr.(Orchidaceae) floral oil

  2003cites this paper
• Exploiting predisposition in the stereoselective synthesis of mono-, bi- and tetracyclic oxygen heterocycles: equilibration between, and trapping of, alternative di- and tetraacetals.

  2003cites this paper
• 1-alkylthio-3-aryloxypropan-2-ols: synthesis and enantiomer separation by lipase-catalyzed transesterification

  2003cites this paper
• Olefin cross-metathesis as a tool in natural product degradation. The stereochemistry of (+)-falcarindiol.

  2002cites this paper
• Empirical model for the molar rotations of syn-2,2-dimethyl-1,3-dioxanes.

  2002cites this paper
• Synthesis of (+)‐9‐Demethyl‐7,8‐dideoxycalopin as a Model for the Determination of the Absolute Stereochemistry of a New Group of Fungal Metabolites

  2002cites this paper
• Incorrect procedure for the assignment of the absolute configuration of carbonucleosides by NMR: MPA must not be used with primary alcohols

  2002cites this paper
• Application of hitherto unexplored macrocyclization strategies in the epothilone series: novel epothilone analogs by total synthesis.

  2002cites this paper
• Use of a diamagnetic lanthanide complex for extending the scope of NMR determination of absolute configuration by the modified Mosher's method

  2002cites this paper
• Simultaneous enantioresolution and assignment of absolute configuration of secondary alcohols by directly coupled HPLC–NMR of 9-AMA esters

  2002cites this paper
• Caylobolide A, a unique 36-membered macrolactone from a Bahamian Lyngbya majuscula.

  2002cites this paper
• Revision of the absolute configuration of the tricyclic sesquiterpene (+)-kelsoene by chemical correlation and enantiospecific total synthesis of its enantiomer.

  2001cites this paper
• First total synthesis of mosin B.

  2001cites this paper
• A practical guide for the assignment of the absolute configuration of alcohols, amines and carboxylic acids by NMR

  2001cites this paper
• The absolute configuration of the mushroom metabolites involutin and chamonixin

  2001cites this paper
• Absolute configuration of 1,n-diols by NMR: the importance of the combined anisotropic effects in bis-arylmethoxyacetates

  2000cites this paper