Recent advances in entropy-driven ring-opening polymerizations

No abstract is available for this paper.

• Publication year

  2011

• Venue

  Polymer Chemistry

• Publication date

  2011-03-15

• Fields of study

  Materials Science, Chemistry

• Identifiers
  DOI 10.1039/C0PY00328J
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Shape memory properties of main chain bile acids polymers

  2010cited by this paper
• Lipase-catalyzed polyester synthesis – A green polymer chemistry

  2010cited by this paper
• Studies on NO releasing from PCU grafted with endogenous NO donors

  2010cited by this paper
• Entropically-driven ring-opening polymerization of macrocyclic esters with up to 84-membered rings catalysed by polymer-supported Candida antarctica lipase B

  2010cited by this paper
• The ROMP toolbox upgraded

  2010cited by this paper
• Synthesis and ring‐opening polymerization of macrocyclic aryl ketone oligomers

  2009cited by this paper
• Macrocyclic bile acids: from molecular recognition to degradable biomaterial building blocks

  2009cited by this paper
• Handbook of ring-opening polymerization

  2009cited by this paper
• Shape Memory Polymers Based on Naturally-Occurring Bile Acids

  2009cited by this paper
• Polymer-supported well-defined metathesis catalysts.

  2009cited by this paper
• Organic polymer supports for synthesis and for reagent and catalyst immobilization.

  2009cited by this paper
• Using soluble polymer supports to facilitate homogeneous catalysis.

  2009cited by this paper
• Equilibrium ring-closing metathesis.

  2009cited by this paper
• Entropy-driven ring-opening olefin metathesis polymerizations of macrocycles

  2009cited by this paper
• High throughput synthesis of polyesters using entropically driven ring-opening polymerizations.

  2008cited by this paper
• Polypseudorotaxanes via ring-opening metathesis polymerizations of [2]catenanes.

  2008cited by this paper
• Polymers from functional macrolactones as potential biomaterials: enzymatic ring opening polymerization, biodegradation, and biocompatibility.

  2008cited by this paper
• Glycolipid Biomaterials: Solid-State Properties of a Poly(sophorolipid)

  2008cited by this paper
• High molecular weight bile acid and ricinoleic acid-based copolyesters via entropy-driven ring-opening metathesis polymerisation.

  2008cited by this paper
• Glycolipid Polymer Synthesized from Natural Lactonic Sophorolipids by Ring-Opening Metathesis Polymerization

  2007cited by this paper
• Polymer-supported syntheses of cyclic oligodepsipeptides

  2007cited by this paper
• Microbial production and application of sophorolipids

  2007cited by this paper
• Main-Chain Calix[4]arene Elastomers by Ring-Opening Metathesis Polymerization

  2007cited by this paper
• Living ring-opening metathesis polymerization

  2007cited by this paper
• Heptane-soluble ring-closing metathesis catalysts.

  2007cited by this paper
• Cyclo-depolymerization of olefin-containing polymers to give macrocyclic oligomers by metathesis and the entropically-driven ROMP of the olefin-containing macrocyclic esters

  2007cited by this paper
• Investigation of lipase-catalyzed ring-opening polymerizations of lactones with various ring sizes : kinetic evaluation

  2006cited by this paper
• Application of ring closing metathesis in efficient synthesis of macrocyclic crown compounds

  2006cited by this paper
• Enzymatic synthesis of polyesters via ring-opening polymerization

  2006cited by this paper
• Ring closing metathesis employing organometallic substrates and the templated synthesis of macrocycles

  2006cited by this paper
• Olefin-metathesis catalysts for the preparation of molecules and materials (Nobel Lecture).

  2006cited by this paper
• Synthesis of a catechol-based poly(ether ether ketone) ( o-PEEK ) by classical step-growth polymerization and by entropically driven ring-opening polymerization of macrocyclic oligomers

  2006cited by this paper
• Macrocyclization by ring-closing metathesis in the total synthesis of natural products: reaction conditions and limitations.

  2006cited by this paper
• Initiation of shape-memory effect by inductive heating of magnetic nanoparticles in thermoplastic polymers.

  2006cited by this paper
• Entropically driven ring-opening metathesis polymerization (ED-ROMP) of macrocyclic olefin-containing oligoamides

  2006cited by this paper
• Main-chain bile acid based degradable elastomers synthesized by entropy-driven ring-opening metathesis polymerization.

  2006cited by this paper
• New Strategy for Enzymatic Synthesis of High‐Molecular‐Weight Poly(butylene succinate) via Cyclic Oligomers

  2006cited by this paper
• Recent work on entropically‐driven ring‐opening polymerizations: some potential applications

  2005cited by this paper
• Enzyme catalyzed synthesis of polyesters

  2005cited by this paper
• Ring-chain interconversion in high-performance polymer systems. 3. Cyclodepolymerization of poly(m-phenylene isophthalamide) (Nomex) and entropically driven ring-opening polymerization of the macrocyclic oligomers so produced

  2005cited by this paper
• Macrolactones and polyesters from ricinoleic acid.

  2005cited by this paper
• Lipase-catalyzed transformation of poly(lactic acid) into cyclic oligomers.

  2004cited by this paper
• Transformation of biodegradable polyesters into cyclic oligomers under continuous flow using an enzyme-packed column.

  2004cited by this paper
• Spontaneous Ring‐Opening Polymerization of Macrocyclic Aromatic Thioether Ketones under Transient High‐Temperature Conditions

  2004cited by this paper
• Cyclo-depolymerisations of polyurethanes to give macrocyclic oligomers: entropically driven ring-opening polymerisations of the macrocyclic oligomers produced

  2004cited by this paper
• A New Synthetic Route to Poly[3-hydroxypropionic acid] (P[3-HP]): Ring-Opening Polymerization of 3-HP Macrocyclic Esters

  2004cited by this paper
• Rapid, Uncatalyzed Ring-Opening Polymerization of Individual Macrocyclic Poly(arylene thioether ketone)s under Dynamic Heating Conditions

  2004cited by this paper
• Isotactic Polymers with Alternating Lactic Acid and Oxetane Subunits from the Endoentropic Polymerization of a 14-Membered Ring

  2004cited by this paper
• Ring-Opening Polymerization of the Cyclic Ester Amide Derived from Adipic Anhydride and 1-Amino-5-pentanol

  2003cited by this paper
• Microfabrication of high-performance aromatic polymers as nanotubes or fibrils by in situ ring-opening polymerisation of macrocyclic precursors

  2003cited by this paper
• Recent developments in ring opening polymerization of lactones for biomedical applications.

  2003cited by this paper
• Regioselective enzyme-catalyzed synthesis of sophorolipid esters, amides, and multifunctional monomers.

  2003cited by this paper
• Lipase-catalyzed transformation of poly(butylene adipate) and poly(butylene succinate) into repolymerizable cyclic oligomers.

  2003cited by this paper
• Entropically driven ring-opening-metathesis polymerization of macrocyclic olefins with 21-84 ring atoms.

  2003cited by this paper
• Synthesis of cyclic polybutadiene via ring-opening metathesis polymerization: the importance of removing trace linear contaminants.

  2003cited by this paper
• A new method for the polymer-supported synthesis of cyclic oligoesters for potential applications in macrocyclic lactone synthesis and combinatorial chemistry

  2002cited by this paper
• Kinetics of the Ring-Opening Polymerization of 6-, 7-, 9-, 12-, 13-, 16-, and 17-Membered Lactones. Comparison of Chemical and Enzymatic Polymerizations

  2002cited by this paper
• Ring-chain interconversion in high-performance polymer systems. 1. [Poly(oxy-4,4'-biphenyleneoxy-1,4-phenylenesulfonyl-1,4-phenylene)] (Radel-R)

  2002cited by this paper
• Controlled Ring-Opening Polymerization: Polymers with designed Macromolecular Architecture

  2002cited by this paper
• Unexpected entropy-driven ring-opening polymerization in a reversible supramolecular system.

  2001cited by this paper
• Polyester and polycarbonate synthesis by in vitro enzyme catalysis

  2001cited by this paper
• Mechanism and activity of ruthenium olefin metathesis catalysts.

  2001cited by this paper
• Synthesis of cocyclic(arylene disulfide) oligomers and their adhesion properties as heating-melt adhesive

  2001cited by this paper
• Concave 1,10-Phenanthrolines by Ring-Closing Metathesis

  2001cited by this paper
• Polymer synthesis by in vitro enzyme catalysis.

  2001cited by this paper
• Efficient Ring-Opening Polymerization and Copolymerization of ε-Caprolactone and ω-Pentadecalactone Catalyzed by Candida antartica Lipase B

  2000cited by this paper
• Highly Efficient Ring-Opening Metathesis Polymerization (ROMP) Using New Ruthenium Catalysts Containing N-Heterocyclic Carbene Ligands C.B. is grateful to the National Science Foundation for a pre-doctoral fellowship. The authors thank Dr. Matthias Scholl for providing catalysts 4 a and 4 c.

  2000cited by this paper
• Lipase-Catalyzed Synthesis of Aliphatic Polyesters by Polycondensation of Dicarboxylic Acids and Glycols in Solvent-Free System

  2000cited by this paper
• Synthesis and activity of a new generation of ruthenium-based olefin metathesis catalysts coordinated with 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ligands.

  1999cited by this paper
• Quantitative description of the metathesis polymerization/depolymerization equilibrium in the 1,4‐polybutadiene system, 1. Influence of feed concentration and temperature

  1999cited by this paper
• Recent research on the synthesis and applications of cyclic oligomers

  1999cited by this paper
• Ring-Opening Copolymerization of (R)-β-Butyrolactone with Macrolide: A New Series of Poly(Hydroxyalkanoate)s

  1999cited by this paper
• Synthesis of Functionalized Polyethers by Ring-Opening Metathesis Polymerization of Unsaturated Crown Ethers

  1999cited by this paper
• Synthesis, characterization, and ring-opening polymerization of the cyclic oligomers of poly(oxy-1,3-phenylenecarbonyl-1,4-phenylene)

  1998cited by this paper
• Cyclodepolymerisation of bisphenol A polysulfone: evidence for self-complementarity in macrocyclic poly(ether sulfones)

  1998cited by this paper
• Lipase-catalyzed ring-opening polymerization of 16-hexadecanolide

  1998cited by this paper
• Synthesis and ring-opening polymerization of single-sized aromatic macrocycles for poly(arylene ether)s

  1997cited by this paper
• A macrocyclic aromatic thioether ketone: synthesis, structure and anionic ring-opening polymerisation

  1997cited by this paper
• Template-Directed Ring-Closing Metathesis: Synthesis and Polymerization of Unsaturated Crown Ether Analogs†

  1997cited by this paper
• Enzyme-Catalyzed Ring-Opening Polymerization of ω-Pentadecalactone†

  1997cited by this paper
• Lipase-Catalyzed Polyester Synthesis in Organic Medium. Study of Ring−Chain Equilibrium

  1997cited by this paper
• Enzymes in polymer chemistry, 9. Polymerizable oligoesters from cholic acid via lipase catalyzed condensation reactions†

  1996cited by this paper
• Large-Sized Macrocyclic Monomeric Precursors of Poly(ether ether ketone): Synthesis and Polymerization

  1996cited by this paper
• Free-Radical Ring-Opening Polymerization of Macrocyclic Aryl Ether Thioether Ketone Oligomers

  1996cited by this paper
• Synthesis and Ring-Opening Polymerization of Poly(alkylene 2,6-naphthalenedicarboxylate) Cyclic Oligomers

  1996cited by this paper
• Ring‐opening polymerization of macrocyclic aryl ether ketone oligomers containing the 1,2‐dibenzoylbenzene moiety

  1996cited by this paper
• Modeling Ring-Chain Equilibria in Ring-Opening Polymerization of Cycloolefins

  1995cited by this paper
• Lipase-Catalyzed Ring-Opening Polymerization of 12-Dodecanolide

  1995cited by this paper
• Synthesis and Novel Free-Radical Ring-Opening Polymerization of Macrocyclic Oligomers Containing an Aromatic Sulfide Linkage

  1995cited by this paper
• Anionic ring-opening polymerization of macrocyclic esters

  1994cited by this paper
• Macrocyclization under thermodynamic control. A theoretical study and its application to the equilibrium cyclooligomerization of .beta.-propiolactone

  1993cited by this paper
• Preparation and polymerization of bisphenol A cyclic oligomeric carbonates

  1991cited by this paper
• Kinetics and thermodynamics of the metathesis reaction of cycloolefins. 2. Molecular weight distribution

  1984cited by this paper
• Ring-closure reactions. 11. The activation parameters for the formation of four- to six-membered lactones from .omega.-bromoalkanoate ions. The role of the entropy factor in small- and common-ring formation

  1978cited by this paper
• Ring-closure reactions. 7. Kinetics and activation parameters of lactone formation in the range of 3- to 23-membered rings

  1977cited by this paper
• Ring-closure reactions. I. Kinetics of lactone formation in the range of seven- to twelve-membered rings

  1973cited by this paper
• The structures and reversible polymerization of cyclic oligomers from poly(ethylene terephthalate)

  1960cited by this paper
• Intramolecular Reaction in Polycondensations. I. The Theory of Linear Systems

  1950cited by this paper
• Studies of Polymerization and Ring Formation. XX. Many-Membered Cyclic Esters

  1933cited by this paper

• Lifecycle of dynamic covalent polar-olefin macrocycles via entropy-driven ring-opening polymerization and closed-loop chemical recycling

  2025cites this paper
• Recent Advances in Ring-Opening Metathesis Polymerizations

  2025cites this paper
• Advances in metallopolymers: Synthesis strategies, catalytic insights, and environmental remediation applications

  2024cites this paper
• Design of Depolymerizable Polymers toward a Circular Economy

  2024influential citation
• Heteroatom-containing degradable polymers by ring-opening metathesis polymerization

  2023cites this paper
• Correlation between Polymerization Rate, Mechanism, and Conformer Thermodynamic Stability in Urea/Methoxide-Catalyzed Polymerization of Macrocyclic Carbonates

  2023cites this paper
• Mechanism and kinetics of melt transesterification with siloxane diol

  2022cites this paper
• Simple and General Approach for Reversible Condensation Polymerization with Cyclization

  2021cites this paper
• Polyaryletherketone (PAEK) thermoplastic composites via in-situ ring opening polymerisation

  2021cites this paper
• Catalytic methods for chemical recycling or upcycling of commercial polymers.

  2021cites this paper
• ED-ROP of macrocyclic oligomers: A synthetic tool for multicomponent polymer materials

  2021cites this paper
• Porphyrin-Based Polyesters Synthesized by Enzymatic Catalysis

  2021cites this paper
• Controlled Ring-Opening Polymerization of Macrocyclic Monomers Based on the Quinone Methide Elimination Cascade Reaction

  2021cites this paper
• Synthetic Approaches to Combine the Versatility of the Thiol Chemistry with the Degradability of Aliphatic Polyesters

  2020cites this paper
• Synthesis of bio-based polymacrolactones with pendant eugenol moieties as novel antimicrobial thermoplastic materials

  2020cites this paper
• Ring opening polymerization of macrocyclic oligoesters derived from renewable sources

  2020cites this paper
• Tuning the thermal properties of poly(ethylene)‐like poly(esters) by copolymerization of ε‐caprolactone with macrolactones, in the presence of a pyridylamidozinc(II) complex

  2020cites this paper
• Organocatalytic ring-opening polymerization of disulfide functional macrocyclic carbonates: An alternative strategy to enzymatic catalysis

  2020cites this paper
• High Glass-Transition Temperature Polymer Networks harnessing the Dynamic Ring Opening of Pinacol Boronates.

  2019cites this paper
• Homo‐ and random copolymerizations of ω‐pentadecalactone with ε‐caprolactone using isothiourea‐based dual catalysis

  2019cites this paper
• Alternating Sequence Control for Poly(ester amide)s by Organocatalyzed Ring-Opening Polymerization.

  2019cites this paper
• Sequence-Controlled Polymers Through Entropy-Driven Ring-Opening Metathesis Polymerization: Theory, Molecular Weight Control, and Monomer Design.

  2019cites this paper
• Synthesis, characterization and nanoaggregates of alkyl and triethylene glycol substituted 3,6-carbazolevinylenes homopolymers and block copolymers

  2019cites this paper
• Dynamic Networks High Glass-Transition Temperature Polymer Networks Harnessing the Dynamic Ring Opening of Pinacol Boronates

  2019cites this paper
• Recent developments in entropy‐driven ring‐opening metathesis polymerization: Mechanistic considerations, unique functionality, and sequence control

  2019cites this paper
• Empowering mechanochemistry with multi-mechanophore polymer architectures

  2018cites this paper
• Partially Renewable Poly(butylene 2,5-furandicarboxylate-co-isophthalate) Copolyesters Obtained by ROP

  2018cites this paper
• Polypentenamer Renaissance: Challenges and Opportunities.

  2018cites this paper
• Ring opening polymerization of macrolactones: high conversions and activities using an yttrium catalyst

  2017cites this paper
• Biodegradable polyester shape memory polymers: Recent advances in design, material properties and applications.

  2017cites this paper
• No Strain, No Gain? Enzymatic Ring-Opening Polymerization of Strainless Aliphatic Macrolactones.

  2017cites this paper
• Ring-opening polymerization of ω-pentadecalactone catalyzed by phosphazene superbases

  2017cites this paper
• Catalysis as an Enabling Science for Sustainable Polymers.

  2017cites this paper
• Two-Step Enzymatic Synthesis of Biocompatible Polymers Made from Cholic Acid

  2017cites this paper
• Aluminum Alkyl Complexes Bearing Salicylaldiminato Ligands : Versatile Initiators in the Ring-Opening Polymerization of Cyclic Esters

  2017cites this paper
• Fully bio-based aromatic–aliphatic copolyesters: poly(butylene furandicarboxylate-co-succinate)s obtained by ring opening polymerization

  2017cites this paper
• An entropy-driven ring-opening metathesis polymerization approach towards main-chain liquid crystalline polymers

  2016cites this paper
• Anionic ring-opening polymerization of cyclic 1,3-dithiocarbonate and thermal depolymerization

  2016cites this paper
• Synthesis of poly(ω‐pentadecalactone)‐b‐poly(acrylate) diblock copolymers via a combination of enzymatic ring‐opening and RAFT polymerization techniques

  2016cites this paper
• An aromatic/aliphatic polyester prepared via ring-opening polymerisation and its remarkably selective and cyclable depolymerisation to monomer

  2016cites this paper
• Recent Developments and Optimization of Lipase-Catalyzed Lactone Formation and Ring-Opening Polymerization.

  2016cites this paper
• Biodegradable shape-memory polymers for biomedical applications

  2015cites this paper
• Sequence-Controlled Copolymers Prepared via Entropy-Driven Ring-Opening Metathesis Polymerization.

  2015cites this paper
• Force-rate characterization of two spiropyran-based molecular force probes.

  2015cites this paper
• Entropically-driven ring-opening metathesis polymerization (ED-ROMP) of macrocyclic olefins prepared from deoxycholic acid to give functionalized polymers

  2015cites this paper
• Enzymatic reactive extrusion: moving towards continuous enzyme-catalysed polyester polymerisation and processing

  2015cites this paper
• A novel tin-based imidazolium-modified montmorillonite catalyst for the preparation of poly(butylene terephthalate)-based nanocomposites using in situ entropically-driven ring-opening polymerization

  2015cites this paper
• Ring-opening polymerization of ω-6-hexadecenlactone by a salicylaldiminato aluminum complex: a route to semicrystalline and functional poly(ester)s

  2015cites this paper
• The use of polymer-supported Candida antarctica lipase B to achieve the entropically-driven ring-opening polymerization of macrocyclic bile acid derivatives via transesterification: selectivity of the reactions and the structures of the polymers produced

  2015cites this paper
• Magnesium and Calcium Complexes in Homogeneous Catalysis

  2015cites this paper
• Entropically driven ring-opening polymerization of strainless organic macrocycles.

  2014cites this paper
• Self-Assembly and Ring-Opening Metathesis Polymerization of a Bifunctional Carbonate-Stilbene Macrocycle

  2014cites this paper
• Preparation and properties of high performance phthalide‐containing bismaleimide reinforced polydicyclopentadiene

  2014cites this paper
• Cyclodepolymerization as a method for the synthesis of macrocyclic oligomers

  2014cites this paper
• Preparation and properties of cyclopentadiene-containing monomer modified polydicyclopentadiene

  2014cites this paper
• Ring-Opening Metathesis Polymerization of a Naturally Derived Macrocyclic Glycolipid

  2013cites this paper
• Synthesis and anionic ring-opening polymerization of crown-ether-like macrocyclic dilactones: An alternative route to PEG-containing polyesters and related networks

  2013cites this paper
• Ring-opening polymerization of bile acid macrocycles by Candida antarctica lipase B

  2013cites this paper
• Living lamellar crystal initiating polymerization and brittleness mechanism investigations based on crystallization during the ring-opening of cyclic butylene terephthalate oligomers

  2013cites this paper
• Ring-opening metathesis polymerization with the second generation Hoveyda-Grubbs catalyst: an efficient approach toward high-purity functionalized macrocyclic oligo(cyclooctene)s.

  2013cites this paper
• Cyclo-depolymerizations of polycarbonates in solution: Use of the macrocyclic oligomers obtained in entropically-driven ring-opening polymerizations and copolymerizations to give carbonate–carbonate and carbonate–carboxylate ester copolymers

  2012cites this paper
• ω-Pentandecalactone Polymerization and ω-Pentadecalactone/ε-Caprolactone Copolymerization Reactions Using Organic Catalysts

  2012cites this paper
• Recent advances in metallo/organo-catalyzed immortal ring-opening polymerization of cyclic carbonates

  2012cites this paper
• Catalytic Ring-Opening Polymerization of Renewable Macrolactones to High Molecular Weight Polyethylene-like Polymers

  2011cites this paper
• Dithioacetal Polymers Capable of Chemical Recycling to Macrocyclic Monomers and Formation of Vitrimers

  year unknowncites this paper