{"corpus_id":146764890,"paper_sha":"8ee2aaf4533796096d4b4719d90266f69576c38c","doi":"10.1021/ACSENERGYLETT.9B00495","arxiv_id":null,"pmid":null,"pmcid":null,"mag_id":2939550032,"dblp_id":null,"acl_id":null,"title":"Determining and Minimizing Resistance for Ion Transport at the Polymer/Ceramic Electrolyte Interface","year":2019,"publication_date":"2019-04-17","venue":"ACS Energy Letters","journal":{"name":"ACS Energy Letters","pages":null,"volume":null},"journal_issn":null,"journal_title":null,"publication_types":[],"pubmed_pub_types":null,"s2_fields_of_study":["Materials Science","Chemistry","Engineering"],"reference_count":29,"citation_count":64,"influential_citation_count":0,"is_open_access":false,"arxiv_categories":null,"arxiv_license":null,"arxiv_journal_ref":null,"mesh_headings":null,"chemicals":null,"comments_corrections":null,"source_flags":1,"s2_open_access_pdf_url":null,"s2_open_access_landing_url":null,"s2_open_access_license":null,"s2_open_access_status":null,"pmc_open_access_pdf_url":null,"pmc_open_access_landing_url":null,"pmc_open_access_license":null,"pmc_open_access_status":null,"unpaywall_open_access_pdf_url":null,"unpaywall_open_access_landing_url":null,"unpaywall_open_access_license":null,"unpaywall_open_access_status":null,"abstract":"In this work, we report methods to quantify and minimize the interfacial resistance for Li ion transport, Rinterface, between a model polymer electrolyte, poly(ethylene oxide) + LiCF3SO3 (PE), and a model Li+-conducting ceramic electrolyte, LICGC from Ohara Corporation. By constructing a PE–ceramic–PE trilayer cell, we found Rinterface to be very large, 1.2 kΩ·cm2 at 30 °C, accounting for 66% of the total trilayer cell resistance. When dimethyl carbonate, a loose-binding solvent of Li+, was introduced into the trilayer, Rinterface decreased to essentially zero. As a result, a composite electrolyte with carbonate plasticizers wherein 40 vol % ceramic particles were dispersed in the polymer showed extraordinary room-temperature conductivity of approximately 10–4 S/cm, 3 orders of magnitude higher than that of the dry composite electrolyte. This discovery can be used as guidance in designing composite electrolytes to achieve synergistic effects.","claims":[{"public_id":"cl_3695c08ab2d9916ed414901f0a08e62a","status":"active","text":"A composite electrolyte with carbonate plasticizers and 40 vol % ceramic particles dispersed in the polymer achieves room-temperature conductivity of approximately 10–4 S/cm, about 3 orders of magnitude higher than the dry composite electrolyte.","confidence":0.97,"contributors":[{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["extraction"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/claims/cl_3695c08ab2d9916ed414901f0a08e62a"},{"public_id":"cl_b6a0e097eba34872d04938aebc93eb1b","status":"active","text":"Introducing dimethyl carbonate into the trilayer reduces the interfacial resistance to essentially zero.","confidence":0.97,"contributors":[{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous 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