{"corpus_id":205369971,"paper_sha":"e897b84c2955cae52c8ce3d6763d4741d5a119eb","doi":"10.1002/anie.201204822","arxiv_id":null,"pmid":23208999,"pmcid":null,"mag_id":2116933801,"dblp_id":null,"acl_id":null,"title":"Catalytic asymmetric dearomatization reactions.","year":2012,"publication_date":"2012-12-14","venue":"Angewandte Chemie","journal":{"name":"Angewandte Chemie","pages":"\n          12662-86\n        ","volume":"51 51"},"journal_issn":null,"journal_title":null,"publication_types":["JournalArticle","Review"],"pubmed_pub_types":["Journal Article"],"s2_fields_of_study":["Medicine","Chemistry"],"reference_count":170,"citation_count":936,"influential_citation_count":0,"is_open_access":false,"arxiv_categories":null,"arxiv_license":null,"arxiv_journal_ref":null,"mesh_headings":null,"chemicals":null,"comments_corrections":null,"source_flags":5,"s2_open_access_pdf_url":null,"s2_open_access_landing_url":null,"s2_open_access_license":null,"s2_open_access_status":null,"pmc_open_access_pdf_url":null,"pmc_open_access_landing_url":null,"pmc_open_access_license":null,"pmc_open_access_status":null,"unpaywall_open_access_pdf_url":null,"unpaywall_open_access_landing_url":null,"unpaywall_open_access_license":null,"unpaywall_open_access_status":null,"abstract":"This Review summarizes the development of catalytic asymmetric dearomatization (CADA) reactions. The CADA reactions discussed herein include oxidative dearomatization reactions, dearomatization by Diels-Alder and related reactions, the alkylative dearomatization of electron-rich arenes, transition-metal-catalyzed dearomatization reactions, cascade sequences involving asymmetric dearomatization as the key step, and nucleophilic dearomatization reactions of pyridinium derivatives. Asymmetric dearomatization reactions with chiral auxiliaries and catalytic asymmetric reactions of dearomatized substrates are also briefly introduced. This Review intends to provide a concept for catalytic asymmetric dearomatization.","claims":[{"public_id":"cl_fe989ea2202fa76978289161a70568b8","status":"active","text":"A conceptual framework for catalytic asymmetric dearomatization is provided.","confidence":0.87,"contributors":[{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["extraction"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/claims/cl_fe989ea2202fa76978289161a70568b8"},{"public_id":"cl_7f205de8426288b7e977d970b8b159f4","status":"active","text":"Asymmetric dearomatization reactions with chiral auxiliaries and catalytic asymmetric reactions of dearomatized substrates are also briefly covered.","confidence":0.91,"contributors":[{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["extraction"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/claims/cl_7f205de8426288b7e977d970b8b159f4"},{"public_id":"cl_ce0e53bbce5362515c3ee37665a91f7e","status":"active","text":"Catalytic asymmetric dearomatization reactions are surveyed across oxidative dearomatization, Diels-Alder and related dearomatization reactions, alkylative dearomatization of electron-rich arenes, transition-metal-catalyzed dearomatization, cascade sequences featuring asymmetric dearomatization as the key step, and nucleophilic dearomatization of pyridinium derivatives.","confidence":0.98,"contributors":[{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["extraction"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/claims/cl_ce0e53bbce5362515c3ee37665a91f7e"}],"concepts":[{"public_id":"co_013390897785dec7834cb5233ab9825a","status":"active","name":"catalytic asymmetric dearomatization 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dearomatization reactions of pyridinium derivatives","description":"Dearomatization reactions of pyridinium derivatives initiated by nucleophilic attack.","types":["reaction class"],"aliases":[],"contributors":[{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["extraction"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/concepts/co_0db92f78ce319562332596cb9fac0523"},{"public_id":"co_26d5883da393e9a04cc0117b5f9f73dd","status":"active","name":"dearomatization by Diels-Alder and related reactions","description":"Dearomatization reactions that proceed through Diels-Alder cycloaddition or related pericyclic processes.","types":["reaction class"],"aliases":[],"contributors":[{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous 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