{"corpus_id":214319104,"paper_sha":"79ceefb7faa2276051bf2d7af1a632b65edbc8c1","doi":"10.1016/j.ccr.2019.213115","arxiv_id":null,"pmid":null,"pmcid":null,"mag_id":2990196510,"dblp_id":null,"acl_id":null,"title":"Hidden ligand noninnocence: A combined spectroscopic and computational perspective","year":2020,"publication_date":"2020-02-15","venue":"","journal":{"name":"Coordination Chemistry Reviews","pages":"213115","volume":"405"},"journal_issn":null,"journal_title":null,"publication_types":[],"pubmed_pub_types":null,"s2_fields_of_study":["Chemistry"],"reference_count":88,"citation_count":19,"influential_citation_count":0,"is_open_access":false,"arxiv_categories":null,"arxiv_license":null,"arxiv_journal_ref":null,"mesh_headings":null,"chemicals":null,"comments_corrections":null,"source_flags":1,"s2_open_access_pdf_url":null,"s2_open_access_landing_url":null,"s2_open_access_license":null,"s2_open_access_status":null,"pmc_open_access_pdf_url":null,"pmc_open_access_landing_url":null,"pmc_open_access_license":null,"pmc_open_access_status":null,"unpaywall_open_access_pdf_url":null,"unpaywall_open_access_landing_url":null,"unpaywall_open_access_license":null,"unpaywall_open_access_status":null,"abstract":"Abstract Ligand noninnocence has been well-established for transition metal complexes containing diatomics such as NO and O2, and bidentate chelates like quinones/semiquinones/catecholates, α-diimines, and α-dithiolenes and also tetrapyrrole macrocycles. The scope of noninnocent ligands is being expanded rapidly for their unique redox properties and catalytic applications. The present contribution attempts to reveal “hidden” noninnocence of molecules that are often believed to be innocent, which includes 1,3-butadiene dianion, carbodicarbene and peroxo ligand, as well as reductive noninnocence of porphyrins and corroles.","claims":[{"public_id":"cl_07573d516dca3f44022e32e7ac4844ec","status":"active","text":"A combined spectroscopic and computational perspective is used to assess the noninnocent behavior of these molecules.","confidence":0.88,"contributors":[{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["extraction"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/claims/cl_07573d516dca3f44022e32e7ac4844ec"},{"public_id":"cl_e76b7f32347d3036a49b8a4ee9afa469","status":"active","text":"Hidden noninnocence is proposed for 1,3-butadiene dianion, carbodicarbene, and peroxo ligand.","confidence":0.93,"contributors":[{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["extraction"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/claims/cl_e76b7f32347d3036a49b8a4ee9afa469"},{"public_id":"cl_fe36f50f1ddf477b4311d8704d785b2f","status":"active","text":"Porphyrins and corroles are discussed in terms of reductive noninnocence.","confidence":0.9,"contributors":[{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["extraction"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/claims/cl_fe36f50f1ddf477b4311d8704d785b2f"}],"concepts":[{"public_id":"co_2d4898d0c2ba18420f0fd0a9cadd7001","status":"active","name":"transition metal complexes","description":"Complexes of transition metals with ligands, used as the broader chemical context for ligand noninnocence.","types":["chemical system"],"aliases":[],"contributors":[{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous 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