{"corpus_id":23366788,"paper_sha":"6e535212ebb9948be36ac827d9a095ff136f4a7c","doi":"10.1021/ja0570032","arxiv_id":null,"pmid":16366539,"pmcid":null,"mag_id":null,"dblp_id":null,"acl_id":null,"title":"Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature.","year":2005,"publication_date":null,"venue":"Journal of the American Chemical Society","journal":{"name":"Journal of the American Chemical Society","pages":"\n          17998-9\n        ","volume":"127 51"},"journal_issn":null,"journal_title":null,"publication_types":["JournalArticle"],"pubmed_pub_types":["Journal Article"],"s2_fields_of_study":["Medicine","Materials Science","Chemistry"],"reference_count":0,"citation_count":1195,"influential_citation_count":33,"is_open_access":false,"arxiv_categories":null,"arxiv_license":null,"arxiv_journal_ref":null,"mesh_headings":null,"chemicals":null,"comments_corrections":null,"source_flags":5,"s2_open_access_pdf_url":null,"s2_open_access_landing_url":null,"s2_open_access_license":null,"s2_open_access_status":null,"pmc_open_access_pdf_url":null,"pmc_open_access_landing_url":null,"pmc_open_access_license":null,"pmc_open_access_status":null,"unpaywall_open_access_pdf_url":null,"unpaywall_open_access_landing_url":null,"unpaywall_open_access_license":null,"unpaywall_open_access_status":null,"abstract":"Metal-organic frameworks (MOFs) show high CO2 storage capacity at room temperature. Gravimetric CO2 isotherms for MOF-2, MOF-505, Cu3(BTC)2, MOF-74, IRMOFs-11, -3, -6, and -1, and MOF-177 are reported up to 42 bar. Type I isotherms are found in all cases except for MOFs based on Zn4O(O2C)6 clusters, which reveal a sigmoidal isotherm (having a step). The various pressures of the isotherm steps correlate with increasing pore size, which indicates potential for gas separations. The amine functionality of the IRMOF-3 pore shows evidence of relatively increased affinity for CO2. Capacities qualitatively scale with surface area and range from 3.2 mmol/g for MOF-2 to 33.5 mmol/g (320 cm3(STP)/cm3, 147 wt %) for MOF-177, the highest CO2 capacity of any porous material reported.","claims":[{"public_id":"cl_4afd254b2e367843d4b8a6a569c19014","status":"active","text":"CO2 storage capacity scales qualitatively with surface area and reaches 33.5 mmol/g for MOF-177, the highest carbon dioxide capacity reported for any porous material.","confidence":0.98,"contributors":[{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["extraction"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/claims/cl_4afd254b2e367843d4b8a6a569c19014"},{"public_id":"cl_91c3c2488dcfbcce5a5b22a7ae28645d","status":"active","text":"Gravimetric carbon dioxide isotherms were measured for eight metal-organic frameworks up to 42 bar at room temperature.","confidence":0.98,"contributors":[{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous 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