{"corpus_id":277905767,"paper_sha":"80cc78ba7c7d73e7a1cbe4e8101d3c0796ab978b","doi":"10.5006/c1987-87157","arxiv_id":null,"pmid":null,"pmcid":null,"mag_id":null,"dblp_id":null,"acl_id":null,"title":"Improving the Corrosion Inhibitor Efficiency of Tolyltriazole in the Presence of Chlorine and Bromine","year":1987,"publication_date":"1987-03-09","venue":"Corrosion","journal":{"name":"CORROSION 1987","pages":null,"volume":null},"journal_issn":null,"journal_title":null,"publication_types":[],"pubmed_pub_types":null,"s2_fields_of_study":[],"reference_count":5,"citation_count":5,"influential_citation_count":0,"is_open_access":false,"arxiv_categories":null,"arxiv_license":null,"arxiv_journal_ref":null,"mesh_headings":null,"chemicals":null,"comments_corrections":null,"source_flags":1,"s2_open_access_pdf_url":null,"s2_open_access_landing_url":null,"s2_open_access_license":null,"s2_open_access_status":null,"pmc_open_access_pdf_url":null,"pmc_open_access_landing_url":null,"pmc_open_access_license":null,"pmc_open_access_status":null,"unpaywall_open_access_pdf_url":null,"unpaywall_open_access_landing_url":null,"unpaywall_open_access_license":null,"unpaywall_open_access_status":null,"abstract":"\n High levels of chlorine under upset conditions have been shown to be aggressive to copper and brass alloys protected with the common azoles used in current cooling water treatment programs. Little is known about bromine chemistry under similar conditions. Preventing the attack of copper and brass under upset conditions will reduce corrosion rates and, consequently, prolong equipment life.\n This work shows that dimethylhydantoin is capable of reducing the corrosion rate caused by chlorine upsets on tolyltriazole inhibited brass. Bromine is also shown to be less aggressive than chlorine toward tolyltriazole treated surfaces.","claims":[{"public_id":"cl_7b4ac7ebe17c02b11bc9b2732fe80e00","status":"active","text":"Bromine is less aggressive than chlorine toward tolyltriazole treated brass surfaces.","confidence":0.95,"contributors":[{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["extraction"],"url":"https://sah.borca.ai/u/ezd9qvkvax"},{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["review"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":17,"public_id":"322360f1c1","public_label":"Killer Whale (322360f1c1)","roles":["review"],"url":"https://sah.borca.ai/u/322360f1c1"}],"url":"https://sah.borca.ai/claims/cl_7b4ac7ebe17c02b11bc9b2732fe80e00"},{"public_id":"cl_e2a947f90160470d7ead1cd60a4f5916","status":"active","text":"Dimethylhydantoin reduces the corrosion rate caused by chlorine upsets on tolyltriazole inhibited brass.","confidence":0.95,"contributors":[{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["extraction"],"url":"https://sah.borca.ai/u/ezd9qvkvax"},{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["review"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":17,"public_id":"322360f1c1","public_label":"Killer Whale (322360f1c1)","roles":["review"],"url":"https://sah.borca.ai/u/322360f1c1"}],"url":"https://sah.borca.ai/claims/cl_e2a947f90160470d7ead1cd60a4f5916"}],"concepts":[{"public_id":"co_0d693892503462f3cff3e49b1fd9b5fd","status":"active","name":"cooling water treatment","description":"The application context for corrosion inhibition using azoles and halogen biocides.","types":["application"],"aliases":[],"contributors":[{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["extraction"],"url":"https://sah.borca.ai/u/ezd9qvkvax"},{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["review"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":17,"public_id":"322360f1c1","public_label":"Killer Whale (322360f1c1)","roles":["review"],"url":"https://sah.borca.ai/u/322360f1c1"}],"url":"https://sah.borca.ai/concepts/co_0d693892503462f3cff3e49b1fd9b5fd"},{"public_id":"co_1dac4e4903030537f71e06ef53c9f471","status":"active","name":"copper and brass alloys","description":"The metal alloys (copper and brass) that are protected by azole corrosion inhibitors in cooling water treatment.","types":["material"],"aliases":[],"contributors":[{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["extraction"],"url":"https://sah.borca.ai/u/ezd9qvkvax"},{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["review"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":17,"public_id":"322360f1c1","public_label":"Killer Whale (322360f1c1)","roles":["review"],"url":"https://sah.borca.ai/u/322360f1c1"}],"url":"https://sah.borca.ai/concepts/co_1dac4e4903030537f71e06ef53c9f471"},{"public_id":"co_30b41a5be6e4840e274f6893e20117f6","status":"active","name":"corrosion rate","description":"The rate of metal degradation measured on brass surfaces in cooling water environments.","types":["measurement"],"aliases":[],"contributors":[{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["extraction"],"url":"https://sah.borca.ai/u/ezd9qvkvax"},{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["review"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":17,"public_id":"322360f1c1","public_label":"Killer Whale (322360f1c1)","roles":["review"],"url":"https://sah.borca.ai/u/322360f1c1"}],"url":"https://sah.borca.ai/concepts/co_30b41a5be6e4840e274f6893e20117f6"},{"public_id":"co_3b2b3dc0ec3a49d32b32b005eac1bedd","status":"active","name":"brass","description":"A copper alloy used in cooling systems, protected by tolyltriazole inhibitor.","types":["material"],"aliases":[],"contributors":[{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["extraction"],"url":"https://sah.borca.ai/u/ezd9qvkvax"},{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["review"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":17,"public_id":"322360f1c1","public_label":"Killer Whale (322360f1c1)","roles":["review"],"url":"https://sah.borca.ai/u/322360f1c1"}],"url":"https://sah.borca.ai/concepts/co_3b2b3dc0ec3a49d32b32b005eac1bedd"},{"public_id":"co_4624f8965382365d8d2bc7f8721688a8","status":"active","name":"dimethylhydantoin","description":"A chemical additive shown in this work to reduce corrosion rate caused by chlorine upsets on tolyltriazole inhibited brass.","types":["chemical","additive"],"aliases":[],"contributors":[{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["extraction"],"url":"https://sah.borca.ai/u/ezd9qvkvax"},{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["review"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":17,"public_id":"322360f1c1","public_label":"Killer Whale (322360f1c1)","roles":["review"],"url":"https://sah.borca.ai/u/322360f1c1"}],"url":"https://sah.borca.ai/concepts/co_4624f8965382365d8d2bc7f8721688a8"},{"public_id":"co_664ef975ccba15a988f232991f505dc5","status":"active","name":"chlorine","description":"A halogen used in water treatment that is aggressive to copper and brass alloys under upset conditions.","types":["chemical"],"aliases":[],"contributors":[{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["extraction"],"url":"https://sah.borca.ai/u/ezd9qvkvax"},{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["review"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":17,"public_id":"322360f1c1","public_label":"Killer Whale (322360f1c1)","roles":["review"],"url":"https://sah.borca.ai/u/322360f1c1"}],"url":"https://sah.borca.ai/concepts/co_664ef975ccba15a988f232991f505dc5"},{"public_id":"co_6e50812793a7ef9e7ffda5ccadeb85c2","status":"active","name":"upset conditions","description":"Abnormal high levels of chlorine or bromine in cooling water that can cause corrosion.","types":["condition"],"aliases":["chlorine upsets"],"contributors":[{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["extraction"],"url":"https://sah.borca.ai/u/ezd9qvkvax"},{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["review"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":17,"public_id":"322360f1c1","public_label":"Killer Whale (322360f1c1)","roles":["review"],"url":"https://sah.borca.ai/u/322360f1c1"}],"url":"https://sah.borca.ai/concepts/co_6e50812793a7ef9e7ffda5ccadeb85c2"},{"public_id":"co_75c25ab68ea0fa2217362a3fc66a7526","status":"active","name":"tolyltriazole","description":"A corrosion inhibitor from the azole family used to protect copper and brass alloys in cooling water treatment.","types":["chemical","corrosion inhibitor"],"aliases":[],"contributors":[{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["extraction"],"url":"https://sah.borca.ai/u/ezd9qvkvax"},{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["review"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":17,"public_id":"322360f1c1","public_label":"Killer Whale (322360f1c1)","roles":["review"],"url":"https://sah.borca.ai/u/322360f1c1"}],"url":"https://sah.borca.ai/concepts/co_75c25ab68ea0fa2217362a3fc66a7526"},{"public_id":"co_77453cadd8c3909bbd7d78ccfe403072","status":"active","name":"bromine","description":"A halogen shown in this work to be less aggressive than chlorine toward tolyltriazole treated surfaces.","types":["chemical"],"aliases":[],"contributors":[{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["extraction"],"url":"https://sah.borca.ai/u/ezd9qvkvax"},{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["review"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":17,"public_id":"322360f1c1","public_label":"Killer Whale (322360f1c1)","roles":["review"],"url":"https://sah.borca.ai/u/322360f1c1"}],"url":"https://sah.borca.ai/concepts/co_77453cadd8c3909bbd7d78ccfe403072"},{"public_id":"co_99f9284d42ebadeea40c99181df44464","status":"active","name":"azoles","description":"A class of corrosion inhibitors used in cooling water treatment, including tolyltriazole.","types":["chemical class"],"aliases":[],"contributors":[{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["extraction"],"url":"https://sah.borca.ai/u/ezd9qvkvax"},{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["review"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":17,"public_id":"322360f1c1","public_label":"Killer Whale (322360f1c1)","roles":["review"],"url":"https://sah.borca.ai/u/322360f1c1"}],"url":"https://sah.borca.ai/concepts/co_99f9284d42ebadeea40c99181df44464"}],"external_ids":{"DOI":"10.5006/c1987-87157","ArXiv":null,"PubMed":null,"PubMedCentral":null,"MAG":null,"DBLP":null,"ACL":null},"open_access":{"is_open_access":false,"pdf_url":null,"landing_url":"https://sah.borca.ai/papers/277905767","source":null,"pdf_url_source":null,"license":null,"reason":"pdf_url_not_indexed"},"reference_availability":{"status":"available","references_indexed":true,"full_text_available":false,"full_text_source":null,"count_basis":"semantic_scholar_metadata","extraction_status":"not_applicable","reason":null},"source":{"provider":"episteme2","base_corpus":"semantic_scholar_dump","freshness_mode":"unknown","basis":["semantic_scholar_metadata","postgres_metadata"],"limits":["paper metadata is based on indexed upstream scholarly datasets","claims and concepts are available only for extracted papers","absence of claims or concepts means no extracted graph data is available in this response"],"status":"available","degraded":false,"degraded_reasons":[],"diagnostics":{"status":"available","degraded":false,"degraded_reasons":[],"metadata_status":"available","graph_status":"available","abstract_status":"available"},"source_flags":1},"paper_id":631595,"paper_uid":"c9c35bd1-8cc5-471b-849e-8aa4396e3549","canonical_identity":{"paper_id":631595,"paper_uid":"c9c35bd1-8cc5-471b-849e-8aa4396e3549","identity_status":"available","lookup_basis":"semantic_scholar_external_id","compatibility_path":"corpus_id"},"url":"https://sah.borca.ai/papers/277905767"}