{"corpus_id":32319094,"paper_sha":"77c21d7fef4407e09476e5f63439d3abcd0810d7","doi":"10.1021/JA035851W","arxiv_id":null,"pmid":12862446,"pmcid":null,"mag_id":2051881105,"dblp_id":null,"acl_id":null,"title":"Rhodium-catalyzed enantioselective diboration of simple alkenes.","year":2003,"publication_date":"2003-06-26","venue":"Journal of the American Chemical Society","journal":{"name":"Journal of the American Chemical Society","pages":"\n          8702-3\n        ","volume":"125 29"},"journal_issn":null,"journal_title":null,"publication_types":["JournalArticle"],"pubmed_pub_types":["Journal Article","Research Support, Non-U.S. Gov't","Research Support, U.S. Gov't, P.H.S."],"s2_fields_of_study":["Medicine","Chemistry"],"reference_count":1,"citation_count":147,"influential_citation_count":0,"is_open_access":true,"arxiv_categories":null,"arxiv_license":null,"arxiv_journal_ref":null,"mesh_headings":[{"d":"Alcohols","mj":false,"qs":[{"q":"chemical synthesis","mj":true,"ui":"Q000138"}],"ui":"D000438"},{"d":"Alkenes","mj":false,"qs":[{"q":"chemistry","mj":true,"ui":"Q000737"}],"ui":"D000475"},{"d":"Boranes","mj":false,"qs":[{"q":"chemistry","mj":true,"ui":"Q000737"}],"ui":"D001880"},{"d":"Catalysis","mj":false,"ui":"D002384"},{"d":"Rhodium","mj":false,"qs":[{"q":"chemistry","mj":true,"ui":"Q000737"}],"ui":"D012238"},{"d":"Stereoisomerism","mj":false,"ui":"D013237"}],"chemicals":[{"n":"Alcohols","ui":"D000438","reg":"0"},{"n":"Alkenes","ui":"D000475","reg":"0"},{"n":"Boranes","ui":"D001880","reg":"0"},{"n":"Rhodium","ui":"D012238","reg":"DMK383DSAC"}],"comments_corrections":null,"source_flags":5,"s2_open_access_pdf_url":"https://figshare.com/articles/journal_contribution/Rhodium-Catalyzed_Enantioselective_Diboration_of_Simple_Alkenes/3652140/1/files/5741022.pdf","s2_open_access_landing_url":"https://www.semanticscholar.org/paper/77c21d7fef4407e09476e5f63439d3abcd0810d7","s2_open_access_license":"CCBYNC","s2_open_access_status":"GREEN","pmc_open_access_pdf_url":null,"pmc_open_access_landing_url":null,"pmc_open_access_license":null,"pmc_open_access_status":null,"unpaywall_open_access_pdf_url":null,"unpaywall_open_access_landing_url":null,"unpaywall_open_access_license":null,"unpaywall_open_access_status":null,"abstract":"Enantioselective catalytic reactions that operate directly on inexpensive unactivated alkenes are extraordinarily useful for the preparation of chiral organic building blocks and new materials. 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