{"corpus_id":45504545,"paper_sha":"3ca76e2f5d5bb8b220710ad75c5a6d917341a2e1","doi":"10.1021/jacs.7b05362","arxiv_id":null,"pmid":28650651,"pmcid":null,"mag_id":2722013064,"dblp_id":null,"acl_id":null,"title":"Tuning Selectivity of CO2 Hydrogenation Reactions at the Metal/Oxide Interface.","year":2017,"publication_date":"2017-07-06","venue":"Journal of the American Chemical Society","journal":{"name":"Journal of the American Chemical Society","pages":"\n          9739-9754\n        ","volume":"139 29"},"journal_issn":null,"journal_title":null,"publication_types":["JournalArticle"],"pubmed_pub_types":["Journal Article","Research Support, U.S. Gov't, Non-P.H.S."],"s2_fields_of_study":["Medicine","Materials Science","Chemistry","Environmental Science"],"reference_count":178,"citation_count":990,"influential_citation_count":8,"is_open_access":false,"arxiv_categories":null,"arxiv_license":null,"arxiv_journal_ref":null,"mesh_headings":null,"chemicals":null,"comments_corrections":null,"source_flags":5,"s2_open_access_pdf_url":null,"s2_open_access_landing_url":null,"s2_open_access_license":null,"s2_open_access_status":null,"pmc_open_access_pdf_url":null,"pmc_open_access_landing_url":null,"pmc_open_access_license":null,"pmc_open_access_status":null,"unpaywall_open_access_pdf_url":null,"unpaywall_open_access_landing_url":null,"unpaywall_open_access_license":null,"unpaywall_open_access_status":null,"abstract":"The chemical transformation of CO2 not only mitigates the anthropogenic CO2 emission into the Earth’s atmosphere but also produces carbon compounds that can be used as precursors for the production of chemicals and fuels. The activation and conversion of CO2 can be achieved on multifunctional catalytic sites available at the metal/oxide interface by taking advantage of the synergy between the metal nanoparticles and oxide support. Herein, we look at the recent progress in mechanistic studies of CO2 hydrogenation to C1 (CO, CH3OH, and CH4) compounds on metal/oxide catalysts. On this basis, we are able to provide a better understanding of the complex reaction network, grasp the capability of manipulating structure and combination of metal and oxide at the interface in tuning selectivity, and identify the key descriptors to control the activity and, in particular, the selectivity of catalysts. Finally, we also discuss challenges and future research opportunities for tuning the selective conversion of CO2 on metal/oxide catalysts.","claims":[{"public_id":"cl_1992a2d28040e04b8f86e18e652662b9","status":"active","text":"Key descriptors can be identified to control catalyst activity and especially selectivity in CO2 hydrogenation on metal/oxide catalysts.","confidence":0.78,"contributors":[{"id":136,"public_id":"3c2apqe3ut","public_label":"Anonymous (3c2apqe3ut)","roles":["extraction"],"url":"https://sah.borca.ai/u/3c2apqe3ut"},{"id":17,"public_id":"322360f1c1","public_label":"Killer Whale (322360f1c1)","roles":["review"],"url":"https://sah.borca.ai/u/322360f1c1"},{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["review"],"url":"https://sah.borca.ai/u/ezd9qvkvax"}],"url":"https://sah.borca.ai/claims/cl_1992a2d28040e04b8f86e18e652662b9"},{"public_id":"cl_5f3f386577bc61fb442ebb096755985f","status":"active","text":"Manipulating the structure and combination of metal and oxide at the interface can tune selectivity in CO2 hydrogenation to C1 compounds.","confidence":0.86,"contributors":[{"id":136,"public_id":"3c2apqe3ut","public_label":"Anonymous (3c2apqe3ut)","roles":["extraction"],"url":"https://sah.borca.ai/u/3c2apqe3ut"},{"id":17,"public_id":"322360f1c1","public_label":"Killer Whale (322360f1c1)","roles":["review"],"url":"https://sah.borca.ai/u/322360f1c1"},{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["review"],"url":"https://sah.borca.ai/u/ezd9qvkvax"}],"url":"https://sah.borca.ai/claims/cl_5f3f386577bc61fb442ebb096755985f"},{"public_id":"cl_be6257b174401f338e06725b590b55ec","status":"active","text":"Multifunctional catalytic sites at the metal/oxide interface can activate and convert CO2 through synergy between metal nanoparticles and oxide support.","confidence":0.84,"contributors":[{"id":136,"public_id":"3c2apqe3ut","public_label":"Anonymous 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