{"corpus_id":5522344,"paper_sha":"abc5b445f42f409bbcbd4e339b5b133897d85375","doi":"10.1021/cr900202j","arxiv_id":null,"pmid":19938813,"pmcid":null,"mag_id":2018014134,"dblp_id":null,"acl_id":null,"title":"Dehydrogenation as a substrate-activating strategy in homogeneous transition-metal catalysis.","year":2010,"publication_date":"2010-02-10","venue":"Chemical Reviews","journal":{"name":"Chemical reviews","pages":"\n          681-703\n        ","volume":"110 2"},"journal_issn":null,"journal_title":null,"publication_types":["Review","JournalArticle"],"pubmed_pub_types":["Journal Article","Research Support, Non-U.S. Gov't","Research Support, U.S. Gov't, Non-P.H.S.","Review"],"s2_fields_of_study":["Medicine","Chemistry"],"reference_count":0,"citation_count":1324,"influential_citation_count":1,"is_open_access":false,"arxiv_categories":null,"arxiv_license":null,"arxiv_journal_ref":null,"mesh_headings":[{"d":"Alcohols","mj":false,"qs":[{"q":"chemistry","mj":false,"ui":"Q000737"}],"ui":"D000438"},{"d":"Alkanes","mj":false,"qs":[{"q":"chemistry","mj":false,"ui":"Q000737"}],"ui":"D000473"},{"d":"Amination","mj":false,"ui":"D000586"},{"d":"Amines","mj":false,"qs":[{"q":"chemistry","mj":false,"ui":"Q000737"}],"ui":"D000588"},{"d":"Catalysis","mj":false,"ui":"D002384"},{"d":"Nitriles","mj":false,"qs":[{"q":"chemistry","mj":false,"ui":"Q000737"}],"ui":"D009570"},{"d":"Oxidation-Reduction","mj":false,"ui":"D010084"},{"d":"Transition Elements","mj":false,"qs":[{"q":"chemistry","mj":true,"ui":"Q000737"}],"ui":"D028561"}],"chemicals":[{"n":"Alcohols","ui":"D000438","reg":"0"},{"n":"Alkanes","ui":"D000473","reg":"0"},{"n":"Amines","ui":"D000588","reg":"0"},{"n":"Nitriles","ui":"D009570","reg":"0"},{"n":"Transition Elements","ui":"D028561","reg":"0"}],"comments_corrections":null,"source_flags":5,"s2_open_access_pdf_url":null,"s2_open_access_landing_url":null,"s2_open_access_license":null,"s2_open_access_status":null,"pmc_open_access_pdf_url":null,"pmc_open_access_landing_url":null,"pmc_open_access_license":null,"pmc_open_access_status":null,"unpaywall_open_access_pdf_url":null,"unpaywall_open_access_landing_url":null,"unpaywall_open_access_license":null,"unpaywall_open_access_status":null,"abstract":"ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTDehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal CatalysisGraham E. Dobereiner and Robert H. Crabtree*View Author Information Department of Chemistry, Yale University, 225 Prospect Street, New Haven, Connecticut 06520* To whom correspondence should be addressed. E-mail: [email protected]Cite this: Chem. Rev. 2010, 110, 2, 681–703Publication Date (Web):November 25, 2009Publication History Received21 May 2009Published online25 November 2009Published inissue 10 February 2010https://pubs.acs.org/doi/10.1021/cr900202jhttps://doi.org/10.1021/cr900202jreview-articleACS PublicationsCopyright © 2009 American Chemical SocietyRequest reuse permissionsArticle Views25264Altmetric-Citations1451LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. 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Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Alcohols,Amines,Catalysts,Hydrogen,Organic reactions Get e-Alerts","claims":[{"public_id":"cl_8c9fa6a9dcaf57708a6fc8df2cba2e58","status":"active","text":"Dehydrogenation is a substrate-activating strategy in homogeneous transition-metal catalysis.","confidence":0.95,"contributors":[{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["extraction"],"url":"https://sah.borca.ai/u/ezd9qvkvax"},{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["review"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["review"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/claims/cl_8c9fa6a9dcaf57708a6fc8df2cba2e58"}],"concepts":[{"public_id":"co_1a6750bed33463f0bd3e38210d88e65a","status":"active","name":"homogeneous transition-metal catalysis","description":"Catalysis where the catalyst and reactants are in the same phase and the catalyst is a transition metal complex.","types":["catalytic method","approach"],"aliases":[],"contributors":[{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["extraction"],"url":"https://sah.borca.ai/u/ezd9qvkvax"},{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["review"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["review"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/concepts/co_1a6750bed33463f0bd3e38210d88e65a"},{"public_id":"co_33c9529ab04fadb509e7bc1c15ae1538","status":"active","name":"dehydrogenation","description":"A chemical reaction that removes hydrogen atoms from a substrate.","types":["reaction"],"aliases":[],"contributors":[{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["extraction"],"url":"https://sah.borca.ai/u/ezd9qvkvax"},{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["review"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["review"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/concepts/co_33c9529ab04fadb509e7bc1c15ae1538"},{"public_id":"co_6f2552b58cc772208adef291a22e5e3c","status":"active","name":"substrate-activating strategy","description":"A strategy for activating a substrate by removing hydrogen, making it more reactive.","types":["strategy","approach"],"aliases":[],"contributors":[{"id":1165,"public_id":"ezd9qvkvax","public_label":"The Reverser‮ (ezd9qvkvax)","roles":["extraction"],"url":"https://sah.borca.ai/u/ezd9qvkvax"},{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["review"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["review"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/concepts/co_6f2552b58cc772208adef291a22e5e3c"}],"external_ids":{"DOI":"10.1021/cr900202j","ArXiv":null,"PubMed":19938813,"PubMedCentral":null,"MAG":2018014134,"DBLP":null,"ACL":null},"open_access":{"is_open_access":false,"pdf_url":null,"landing_url":"https://sah.borca.ai/papers/5522344","source":null,"pdf_url_source":null,"license":null,"reason":"pdf_url_not_indexed"},"reference_availability":{"status":"unknown","references_indexed":false,"full_text_available":false,"full_text_source":null,"count_basis":"semantic_scholar_metadata","extraction_status":"not_applicable","reason":null},"source":{"provider":"episteme2","base_corpus":"semantic_scholar_dump","freshness_mode":"unknown","basis":["semantic_scholar_metadata","postgres_metadata"],"limits":["paper metadata is based on indexed upstream scholarly datasets","claims and concepts are available only for extracted papers","absence of claims or concepts means no extracted graph data is available in this response"],"status":"available","degraded":false,"degraded_reasons":[],"diagnostics":{"status":"available","degraded":false,"degraded_reasons":[],"metadata_status":"available","graph_status":"available","abstract_status":"available"},"source_flags":5},"paper_id":631482,"paper_uid":"86cdbe94-d220-43a7-98f8-9ae16116e1fd","canonical_identity":{"paper_id":631482,"paper_uid":"86cdbe94-d220-43a7-98f8-9ae16116e1fd","identity_status":"available","lookup_basis":"semantic_scholar_external_id","compatibility_path":"corpus_id"},"url":"https://sah.borca.ai/papers/5522344"}