{"corpus_id":95140820,"paper_sha":"dd6a5e113cc6044ecea3910d83dc16d0cda022c4","doi":"10.1016/S0022-328X(00)00536-2","arxiv_id":null,"pmid":null,"pmcid":null,"mag_id":2014419848,"dblp_id":null,"acl_id":null,"title":"Transmetallations between aryltrialkyltins and borane: synthesis of arylboronic acids and organotin hydrides","year":2000,"publication_date":"2000-11-03","venue":"","journal":{"name":"Journal of Organometallic Chemistry","pages":"236-238","volume":"613"},"journal_issn":null,"journal_title":null,"publication_types":[],"pubmed_pub_types":null,"s2_fields_of_study":["Chemistry"],"reference_count":3,"citation_count":15,"influential_citation_count":0,"is_open_access":true,"arxiv_categories":null,"arxiv_license":null,"arxiv_journal_ref":null,"mesh_headings":null,"chemicals":null,"comments_corrections":null,"source_flags":1,"s2_open_access_pdf_url":"https://ri.conicet.gov.ar/bitstream/11336/129952/2/CONICET_Digital_Nro.7bf52d13-399c-41dc-986e-c03eb65a8f94_A.pdf","s2_open_access_landing_url":"https://www.semanticscholar.org/paper/dd6a5e113cc6044ecea3910d83dc16d0cda022c4","s2_open_access_license":"CCBYNCSA","s2_open_access_status":"GREEN","pmc_open_access_pdf_url":null,"pmc_open_access_landing_url":null,"pmc_open_access_license":null,"pmc_open_access_status":null,"unpaywall_open_access_pdf_url":null,"unpaywall_open_access_landing_url":null,"unpaywall_open_access_license":null,"unpaywall_open_access_status":null,"abstract":"Abstract Aryltrialkyltin compounds react with borane in THF to give mixtures of trialkyltin hydrides and arylboranes, which on hydrolysis give arylboronic acid in high yields. The arylboronic acids are easily separated and obtained free of organotins.","claims":[{"public_id":"cl_8212a4a44b64e33da63c2d75b8c47d9d","status":"active","text":"Aryltrialkyltin compounds react with borane in THF to give mixtures of trialkyltin hydrides and arylboranes, which on hydrolysis give arylboronic acids in high yields.","confidence":0.95,"contributors":[{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["extraction"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["review"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/claims/cl_8212a4a44b64e33da63c2d75b8c47d9d"},{"public_id":"cl_eaa047dc01fb7d774254ff2025fcaab2","status":"active","text":"The arylboronic acids are easily separated and obtained free of organotins.","confidence":0.9,"contributors":[{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["extraction"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["review"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/claims/cl_eaa047dc01fb7d774254ff2025fcaab2"}],"concepts":[{"public_id":"co_426925d6122e6ba2d61b891883711cb8","status":"active","name":"aryltrialkyltin compounds","description":"Organotin compounds with an aryl group and three alkyl groups attached to tin, used as reactants in the transmetallation.","types":["reactant"],"aliases":[],"contributors":[{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["extraction"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["review"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/concepts/co_426925d6122e6ba2d61b891883711cb8"},{"public_id":"co_6f47fb4b4d6bac22d170234609b03e72","status":"active","name":"arylboronic acids","description":"Boron-containing acids with an aryl substituent, obtained in high yields after hydrolysis of the arylborane intermediates.","types":["product"],"aliases":[],"contributors":[{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["extraction"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["review"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/concepts/co_6f47fb4b4d6bac22d170234609b03e72"},{"public_id":"co_82ddab23085bb502c45cfb1267c06240","status":"active","name":"trialkyltin hydrides","description":"Organotin hydride products formed from the transmetallation reaction, containing three alkyl groups and a hydrogen on tin.","types":["product"],"aliases":[],"contributors":[{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["extraction"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["review"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/concepts/co_82ddab23085bb502c45cfb1267c06240"},{"public_id":"co_cab02c7fc2eecb2188dd8492d977993e","status":"active","name":"arylboranes","description":"Boron intermediates produced from the transmetallation, which upon hydrolysis yield arylboronic acids.","types":["intermediate"],"aliases":[],"contributors":[{"id":2,"public_id":"4715169a40","public_label":"AK (4715169a40)","roles":["extraction"],"url":"https://sah.borca.ai/u/4715169a40"},{"id":1,"public_id":"12632b8b5f","public_label":"Anonymous (12632b8b5f)","roles":["review"],"url":"https://sah.borca.ai/u/12632b8b5f"}],"url":"https://sah.borca.ai/concepts/co_cab02c7fc2eecb2188dd8492d977993e"},{"public_id":"co_dcca056511d9729f16e2fc5799321205","status":"active","name":"organotins","description":"Organotin compounds present in the reaction mixture; 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