Reductive approach to nitrones from N-Siloxyamides and N-Hydroxyamides

No abstract is available for this paper.

• Publication year

  2017

• Venue

  Bulletin of the Chemical Society of Japan

• Publication date

  2017-05-09

• Fields of study

  Chemistry

• Identifiers
  DOI 10.1246/BCSJ.20170086
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Direct and Co‐catalytic Oxidation of Hydroxylamines to Nitrones Promoted by Rhodium Nanoparticles Supported on Carbon Nanotubes

  2017cited by this paper
• Iridium-Catalyzed Reductive Strecker Reaction for Late-Stage Amide and Lactam Cyanation.

  2017cited by this paper
• Total Synthesis of the Proposed Structure of Turkiyenine

  2016cited by this paper
• Chemoselective reductive alkynylation of tertiary amides by Ir and Cu(i) bis-metal sequential catalysis.

  2016cited by this paper
• Metal-Free C–H Alkyliminylation and Acylation of Alkenes with Secondary Amides

  2016cited by this paper
• Chemoselective Reduction of Tertiary Amides under Thermal Control: Formation of either Aldehydes or Amines.

  2016cited by this paper
• Catalytic Reductive ortho-C-H Silylation of Phenols with Traceless, Versatile Acetal Directing Groups and Synthetic Applications of Dioxasilines.

  2016cited by this paper
• Expeditious and Divergent Total Syntheses of Aspidosperma Alkaloids Exploiting Iridium(I)-Catalyzed Generation of Reactive Enamine Intermediates.

  2016cited by this paper
• Chemoselective reduction of carboxamides.

  2016cited by this paper
• An Iridium-Catalyzed Reductive Approach to Nitrones from N-Hydroxyamides.

  2016cited by this paper
• One-Pot Reductive 1,3-Dipolar Cycloaddition of Secondary Amides: A Two-Step Transformation of Primary Amides.

  2016cited by this paper
• Copper-catalyzed electrophilic amination using N-methoxyamines.

  2016cited by this paper
• Triphenylbismuth carbonate-mediated oxidation of hydroxylamines to nitrones and in situ 1,3-dipolar cycloaddition

  2016cited by this paper
• Formal [3+2] Cycloaddition of Nitrosoallenes with Carbonyl and Nitrile Compounds to Form Functional Cyclic Nitrones.

  2016cited by this paper
• Direct reductive coupling of secondary amides: chemoselective formation of vicinal diamines and vicinal amino alcohols.

  2015cited by this paper
• Iridium-catalyzed chemoselective reductive nucleophilic addition to N-methoxyamides.

  2015cited by this paper
• Total Syntheses of (±)-Gephyrotoxin and (±)-Perhydrogephyrotoxin

  2015cited by this paper
• Reductive arene ortho-silanolization of aromatic esters with hydridosilyl acetals.

  2015cited by this paper
• Formal Synthesis of Sarain A: Intramolecular Cycloaddition of an Eight-Membered Cyclic Nitrone to Construct the 2-Azabicyclo[3.3.1]nonane Framework.

  2015cited by this paper
• Synthesis of polyhydroxylated piperidine and pyrrolidine peptidomimetics via one-pot sequential lactam reduction/Joullié-Ugi reaction.

  2015cited by this paper
• Catalyst Design of Vaska-Type Iridium Complexes for Highly Efficient Synthesis of π-Conjugated Enamines

  2015cited by this paper
• Lewis Base Activation of Silyl Acetals: Iridium-Catalyzed Reductive Horner-Wadsworth-Emmons Olefination.

  2015cited by this paper
• A general method for the one-pot reductive functionalization of secondary amides.

  2015cited by this paper
• Two-step synthesis of multi-substituted amines by using an N-methoxy group as a reactivity control element.

  2014cited by this paper
• Tertiary amide-based Knoevenagel-type reactions: a direct, general, and chemoselective approach to enaminones.

  2014cited by this paper
• Total synthesis of (±)-gephyrotoxin by amide-selective reductive nucleophilic addition.

  2014cited by this paper
• Iridium-Catalyzed Reductive Nitro-Mannich Cyclization

  2014cited by this paper
• Ring‐Expanding Metathesis Oligomerization of Cyclic Nitrones

  2014cited by this paper
• Catalytic reductive dehydration of tertiary amides to enamines under hydrosilylation conditions.

  2014cited by this paper
• Catalytic enantioselective C-H functionalization of alcohols by redox-triggered carbonyl addition: borrowing hydrogen, returning carbon.

  2014cited by this paper
• Chemoselective reductive nucleophilic addition to tertiary amides, secondary amides, and N-methoxyamides.

  2014cited by this paper
• Increasing the Reactivity of Amides towards Organometallic Reagents: An Overview

  2014cited by this paper
• Nucleophilic addition to N-alkoxyamides.

  2014cited by this paper
• Enantioselective synthesis of alcohols and amines by iridium-catalyzed hydrogenation, transfer hydrogenation, and related processes.

  2013cited by this paper
• Direct nucleophilic addition to N-alkoxyamides.

  2013cited by this paper
• Direct transformation of amides into α-amino phosphonates via a reductive phosphination process.

  2013cited by this paper
• Indium triiodide catalyzed reductive functionalization of amides via the single-stage treatment of hydrosilanes and organosilicon nucleophiles.

  2013cited by this paper
• Total synthesis of (-)-nakadomarin A.

  2013cited by this paper
• Addition of organometallic reagents to chiral N-methoxylactams: enantioselective syntheses of pyrrolidines and piperidines.

  2013cited by this paper
• Chemoselective Activation Strategies of Amidic Carbonyls towards Nucleophilic Reagents

  2013cited by this paper
• General one-pot reductive gem-bis-alkylation of tertiary lactams/amides: rapid construction of 1-azaspirocycles and formal total synthesis of (±)-cephalotaxine.

  2013cited by this paper
• Recent Advances in Iridium-Catalyzed Alkylation of C–H and N–H Bonds

  2013cited by this paper
• Stereodivergent synthesis of piperidine alkaloids by ring-rearrangement metathesis/reductive lactam alkylation of nitroso Diels-Alder cycloadducts.

  2013cited by this paper
• Thioamides and Thioformamides for Sequential Reactions with Organolithium and Grignard Reagents

  2012cited by this paper
• A concise and versatile double-cyclization strategy for the highly stereoselective synthesis and arylative dimerization of Aspidosperma alkaloids.

  2012cited by this paper
• Direct chemoselective allylation of inert amide carbonyls.

  2012cited by this paper
• Iridium-catalyzed reduction of secondary amides to secondary amines and imines by diethylsilane.

  2012cited by this paper
• Versatile and Direct Transformation of Secondary Amides into Ketones by Deaminative Alkylation with Organocerium Reagents

  2012cited by this paper
• Chemoselective synthesis of ketones and ketimines by addition of organometallic reagents to secondary amides.

  2012cited by this paper
• Direct transformation of secondary amides into secondary amines: triflic anhydride activated reductive alkylation.

  2012cited by this paper
• Rapid assembly of quinolizidines via consecutive nucleophilic cyclizations onto activated amides.

  2011cited by this paper
• Regioselectivity of the borylation of alkanes and arenes.

  2011cited by this paper
• Molybdenum oxide/bipyridine hybrid material {[MoO3(bipy)][MoO3(H2O)]}n as catalyst for the oxidation of secondary amines to nitrones

  2011cited by this paper
• Enantioselective iridium-catalyzed allylic substitutions with hydroxamic acid derivatives as N-nucleophiles.

  2011cited by this paper
• Regio- and enantioselective allylic substitution with less active N- or O-nucleophiles catalyzed by iridium-complex of bis(oxazolinyl)pyridine.

  2011cited by this paper
• Stereodivergent synthesis of substituted N,O-containing bicyclic compounds by sequential addition of nucleophiles to N-alkoxybicyclolactams.

  2011cited by this paper
• Dehydrogenation and related reactions catalyzed by iridium pincer complexes.

  2011cited by this paper
• Generation of secondary, tertiary, and quaternary centers by geminal disubstitution of carbonyl oxygens.

  2011cited by this paper
• Stereodivergent synthesis of 1,3-syn- and -anti-tetrahydropyrimidinones.

  2010cited by this paper
• A direct entry to substituted N-methoxyamines from N-methoxyamides via N-oxyiminium ions.

  2010cited by this paper
• Recent progress in a chiral multinucleating system utilizing tartaric acid esters.

  2010cited by this paper
• Versatile one-pot reductive alkylation of lactams/amides via amide activation: application to the concise syntheses of bioactive alkaloids (±)-bgugaine, (±)-coniine, (+)-preussin, and (-)-cassine.

  2010cited by this paper
• Chemoselectivity and the curious reactivity preferences of functional groups.

  2010cited by this paper
• Mechanistically driven development of iridium catalysts for asymmetric allylic substitution.

  2010cited by this paper
• Highly efficient synthesis of aldenamines from carboxamides by iridium-catalyzed silane-reduction/dehydration under mild conditions.

  2009cited by this paper
• An Efficient Solvent-Free Route to Silyl Esters and Silyl Ethers

  2009cited by this paper
• A stereodivergent strategy to both product enantiomers from the same enantiomer of a stereoinducing catalyst: agelastatin A.

  2009cited by this paper
• Enantioselective iridium-catalyzed carbonyl allylation from the alcohol oxidation level via transfer hydrogenation: minimizing pre-activation for synthetic efficiency.

  2009cited by this paper
• Chemoselectivity: the mother of invention in total synthesis.

  2009cited by this paper
• Enantioselective copper-catalyzed 1,3-dipolar cycloadditions.

  2008cited by this paper
• Synthesis of Tertiary sec-Alkylamines by the Addition of Grignard Reagents to N,N-Dialkylformamides Mediated by Ti(OiPr)4 and Me3SiCl

  2008cited by this paper
• Mild catalytic oxidation of secondary and tertiary amines to nitrones and N-oxides with H2O2 mediated by Pt(II) catalysts

  2008cited by this paper
• Nitrile oxides, nitrones, and nitronates in organic synthesis : novel strategies in synthesis

  2007cited by this paper
• A rapid and simple cleanup procedure for metathesis reactions.

  2007cited by this paper
• Intramolecular 1,3‐Dipolar Cycloaddition Reactions in Targeted Syntheses.

  2007cited by this paper
• Mild and selective hydrozirconation of amides to aldehydes using Cp2Zr(H)Cl: scope and mechanistic insight.

  2007cited by this paper
• Total synthesis of rac-longamide B

  2007cited by this paper
• Three-component coupling reactions of thioformamides with organolithium and grignard reagents leading to formation of tertiary amines and a thiolating agent.

  2007cited by this paper
• Asymmetric 1,3-Dipolar Cycloadditions

  2007cited by this paper
• Total synthesis of the putative structure of stemonidine: the definitive proof of misassignment.

  2007cited by this paper
• Mild and efficient Lewis acid-promoted detritylation in the synthesis of N-hydroxy amides: a concise synthesis of (-)-Cobactin T.

  2007cited by this paper
• Asymmetric 1,3-Dipolar Cycloadditions of Cyclic Stabilized Ylides Derived from Chiral 1,2-Amino Alcohols

  2006cited by this paper
• New C-3' hydroxamate-substituted and more lipophilic cyclic hydroxamate cephalosporin derivatives as a potential new generation of selective antimicrobial agents.

  2006cited by this paper
• New class of nucleophiles for palladium-catalyzed asymmetric allylic alkylation. Total synthesis of agelastatin A.

  2006cited by this paper
• An Effective Use of Benzoic Anhydride and Its Derivatives for the Synthesis of Carboxylic Esters and Lactones-Powerful and Convenient Mixed Anhydride Methods Promoted by Lewis Acids or Basic Catalysts

  2005cited by this paper
• Regioselectively trisilylated hexopyranosides through homogeneously catalyzed silane alcoholysis.

  2005cited by this paper
• Synthesis of tertiary propargylamines by sequential reactions of in situ generated thioiminium salts with organolithium and -magnesium reagents.

  2004cited by this paper
• Utility of the iridium complex of the pybox ligand in regio- and enantioselective allylic substitution.

  2004cited by this paper
• A concise asymmetric synthesis of the marine hepatotoxin 7-epicylindrospermopsin.

  2004cited by this paper
• Cationic Iridium(I) Complexes as Catalysts for the Alcoholysis of Silanes

  2003cited by this paper
• Jüngste Entwicklungen bei der gekreuzten Olefinmetathese

  2003cited by this paper
• Recent developments in olefin cross-metathesis.

  2003cited by this paper
• A ‘waterproof’ catalyst for the oxidation of secondary amines to nitrones with alkyl hydroperoxides

  2003cited by this paper
• A novel and efficient macrolactonization of ω-hydroxycarboxylic acids using 2-methyl-6-nitrobenzoic anhydride (MNBA)

  2002cited by this paper
• Metal-Assisted Stereocontrol of 1,3-Dipolar Cycloaddition Reactions

  2002cited by this paper
• ChemInform Abstract: The Versatile Conversion of Acyclic Amides to α-Alkylated Amines.

  2002cited by this paper
• Asymmetric total synthesis of (-)-alpha-kainic acid using an enantioselective, metal-promoted ene cyclization.

  2001cited by this paper
• Transannular nitrone cycloaddition. A stereocontrolled entry to the spirocyclic core of pinnaic acid.

  2001cited by this paper
• New Applications of Polyfunctional Organometallic Compounds in Organic Synthesis Frequently used abbreviations are defined at the end of the article.

  2000cited by this paper
• A Novel and Expeditious Reduction of Tertiary Amides to Aldehydes Using Cp2Zr(H)Cl

  2000cited by this paper

• Natural Product Synthesis via Intramolecular Cycloaddition of Nitrogen-Containing 1,3-Dipoles

  2025cites this paper
• Intramolecular cycloaddition of nitrones in total synthesis of natural products.

  2025cites this paper
• Hetero Cope-Type Hydroamination of Hetero-Allenes with Oximes Having Olefin Moieties Leading to Nitrones, Causing Intramolecular Cycloaddition.

  2024cites this paper
• Five-Step Total Synthesis of (±)-Aspidospermidine by a Lactam Strategy via an Azomethine Ylide.

  2021cites this paper
• Bicyclic 5–6 systems with one bridgehead (ring junction) nitrogen atom: One extra heteroatom

  2021cites this paper
• Bicyclic 5-5 Systems With One Ring Junction Nitrogen Atom: One Extra Heteroatom 1:0

  2020cites this paper
• Recent topics of iridium-catalyzed hydrosilylation of tertiary amides to silylhemiaminals

  2020cites this paper
• Two-Step Catalytic Transformation of N -Benzyllactams to Alkaloids (±)-Solenopsin, (±)-Solenopsin A, and (+)-Julifloridine

  2020cites this paper
• Transition‐Metal‐Free Alkylation/Arylation of Benzoxazole via Tf 2 O‐Activated‐Amide

  2019cites this paper
• Approach to Fully Substituted Cyclic Nitrones from N-Hydroxylactam Derivatives: Development and Application to the Total Synthesis of Cylindricine C.

  2019cites this paper
• Iridium-PPh3 Catalysts for Conversion of Amides to Enamines

  2019cites this paper
• Iridium-catalyzed Reductive Nucleophilic Addition to Tertiary Amides

  2019cites this paper
• Cross‐Coupling of Secondary Amides with Tertiary Amides: The Use of Tertiary Amides as Surrogates of Alkyl Carbanions for Ketone Synthesis

  2019cites this paper
• Total synthesis of complex alkaloids by nucleophilic addition to amides.

  2018cites this paper
• Asymmetric Total Synthesis and Absolute Configuration Determination of (-)-Verrupyrroloindoline.

  2018cites this paper
• Metal-free approach for the ʟ-proline mediated synthesis of nitrones from nitrosobenzene

  2018cites this paper
• Chemoselective direct reductive trifluoromethylation of amides: a flexible access to functionalized α-trifluoromethylamines

  2018cites this paper
• The iridium-catalysed reductive coupling reaction of tertiary lactams/amides with isocyanoacetates

  2018cites this paper
• Hydrozirconation of C=X Functionalities with Schwartz's Reagent

  2018cites this paper
• Unified Total Synthesis of Stemoamide-Type Alkaloids by Chemoselective Assembly of Five-Membered Building Blocks.

  2017cites this paper
• Oxidation and Reduction

  2011cites this paper