Electron Paramagnetic Resonance Studies of the Electronic Structures of Bis(maleonitriledithiolato)copper(II), -nickel(III), -cobalt(II), and -rhodium(II) Complexes

No abstract is available for this paper.

• Publication year

  1964

• Venue

  Journal of the American Chemical Society

• Publication date

  1964-11-01

• Fields of study

  Chemistry

• Identifiers
  DOI 10.1021/JA01075A013
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• No references are available for this paper.

• State-Interaction Approach for g‑Matrix Calculations in TDDFT: Ground-Excited State Couplings and beyond First-Order Spin–Orbit Effects

  2025cites this paper
• MCM‐41 Supported Anthracene Based Cu(II)‐Schiff Base Complex: A Heterogeneous Catalyst for the Synthesis of 4H‐Pyrans/Chromene

  2024cites this paper
• Square-planar imido complexes of cobalt: synthesis, reactivity and computational study.

  2024cites this paper
• Isolation and Crystallographic Characterization of an Octavalent Co2O2 Diamond Core.

  2024cites this paper
• State-Interaction Approach for Evaluating g-Tensors within EOM-CC and RAS-CI Frameworks: Theory and Benchmarks.

  2023cites this paper
• Selective Cobalt(II)–SNS Dithiolate Complex-Catalyzed Bifunctional Hydroboration of Aldehydes: Kinetics and Mechanistic Studies

  2023cites this paper
• Ligand-Based Redox: Catalytic Applications and Mechanistic Aspects

  2022cites this paper
• {Moco}n, (n = 0-8): A general formalism for describing the highly covalent molybdenum cofactor of sulfite oxidase and related Mo enzymes.

  2022cites this paper
• Synthesis of New Cobalt(III) Meso-Porphyrin Complex, Photochemical, X-ray Diffraction, and Electrical Properties for Photovoltaic Cells

  2022cites this paper
• Synthesis, electronic structures, and reactivity of mononuclear and dinuclear low-valent molybdenum complexes in iminopyridine and bis(imino)pyridine ligand environments.

  2022cites this paper
• The Impact of Ligand Oxidation State and Fold Angle on the Charge Transfer Processes of MoIVO-Dithione Complexes.

  2021cites this paper
• Dithiolate and Catecholate Binding of Copper by the OO∼SS Bifunctional Ligand: Regioselectivity and Regioisomeric Transformations

  2021cites this paper
• Facile Access to Dative, Single, and Double Silicon−Metal Bonds Through M−Cl Insertion Reactions of Base‐Stabilized SiII Cations

  2020cites this paper
• Ligand-Based Reactivity of Oxygenation and Alkylation in Cobalt Complexes Binding with (Thiolato)phosphine Derivatives.

  2020cites this paper
• A novel waste activated sludge multistage utilization strategy for preparing carbon-based Fenton-like catalysts: Catalytic performance assessment and micro-interfacial mechanisms.

  2019cites this paper
• Anisotropic Magnetic Spin Interactions of Transition Metal Complexes and Metalloenzymes from Spectroscopy and Quantum Chemistry

  2019cites this paper
• Challenges in Multireference Perturbation Theory for the Calculations of the g-Tensor of First-Row Transition-Metal Complexes.

  2018cites this paper
• Probing the Electron Accepting Orbitals of Ni-Centered Hydrogen Evolution Catalysts with Noninnocent Ligands by Ni L-Edge and S K-Edge X-ray Absorption.

  2018cites this paper
• Molecular qubits based on potentially nuclear-spin-free nickel ions.

  2017cites this paper
• A Nickel Dithiolate Water Reduction Catalyst Providing Ligand-Based Proton-Coupled Electron-Transfer Pathways.

  2017cites this paper
• d‐electron count, ion‐pairing and diagonal twist angles in metallo‐bis(dithiolene) complexes

  2017cites this paper
• Electrochemical deposition of highly-conducting metal dithiolene films.

  2016cites this paper
• CO Binding at a Four-Coordinate Cobaltous Porphyrin Site in a Metal-Organic Framework: Structural, EPR, and Gas Adsorption Analysis.

  2016cites this paper
• Identifying similarities and differences between analogous bisdithiolene and bisdiselenolene complexes: A computational study

  2016cites this paper
• Negative Ion Photoelectron Spectroscopy Reveals Remarkable Noninnocence of Ligands in Nickel Bis(dithiolene) Complexes [Ni(dddt)2](-) and [Ni(edo)2](-).

  2016cites this paper
• Influence of Ligand Substitution Pattern on Structure in Cobalt(II) Complexes of Bulky N,N′-Diarylformamidinate N-Oxides

  2015cites this paper
• Influence of Electron-Withdrawing Substituents on the Electronic Structure of Oxidized Ni and Cu Salen Complexes.

  2015cites this paper
• Bioinspired design of redox-active ligands for multielectron catalysis: effects of positioning pyrazine reservoirs on cobalt for electro- and photocatalytic generation of hydrogen from water

  2015cites this paper
• Assessment of several DFT functionals in calculation of the reduction potentials for Ni-, Pd-, and Pt-bis-ethylene-1,2-dithiolene and -diselenolene complexes.

  2015cites this paper
• Bis(phosphine)cobalt dialkyl complexes for directed catalytic alkene hydrogenation.

  2014cites this paper
• Four-coordinate cobalt pincer complexes: electronic structure studies and ligand modification by homolytic and heterolytic pathways.

  2014cites this paper
• Basis set error estimation for DFT calculations of electronic g‐tensors for transition metal complexes

  2014cites this paper
• Tris(dithiolene) Chemistry: a Golden Jubilee

  2014cites this paper
• The coordination chemistry of dithione ligands: Design, syntheses, characterization and reactivity study of molybdenum and select first row transition metal complexes

  2014cites this paper
• Dithiolopyranthione Synthesis, Spectroscopy and an Unusual Reactivity with DDQ.

  2013cites this paper
• Electronic structure of [Ni(II)S4] complexes from S K-edge X-ray absorption spectroscopy

  2013cites this paper
• Zeolite-Y Encapsulated Metal Picolinato Complexes as Catalyst for Oxidation of Phenol with Hydrogen Peroxide

  2013cites this paper
• A combined DFT and restricted open-shell configuration interaction method including spin-orbit coupling: application to transition metal L-edge X-ray absorption spectroscopy.

  2013cites this paper
• Nickel(III) complexes of di-amidato-di-phenolato ligands: effect of H-bonding.

  2013cites this paper
• Validating and Analyzing EPR Hyperfine Coupling Constants with Density Functional Theory.

  2013cites this paper
• Catalytic hydrogenation activity and electronic structure determination of bis(arylimidazol-2-ylidene)pyridine cobalt alkyl and hydride complexes.

  2013cites this paper
• Assembled structures and magnetic properties of viologen–[M(mnt)2] charge-transfer salts (mnt = maleonitriledithiolate; M = Cu, Ni, Pt)

  2012cites this paper
• Organic π-Radicals in the Solid-State: From Localised to Delocalised σ-Bonding

  2012cites this paper
• A new approach to the design of antioxidants derived from 3,5,7,3′,4′-pentahydroxyflavone

  2012cites this paper
• Improving the calculation of Electron Paramagnetic Resonance hyperfine coupling tensors for d-block metals.

  2012cites this paper
• Diversities of Coordination Geometry Around the Cu2+ Center in Bis(maleonitriledithiolato)metalate Complex Anions: Geometry Controlled by Varying the Alkyl Chain Length of Imidazolium Cations

  2012cites this paper
• On the electronic structure of nitro-substituted bipyridines and their platinum complexes.

  2012cites this paper
• Dithiolene complexes as metalloligands: [Cu(en) 2 ][Cu(mnt) 2 ], an S = ½ spin chain

  2012cites this paper
• Electronic Structure of (NiS4) - Investigated by Single-Crystal EPR and Density Functional Theory

  2012cites this paper
• Molecular motion of the bis(maleonitriledithiolato)nickel trianion in solution.

  2012cites this paper
• Synthesis, structure and physical properties of transition metal bis 4-cyanobenzene-1,2-dithiolate complexes [M(cbdt)2]z− (M = Zn, Co, Cu, Au, Ni, Pd, z = 0, 1, 2)

  2012cites this paper
• Structural, spectroscopic and redox properties of a mononuclear Co(II) thiolate complex--the reactivity toward S-alkylation: an experimental and theoretical study.

  2012cites this paper
• pH-responsive switching of near-infrared absorption of a diradical complex of PtII and 3,4-diaminobenzoate formed in aqueous solutions

  2011cites this paper
• Anchoring of copper(II) complexes onto the organically modified MCM-41: Preparation, characterization and catalytic epoxidation

  2011cites this paper
• Dithiolene Radicals: Sulfur K-Edge X-Ray Absorption Spectroscopy and Harry's Intuition

  2011cites this paper
• Trigonal prismatic coordination in tris(dithiolene) complexes: Guilty or just non-innocent?

  2011cites this paper
• Organometallic dithiolene complexes of the group 8-10 metals: reactivities, structures and electrochemical behavior.

  2011cites this paper
• Square-Planar Cobalt Complexes with Monodentate N-Heterocyclic Carbene Ligation: Synthesis, Structure, and Catalytic Application

  2011cites this paper
• Noninnocence in metal complexes: a dithiolene dawn.

  2011cites this paper
• Probing magnetic interactions in columnar phases of a paramagnetic gold dithiolene complex

  2011cites this paper
• Comment on "A nickel(II)-based radical-ligand complex as a functional model of hydrogenase".

  2011cites this paper
• Optimized Basis Sets for Calculation of Electron Paramagnetic Resonance Hyperfine Coupling Constants: aug-cc-pVTZ-J for the 3d Atoms Sc-Zn.

  2011cites this paper
• Determining the site of reduction of 4-NO2-2,2'-bipyridine and [Pt(4-NO2-2,2'-bipyridine)Cl2].

  2010cites this paper
• ESR-Untersuchungen an einem Dithiolen-1,2-Diimin-Gemischt-Ligand-Komplex des Kupfer(II)†

  2010cites this paper
• ESR-Untersuchungen zu den Bindungsverhältnissen in fünffach koordinierten neutralen Niedrigspin-Kobalt-Dithiolenen, [Co(PR3)S4C4H4]0

  2010cites this paper
• Synthesis, Structures, and Spectroscopic Properties of Three Polynuclear Complexes from Nickel(II) Precursor with a 14-membered Tetraaza Macrocyclic Ligand

  2010cites this paper
• ESR-Untersuchungen zur chemischen Oxydation von makrocyclischen und tricyclischen Nickel(II)-chelaten Schiffscher Basen

  2010cites this paper
• pH-Responsive Switching of the Near-Infrared Absorption of the Water-Soluble Bis(o-diiminobenzosemiquinonato)platinum(II) Complex

  2010cites this paper
• ESR‐Untersuchungen zu Ligandenaustausch‐reaktionen an Kupfer(11)‐bis(0,0′‐di‐isobutyl‐dithiophosphat) durch Selen‐ und (oder) Schwefel‐Donoratome enthaltende Liganden

  2010cites this paper
• ESR-Einkristalluntersuchungen an dem Gemischtligand-Nickel(III)-Chelat [Ni(mnt)(Et2dtc)]

  2010cites this paper
• Dimercapto-isotrithion — ein neuer, ungesättigter 1,2-Dithiolatligand

  2010cites this paper
• Ligand-solvent interactions in a highly reduced metal chelate complex: medium dependence of the one-electron reduction of the bis(maleonitriledithiolato)gold dianion.

  2009cites this paper
• Rare monomeric structure of CpRh(III) dithiolene complex: Combined ESR and electronic absorption studies on electrochemically generated Rh(II) species

  2009cites this paper
• Tetramethyl ammonium as masking agent for molecular stencil patterning in the confined space of the nano-channels of 2D hexagonal-templated porous silicas.

  2009cites this paper
• Design of grafted copper complex in mesoporous silica in defined coordination, hydrophobicity and confinement states

  2009cites this paper
• Structural Origins of Noninnocent Coordination Chemistry

  2009cites this paper
• One-electron oxidized nickel(II) complexes of bis and tetra(salicylidene) phenylenediamine Schiff bases: from monoradical to interacting Ni(III) ions.

  2009cites this paper
• Characterisation of nanohybrids of porphyrins with metallic and semiconducting carbon nanotubes by EPR and optical spectroscopy.

  2008cites this paper
• Chapter 6 – EPR and Low-temperature MCD Spectroscopy of Ferrous Heme Nitrosyls

  2008cites this paper
• Metal 1,2-Dithiolene and Related Complexes

  2007cites this paper
• One‐Dimensional Inorganic Complexes

  2007cites this paper
• Nickel and the carbon cycle.

  2007cites this paper
• A Square‐Planar Nickel(II) Monoradical Complex with a Bis(salicylidene)diamine Ligand

  2007cites this paper
• The Chemistry of Nickel‐Containing Enzymes

  2007cites this paper
• Metal Complexes of Schiff Bases and β‐Ketoamines

  2007cites this paper
• Metal Complexes Derived from cis‐1,2‐dicyano‐1,2‐ethylenedithiolate and Bis(Trifluoromethyl)‐1,2‐dithiete

  2007cites this paper
• Evidence from ESR studies for [Co(η‐C2H4)3] produced at 77 K in a rotating cryostat

  2006cites this paper
• Quasi-one-dimensional molecular magnets based on derivatives of (fluorobenzyl)pyridinium with the [M(mnt)2] monoanion (M = Ni, Pd or Pt; mnt2- = maleonitriledithiolate): syntheses, crystal structures and magnetic properties.

  2006cites this paper
• Diversities of Coordination Geometry at Cu2+ Center in the Bis(maleonitriledithiolato)cuprate Complexes: Syntheses, Magnetic Properties, X-ray Crystal Structural Analyses, and DFT Calculations

  2006cites this paper
• Salts of ammonium-crown ether supramolecular cation with bis(maleonitriledithiolato)copperate(II): Crystal structures, magnetic susceptibilities, single crystal EPR spectra and DFT calculation

  2005cites this paper
• Ligand K-edge x-ray absorption spectroscopy: Covalency of ligand-metal bonds

  2005cites this paper
• Valent state and coordination of cobalt Ions in beryl and chrysoberyl crystals

  2004cites this paper
• Near-IR absorption due to supramolecular electronic interaction in an extended 3D hydrogen-bonding network material: synthesis, crystal structure and properties of [4,4′-H2bpy][Cu(mnt)2] ☆

  2004cites this paper
• Relativistic spin-orbit effects on hyperfine coupling tensors by density-functional theory.

  2004cites this paper
• A comparison of the gas, solution, and solid state coordination environments for the Ni(II) complexes of a series of linear penta- and hexadentate aminopyridine ligands with accessible Ni(III) oxidation states

  2004cites this paper
• Chemistry of Dithiolenes and Their Nickel and Molybdenum Complexes

  2004cites this paper
• EPR Spectroscopic Investigation of the Active Site of [NiFe]-Hydrogenase

  2003cites this paper
• Ni(III) vs. Ni(II)-thiyl radical: charge-delocalisation in a binuclear Ni(III)Ni(II)-dithiolate complex.

  2003cites this paper
• 67 – Biochemistry of Methyl-CoM Reductase and Coenzyme F430

  2003cites this paper
• Electron spin resonance studies of Co(tbp)·C60 single crystal

  2002cites this paper