Above a certain density threshold, suspensions of rodlike colloidal particles form system-spanning networks. Using Monte Carlo simulations, we investigate how the depletion forces caused by spherical particles affect these networks in isotropic suspensions of rods. Although the depletion forces are strongly anisotropic and favor alignment of the rods, the percolation threshold of the rods decreases significantly. The relative size of the effect increases with the aspect ratio of the rods. The structural changes induced in the suspension by the depletant are characterized in detail and the system is compared to an ideal fluid of freely interpenetrable rods.
Depletion-induced percolation in networks of nanorods.
T. Schilling,S. Jungblut,Mark A. Miller
Published 2006 in Physical Review Letters
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- Publication year
2006
- Venue
Physical Review Letters
- Publication date
2006-08-23
- Fields of study
Medicine, Materials Science, Physics
- Identifiers
- External record
- Source metadata
Semantic Scholar, PubMed
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