We use confocal microscopy to study particle motion in colloidal systems. Near the glass transition, motion is inhibited, as particles spend time trapped in transient "cages" formed by neighboring particles. We measure the cage sizes and lifetimes, which, respectively, shrink and grow as the glass transition approaches. Cage rearrangements are more prevalent in regions with lower concentrations and higher disorder. Neighboring rearranging particles typically move in parallel directions, although a nontrivial fraction moves in antiparallel directions, usually from particle pairs with initial separations corresponding to local maxima and minima of the pair correlation function g(r), respectively.
Properties of cage rearrangements observed near the colloidal glass transition.
Published 2001 in Physical Review Letters
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- Publication year
2001
- Venue
Physical Review Letters
- Publication date
2001-07-13
- Fields of study
Medicine, Materials Science, Physics
- Identifiers
- External record
- Source metadata
Semantic Scholar, PubMed
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