Shaping well-defined noble-metal-based nanostructures for fabricating high-performance electrocatalysts: advances and perspectives

This review highlights recent advances in shaping protocols and structure-activity relationships of noble-metal-based catalysts with well-defined nanostructures in electrochemical reactions.

• Publication year

  2019

• Venue

  Inorganic Chemistry Frontiers

• Publication date

  2019-10-08

• Fields of study

  Materials Science, Chemistry

• Identifiers
  DOI 10.1039/C9QI00689C
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Charge-Redistribution-Enhanced Nanocrystalline Ru@IrOx Electrocatalysts for Oxygen Evolution in Acidic Media

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• Engineering Surface Structure of Pt Nanoshells on Pd Nanocubes to Preferentially Expose Active Surfaces for ORR by Manipulating the Growth Kinetics.

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• Shell Nanoparticles : Impact of the Atomic Ordering of the Ru Metal Core on the Electrocatalytic Activity of the Pt Shell

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• Low-Coordinated Gold Atoms Boost Electrochemical Nitrogen Reduction Reaction under Ambient Conditions

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• Enhanced Electroreduction of Carbon Dioxide to Methanol Using Zinc Dendrites Pulse-Deposited on Silver Foam.

  2019cited by this paper
• High-Performance Ru@C4N Electrocatalyst for Hydrogen Evolution Reaction in Both Acidic and Alkaline Solutions.

  2019cited by this paper
• Ambient Nitrogen Reduction to Ammonia Electrocatalyzed by Bimetallic PdRu Porous Nanostructures

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• Ru Octahedral Nanocrystals with a Face-Centered Cubic Structure, {111} Facets, Thermal Stability up to 400 °C, and Enhanced Catalytic Activity.

  2019cited by this paper
• Combining the Advantages of Hollow and One-Dimensional Structures: Balanced Activity and Stability toward Methanol Oxidation Based on the Interface of PtCo Nanochains

  2019cited by this paper
• Transition‐Metal‐Doped RuIr Bifunctional Nanocrystals for Overall Water Splitting in Acidic Environments

  2019cited by this paper
• Structural Sensitivities in Bimetallic Catalysts for Electrochemical CO2 Reduction Revealed by Ag-Cu Nanodimers.

  2019cited by this paper
• Electrochemical Fabrication of Porous Au Film on Ni Foam for Nitrogen Reduction to Ammonia.

  2019cited by this paper
• Enhanced electrocatalytic CO formation from CO2 on nanostructured silver foam electrodes in ionic liquid/water mixtures

  2019cited by this paper
• Mesoporous Pd@Ru Core-Shell Nanorods for Hydrogen Evolution Reaction in Alkaline Solution.

  2018cited by this paper
• Molybdenum Doping Augments Platinum-Copper Oxygen Reduction Electrocatalyst.

  2018cited by this paper
• Intrinsic composition and electronic effects of multicomponent platinum nanocatalysts with high activity and selectivity for ethanol oxidation reaction

  2018cited by this paper
• Comprehensive Analysis on the Highly Active and Stable PdAu/C Electrocatalyst for Ethanol Oxidation Reaction in Alkaline Media

  2018cited by this paper
• Single‐Atom Catalysts for the Hydrogen Evolution Reaction

  2018cited by this paper
• Thin-walled hollow Au–Cu nanostructures with high efficiency in electrochemical reduction of CO2 to CO

  2018cited by this paper
• Synthesis of Ru Icosahedral Nanocages with a Face-Centered-Cubic Structure and Evaluation of Their Catalytic Properties

  2018cited by this paper
• Cubic-Core Hexagonal-Branch Mechanism To Synthesize Bimetallic Branched and Faceted Pd-Ru Nanoparticles for Oxygen Evolution Reaction Electrocatalysis.

  2018cited by this paper
• Surface Evolution of PtCu Alloy Shell over Pd Nanocrystals Leads to Superior Hydrogen Evolution and Oxygen Reduction Reactions

  2018cited by this paper
• Electrochemical Synthesis of Ammonia from N2 and H2O under Ambient Conditions Using Pore-Size-Controlled Hollow Gold Nanocatalysts with Tunable Plasmonic Properties.

  2018cited by this paper
• Ambient Electrochemical Synthesis of Ammonia from Nitrogen and Water Catalyzed by Flower-Like Gold Microstructures.

  2018cited by this paper
• Crystallinity Dependence of Ruthenium Nanocatalyst toward Hydrogen Evolution Reaction

  2018cited by this paper
• Porous Trimetallic PtRhCu Cubic Nanoboxes for Ethanol Electrooxidation

  2018cited by this paper
• Dopant-induced electron localization drives CO2 reduction to C2 hydrocarbons

  2018cited by this paper
• BCC-Phased PdCu Alloy as a Highly Active Electrocatalyst for Hydrogen Oxidation in Alkaline Electrolytes.

  2018cited by this paper
• Cyclic Penta-Twinned Rhodium Nanobranches as Superior Catalysts for Ethanol Electro-oxidation.

  2018cited by this paper
• Roles of Mo Surface Dopants in Enhancing the ORR Performance of Octahedral PtNi Nanoparticles.

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• A Spectroscopic Study on the Nitrogen Electrochemical Reduction Reaction on Gold and Platinum Surfaces.

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• Electrocatalytic Alloys for CO2 Reduction.

  2018cited by this paper
• Ir-Pd nanoalloys with enhanced surface-microstructure-sensitive catalytic activity for oxygen evolution reaction in acidic and alkaline media

  2018cited by this paper
• Surfactant-free atomically ultrathin rhodium nanosheet nanoassemblies for efficient nitrogen electroreduction

  2018cited by this paper
• Silver sulfide anchored on reduced graphene oxide as a high -performance catalyst for CO 2 electroreduction

  2018cited by this paper
• Molybdenum-Based Carbon Hybrid Materials to Enhance the Hydrogen Evolution Reaction.

  2018cited by this paper
• Hexapod PtRuCu Nanocrystalline Alloy for Highly Efficient and Stable Methanol Oxidation

  2018cited by this paper
• Performance and In-Situ FTIR Evaluation of Pt−Sn/C Electrocatalysts with Several Pt : Sn Atomic Ratios for the Ethanol Oxidation Reaction in Acidic Media

  2018cited by this paper
• Understanding the Effects of Au Morphology on CO2 Electrocatalysis

  2018cited by this paper
• Anchoring PdCu Amorphous Nanocluster on Graphene for Electrochemical Reduction of N2 to NH3 under Ambient Conditions in Aqueous Solution

  2018cited by this paper
• Vertex‐Reinforced PtCuCo Ternary Nanoframes as Efficient and Stable Electrocatalysts for the Oxygen Reduction Reaction and the Methanol Oxidation Reaction

  2018cited by this paper
• Highly Efficient Acidic Oxygen Evolution Electrocatalysis Enabled by Porous Ir–Cu Nanocrystals with Three-Dimensional Electrocatalytic Surfaces

  2018cited by this paper
• Pt-Richcore/Sn-Richsubsurface/Ptskin Nanocubes As Highly Active and Stable Electrocatalysts for the Ethanol Oxidation Reaction.

  2018cited by this paper
• Core–Shell Nanostructured Cobalt–Platinum Electrocatalysts with Enhanced Durability

  2018cited by this paper
• In situ Raman spectroscopic evidence for oxygen reduction reaction intermediates at platinum single-crystal surfaces

  2018cited by this paper
• Shape-Control of Pt-Ru Nanocrystals: Tuning Surface Structure for Enhanced Electrocatalytic Methanol Oxidation.

  2018cited by this paper
• Strain Effect in Bimetallic Electrocatalysts in the Hydrogen Evolution Reaction

  2018cited by this paper
• Boosting Formate Production in Electrocatalytic CO2 Reduction over Wide Potential Window on Pd Surfaces.

  2018cited by this paper
• Enhancing the rate of electrochemical nitrogen reduction reaction for ammonia synthesis under ambient conditions using hollow gold nanocages

  2018cited by this paper
• Making Ag Present Pt-like Activity for Hydrogen Evolution Reaction

  2018cited by this paper
• Rational Design of Single Molybdenum Atoms Anchored on N-Doped Carbon for Effective Hydrogen Evolution Reaction.

  2017cited by this paper
• Surface Confinement Etching and Polarization Matter: A New Approach To Prepare Ultrathin PtAgCo Nanosheets for Hydrogen-Evolution Reactions

  2017cited by this paper
• Deactivation of Supported Pt Catalysts during Alcohol Oxidation Elucidated by Spectroscopic and Kinetic Analyses

  2017cited by this paper
• The Effect of Surface Site Ensembles on the Activity and Selectivity of Ethanol Electrooxidation by Octahedral PtNiRh Nanoparticles.

  2017cited by this paper
• Shape-tunable Pt-Ir alloy nanocatalysts with high performance in oxygen electrode reactions.

  2017cited by this paper
• Electrochemical Reduction of N2 under Ambient Conditions for Artificial N2 Fixation and Renewable Energy Storage Using N2/NH3 Cycle

  2017cited by this paper
• Synthesis of Ni–Ir Nanocages with Improved Electrocatalytic Performance for the Oxygen Evolution Reaction

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• Electrochemical Activation of CO2 through Atomic Ordering Transformations of AuCu Nanoparticles.

  2017cited by this paper
• Au Sub‐Nanoclusters on TiO2 toward Highly Efficient and Selective Electrocatalyst for N2 Conversion to NH3 at Ambient Conditions

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• Nature of Highly Active Electrocatalytic Sites for the Hydrogen Evolution Reaction at Pt Electrodes in Acidic Media

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• Strain-induced Stranski-Krastanov growth of Pd@Pt core-shell hexapods and octapods as electrocatalysts for methanol oxidation.

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• Single-Atom Electrocatalysts.

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• Preparation and characterization of Cu clusters and Cu–Ag alloy via galvanic replacement method for azo dyes degradation

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• Stability and Activity of Non-Noble-Metal-Based Catalysts Toward the Hydrogen Evolution Reaction.

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• Electrocatalytic Oxygen Evolution Reaction in Acidic Environments – Reaction Mechanisms and Catalysts

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• Icosahedral nanocrystals of noble metals: Synthesis and applications

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• On the design of Pt-Sn efficient catalyst for carbon monoxide and ethanol oxidation in acid and alkaline media

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• Progress in the Electrochemical Synthesis of Ammonia

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• ELECTROCHEMISTRY: Combining theory and experiment in electrocatalysis: Insights into materials design

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• Finely Composition-Tunable Synthesis of Ultrafine Wavy PtRu Nanowires as Effective Electrochemical Sensors for Dopamine Detection.

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• Site-Selective Carving and Co-Deposition: Transformation of Ag Nanocubes into Concave Nanocrystals Encased by Au-Ag Alloy Frames.

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• Nanoporous Au Thin Films on Si Photoelectrodes for Selective and Efficient Photoelectrochemical CO2 Reduction

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• Doping palladium with tellurium for the highly selective electrocatalytic reduction of aqueous CO2 to CO

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• Breaking scaling relations to achieve low-temperature ammonia synthesis through LiH-mediated nitrogen transfer and hydrogenation.

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• Electroreduction of Carbon Dioxide to Hydrocarbons Using Bimetallic Cu-Pd Catalysts with Different Mixing Patterns.

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• Sub-4 nm PtZn Intermetallic Nanoparticles for Enhanced Mass and Specific Activities in Catalytic Electrooxidation Reaction.

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• Unique Cu@CuPt Core-Shell Concave Octahedron with Enhanced Methanol Oxidation Activity.

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• Ag-Sn Bimetallic Catalyst with a Core-Shell Structure for CO2 Reduction.

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• Shape-Dependent Electrocatalytic Reduction of CO2 to CO on Triangular Silver Nanoplates.

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• Platinum–Cobalt Bimetallic Nanoparticles with Pt Skin for Electro-Oxidation of Ethanol

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• Component-Controlled Synthesis of Necklace-Like Hollow NiXRuy Nanoalloys as Electrocatalysts for Hydrogen Evolution Reaction.

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• Mechanistic Roles of Hydroxide in Controlling the Deposition of Gold on Colloidal Silver Nanocrystals

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• In Situ Infrared Spectroscopic Investigations of Pyridine-Mediated CO2 Reduction on Pt Electrocatalysts

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• Synthesis of Durable Small-sized Bilayer Au@Pt Nanoparticles for High Performance PEMFC Catalysts

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• PdCu@Pd Nanocube with Pt-like Activity for Hydrogen Evolution Reaction.

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• Experimental Proof of the Bifunctional Mechanism for the Hydrogen Oxidation in Alkaline Media.

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• Synthesis, Study, and Discrete Dipole Approximation Simulation of Ag-Au Bimetallic Nanostructures

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• Theoretical Insights into the Effects of Oxidation and Mo-Doping on the Structure and Stability of Pt-Ni Nanoparticles.

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• Well-faceted noble-metal nanocrystals with nonconvex polyhedral shapes.

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• Surface engineering of hierarchical platinum-cobalt nanowires for efficient electrocatalysis

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• FeOOH/Co/FeOOH Hybrid Nanotube Arrays as High-Performance Electrocatalysts for the Oxygen Evolution Reaction.

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• Enhanced Electrocatalytic Activity toward the Oxygen Reduction Reaction through Alloy Formation: Platinum–Silver Alloy Nanocages

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• Spatially-controlled growth of platinum on gold nanorods with tailoring plasmonic and catalytic properties

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• Simple synthesis of bimetallic AuPd dendritic alloyed nanocrystals with enhanced electrocatalytic performance for hydrazine oxidation reaction

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• Electrocatalysis by Mass-Selected Ptn Clusters.

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• Trimetallic TriStar Nanostructures: Tuning Electronic and Surface Structures for Enhanced Electrocatalytic Hydrogen Evolution

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• Energy and fuels from electrochemical interfaces.

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• Tailoring ruthenium exposure to enhance the performance of fcc platinum@ruthenium core-shell electrocatalysts in the oxygen evolution reaction.

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• Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide

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• A Critical Review on Hydrogen Evolution Electrocatalysis: Re-exploring the Volcano-relationship

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• Self-assembly of three-shell nanostructures in initially homogeneous binary metallic nanoparticles: hybrid molecular dynamics/Monter-Carlo simulations

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• Surface local strain and diatomic iron doping synergistically promote the plasmonic photoelectrochemical nitrogen reduction reaction.

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• Atomistic Simulation of Segregation in Ternary Pt–Pd–Ni Nanoalloy

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• Morphology-controlled composite of conductive Cu CATs nanorods and bimetallic PdPt nanospheres for electrochemical sensitive detection of 17β-estradiol

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• Puzzles of Surface Segregation in Binary Pt–Pd Nanoparticles: Molecular Dynamics and Thermodynamic Simulations

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• Synthesis of non-cytotoxic Co_3O_4 nanocatalysts for thermocatalytic methane decomposition by resource recovery

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• Controlled Synthesis of Carbon-Supported Pt-Based Electrocatalysts for Proton Exchange Membrane Fuel Cells

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• Recent progress in cobalt-based carbon materials as oxygen electrocatalysts for zinc-air battery applications

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• Melting Behavior of Bimetallic and Trimetallic Nanoparticles: A Review of MD Simulation Studies

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