Catalytic Isomerization of Biomass‐Derived Aldoses: A Review

Abstract Selected aldohexoses (d‐glucose, d‐mannose, and d‐galactose) and aldopentoses (d‐xylose, l‐arabinose, and d‐ribose) are readily available components of biopolymers. Isomerization reactions of these substances are very attractive as carbon‐efficient processes to broaden the portfolio of abundant monosaccharides. This review focuses on the chemocatalytic isomerization of aldoses into the corresponding ketoses as well as epimerization of aldoses at C2. Recent advances in the fields of catalysis by bases and Lewis acids are considered. The emphasis is laid on newly uncovered catalytic systems and mechanisms of carbohydrate transformations.

• Publication year

  2016

• Venue

  ChemSusChem

• Publication date

  2016-03-07

• Fields of study

  Medicine, Chemistry, Environmental Science

• Identifiers
  DOI 10.1002/cssc.201501577PMID 26948404PMCID 5069572
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

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