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The Unusual Photochromic and Hydrochromic Switching Behavior of Cellulose-Embedded 1,8-Naphthalimide-Viologen Derivatives in the Solid-State.

Zhimin Sun,Yanhai Ni,Thirumurugan Prakasam,Wenqi Liu,Huan-Bao Wu,Zhao Zhang,H. Di,K. Baldridge,A. Trabolsi,M. Olson

Published 2021 in Chemistry

ABSTRACT

Stimuli-responsive chromic materials such as photochromes, hydrochromes, thermochromes, and electrochromes have a long history of capturing the attention of scientists due to their potential industrial applications and novelty in popular culture. However, hybrid chromic materials that combine two or more stimuli-triggered color changing properties are not so well known. Herein, we report a design strategy that has led to a series of emissive 1,8-naphthalimide-viologen dyads which exhibit unusual dual photochromic and hydrochromic switching behavior in the solid-state when embedded in a cellulose matrix. This behavior manifests as reversible solid state fluorescence hydrochromism upon changes in relative humidity and reversible solid state photochromism upon generation of a cellulose-stabilized viologen radical cation. In this design strategy, the bipyridinium unit serves as a water-sensitive receptor for the hydrochromic fluorophore-receptor system, and a photochromic group capable of eliciting its own visible colorimetric response, generating an emission quenching radical cation with exposure to UV light. These dyes can be inkjet-printed onto cellulose paper or drop-cast as cellulose powder-based films and can be unidirectionally cycled between three states which can be visualized under UV light or visible light. The material's photochromism, hydrochromism, and underlying mechanism of action was investigated using computational analysis, dynamic vapor sorption isotherms, EPR spectroscopy, and variable humidity UV-Vis adsorption and fluorescence spectroscopies.

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