Assembly and Chiral Memory Effects of Dynamic Macroscopic Supramolecular Helices.

Macroscopic enantiomerically pure helical supramolecular fibers are bottom-up assembled in aqueous media from a chiral π-electron donor template and an achiral π-electron acceptor. The helices can be assembled to the sub-millimeter scale with controlled handedness. These dynamic supramolecular architectures allow for a quantitative exchange of the chiral donor template with achiral analogues. During this process, a chiral memory effect was observed, affording enantiomerically pure helices composed entirely of achiral components.

• Publication year

  2018

• Venue

  Chemistry

• Publication date

  2018-09-10

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1002/chem.201803005PMID 30089198
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

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