Lithium Dichloro(2,2,6,6‐tetramethylpiperidinato)‐Magnesiate

No abstract is available for this paper.

• Publication year

  2021

• Venue

  Encyclopedia of Reagents for Organic Synthesis

• Publication date

  2021-07-16

• Fields of study

  Chemistry

• Identifiers
  DOI 10.1002/047084289X.RN02373
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Functionalization of 1,3,4-Oxadiazoles and 1,2,4-Triazoles via Selective Zincation or Magnesiation Using 2,2,6,6-Tetramethylpiperidyl Bases.

  2020cited by this paper
• Aerobic C(sp2)-H Hydroxylations of 2-Aryloxazolines: Fast Access to Excited-State Intramolecular Proton Transfer (ESIPT)-Based Luminophores.

  2019cited by this paper
• A telescoped Knochel-Hauser/Kumada-Corriu coupling strategy to functionalized aromatic heterocycles

  2019cited by this paper
• An axisymmetric heptacyclic lactam unit for efficient polymer solar cells

  2018cited by this paper
• Regioselective ortho-functionalization of bromofluorenecarbaldehydes using TMPMgCl·LiCl.

  2018cited by this paper
• Amination of Phosphorodiamidate-Substituted Pyridines and Related N-Heterocycles with Magnesium Amides.

  2018cited by this paper
• Directed Zincation or Magnesiation of the 2-Pyridone and 2,7-Naphthyridone Scaffold Using TMP Bases.

  2017cited by this paper
• Selective Metalations of 1,4-Dithiins and Condensed Analogues Using TMP-Magnesium and -Zinc Bases.

  2017cited by this paper
• E/Z-Selectivity Controlled by Participation of Internal Oxy Group During Electrophilic Substitution of Alk-1-enylboronate with Bis(2,4,6-trimethylpyridine)iodonium Salt

  2017cited by this paper
• Transition-Metal-Free Amination of Pyridine-2-sulfonyl Chloride and Related N-Heterocycles Using Magnesium Amides.

  2017cited by this paper
• Selective functionalization of cyano-phenyl-2-oxazolines using TMPMgCl·LiCl

  2017cited by this paper
• Iodoindazoles with Selective Magnesiation at Position 3: A Route to Highly Functionalized Indazoles.

  2016cited by this paper
• Continuous Flow Magnesiation or Zincation of Acrylonitriles, Acrylates, and Nitroolefins. Application to the Synthesis of Butenolides.

  2016cited by this paper
• Lewis Acid Triggered Regioselective Magnesiation and Zincation of Uracils, Uridines, and Cytidines.

  2016cited by this paper
• Solution Structure of Turbo-Hauser Base TMPMgCl⋅LiCl in [D8 ]THF.

  2016cited by this paper
• A Step-Efficient Pathway to Chlorine-Functionalized Thiophene Oligomers by Palladium-Catalyzed Deprotonative Coupling of Chlorothiophenes

  2016cited by this paper
• Synthesis of Poly(3-substituted thiophene)s of Remarkably High Solubility in Hydrocarbon via Nickel-Catalyzed Deprotonative Cross-Coupling Polycondensation

  2016cited by this paper
• Solution Structures of Hauser Base (i)Pr2NMgCl and Turbo-Hauser Base (i)Pr2NMgCl·LiCl in THF and the Influence of LiCl on the Schlenk-Equilibrium.

  2016cited by this paper
• Directed Functionalization of Halophenyl-2-oxazolines with TMPMgCl·LiCl

  2015cited by this paper
• Functionalization of quinoxalines by using TMP bases: preparation of tetracyclic heterocycles with high photoluminescene quantum yields.

  2015cited by this paper
• Directed Functionalization of Cyano-Substituted Furans and Thiophenes with TMPMgCl·LiCl

  2015cited by this paper
• Synthesis of the Azaoxoaporphine Alkaloid Sampangine and Ascididemin‐Type Pyridoacridines through TMPMgCl·LiCl‐Mediated Ring Closure

  2015cited by this paper
• Synthesis and Properties of Regioregular Poly(3-substituted thiophene) Bearing Disiloxane Moiety in the Substituent. Remarkably High Solubility in Hexane

  2014cited by this paper
• New in situ trapping metalations of functionalized arenes and heteroarenes with TMPLi in the presence of ZnCl2 and other metal salts.

  2014cited by this paper
• Nickel(II)-Catalyzed Cross-Coupling Polycondensation of Thiophenes via C–S Bond Cleavage

  2014cited by this paper
• Synthesis of functionalized cyanopyrazoles via magnesium bases.

  2014cited by this paper
• Total synthesis of the marine pyridoacridine alkaloid demethyldeoxyamphimedine.

  2014cited by this paper
• Continuous flow magnesiation of functionalized heterocycles and acrylates with TMPMgCl⋅LiCl.

  2014cited by this paper
• Directed Magnesiation of Polyhaloaromatics using the Tetramethylpiperidylmagnesium Reagents TMP2Mg⋅2 LiCl and TMPMgCl⋅LiCl

  2013cited by this paper
• Full functionalization of the 7-azaindole scaffold by selective metalation and sulfoxide/magnesium exchange.

  2013cited by this paper
• A convenient alumination of functionalized aromatics by using the frustrated Lewis pair Et3 Al and TMPMgCl⋅LiCl.

  2013cited by this paper
• Facile Preparation of Poly(3-substituted thiophene) Block Copolymers by Nickel-catalyzed Deprotonative Polycondensation without External Generation of Thiophene Organometallic Species

  2013cited by this paper
• Synthesis of High-molecular-weight Head-to-tail-type Poly(3-substituted-thiophene)s by Cross-coupling Polycondensation with [CpNiCl(NHC)] as a Catalyst

  2013cited by this paper
• Synthesis of π-conjugated poly(thienylenearylene)s with nickel-catalyzed C–H functionalization polycondensation

  2012cited by this paper
• The ortho and meta magnesiation of functionalized anilines and amino-substituted pyridines and pyrazines at room temperature.

  2012cited by this paper
• Studies on the Generation of Metalating Species Equivalent to the Knochel–Hauser Base in the Dehydrobrominative Polymerization of Thiophene Derivatives

  2012cited by this paper
• Regioselective functionalization of the thiazole scaffold using TMPMgCl·LiCl and TMP2Zn·2MgCl2·2LiCl.

  2011cited by this paper
• C-H functionalization polycondensation of chlorothiophenes in the presence of nickel catalyst with stoichiometric or catalytically generated magnesium amide.

  2011cited by this paper
• Selective multiple magnesiations of the thieno[3,2-b]thiophene scaffold.

  2011cited by this paper
• Selective magnesiation or zincation of highly functionalized alkenes and cycloalkenes using 2,2,6,6-tetramethylpiperidyl bases.

  2011cited by this paper
• Synthesis of functionalized pyridazin-3(2H)-ones via selective bromine-magnesium exchange and lactam directed ortho C-H magnesiation.

  2011cited by this paper
• Regio- and chemoselective metalation of arenes and heteroarenes using hindered metal amide bases.

  2011cited by this paper
• Frustrated Lewis pairs: metal-free hydrogen activation and more.

  2010cited by this paper
• Scaleable Preparation of Functionalized Organometallics via Directed Ortho Metalation Using Mg- and Zn-Amide Bases

  2010cited by this paper
• Regio- and chemoselective synthesis of fully substituted thiophenes.

  2009cited by this paper
• Regio- and chemoselective metalation of chloropyrimidine derivatives with TMPMgCl x LiCl and TMP(2)Zn x 2 MgCl(2) x 2 LiCl.

  2009cited by this paper
• 2,3-Functionalization of furans, benzofurans and thiophenes via magnesiation and sulfoxide-magnesium exchange.

  2009cited by this paper
• Synthesis of fully substituted pyrazoles via regio- and chemoselective metalations.

  2009cited by this paper
• Direct zincation of functionalized aromatics and heterocycles by using a magnesium base in the presence of ZnCl2.

  2009cited by this paper
• Unmasking representative structures of TMP-active Hauser and turbo-Hauser bases.

  2008cited by this paper
• Flash Chemistry: Fast Organic Synthesis in Microsystems

  2008cited by this paper
• Preparation of fully substituted anilines for the synthesis of functionalized indoles.

  2008cited by this paper
• Regio- and chemoselective multiple functionalization of pyrimidine derivatives by selective magnesiations using TMPMgCl.LiCl.

  2008cited by this paper
• Regio- and chemoselective magnesiation of protected uracils and thiouracils using TMPMgCl x LiCl and TMP(2)Mg x 2 LiCl.

  2008cited by this paper
• Multiple regioselective functionalizations of quinolines via magnesiations.

  2007cited by this paper
• Preparation of Di-, Tri-, and Tetra-Substituted Functionalized Ferrocenes via Magnesium Organometallics

  2007cited by this paper
• Direct magnesiation of polyfunctionalized arenes and heteroarenes using (tmp)(2)Mg x 2LiCl.

  2007cited by this paper
• Mixed Mg/Li amides of the type R2NMgCl.LiCl as highly efficient bases for the regioselective generation of functionalized aryl and heteroaryl magnesium compounds.

  2006cited by this paper
• Highly functionalized benzene syntheses by directed mono or multiple magnesiations with TMPMgCl.LiCl.

  2006cited by this paper
• Deprotonation of chloropyridines using lithium magnesates

  2004cited by this paper
• A LiCl-mediated Br/Mg exchange reaction for the preparation of functionalized aryl- and heteroarylmagnesium compounds from organic bromides.

  2004cited by this paper
• A new approach to substituted cyclobutanes: Direct β-deprotonation/ magnesiation of cyclobutane carboxamides

  2003cited by this paper
• BuMgNiPr2: a new base for stoichiometric, position-selective deprotonation of cyclopropane carboxamides and other weak CH acids.

  2002cited by this paper
• Selective metallation of thiophene and thiazole rings with magnesium amide base

  2001cited by this paper
• Magnesiation of indoles with magnesium amide bases

  1996cited by this paper
• Regioselective Metalation of 9-Methoxymethyl-β-carboline-3-carboxamides with Amidomagnesium Chlorides

  1995cited by this paper
• Regioselective Metalation of Pyridinylcarbamates and Pyridinecarboxamides with (2,2,6,6-Tetramethylpiperidino)magnesium Chloride

  1995cited by this paper
• Regioselective monometalation of 2,5‐pyridinedicarboxamides with (2,2,6,6‐tetramethylpiperidino)magnesium chloride (TMPMgCI)

  1995cited by this paper
• Magnesium amide bases and amido-Grignards. 1. Ortho magnesiation

  1989cited by this paper
• Condensations of Esters by Diisopropylaminomagnesium Bromide and Certain Related Reagents

  1949cited by this paper
• Condensation of Certain Esters by Means of Diethylaminomagnesium Bromide1,2

  1947cited by this paper

• No citing papers are available for this paper.