Transition‐Metal‐Catalyzed α,β‐Dehydrogenation of Carbonyl Compounds

α,β‐Unsaturated compounds are one of the most important functional compounds. Due to their unique property and versatile utility, they usually occur as the key intermediates for the synthesis of pharmaceuticals and biological materials. Thus, their synthesis has attracted more attentions than before. The early approaches to α,β‐unsaturated compounds are mainly about transition‐metal‐free methods, such as halogenation‐dehydrohalogenation methods and strong oxidants methods (organosulfur, organoselenium, benzoquinone). Subsequently, palladium and the other transition‐metals catalyzed dehydrogenation of carbonyl compounds appeared respectively. In this review, transition‐metal‐catalyzed α,β‐dehydrogenation is discussed, which is categorized by functional groups.

• Publication year

  2024

• Venue

  Annalen der Pharmacie

• Publication date

  2024-02-14

• Fields of study

  Not labeled

• Identifiers
  DOI 10.1002/ejoc.202301267
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

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