Iodine Chemistry and its Role in Halogen Activation and Ozone Loss in the Marine Boundary Layer: A Model Study

No abstract is available for this paper.

• Publication year

  1999

• Venue

  Journal of Atmospheric Chemistry

• Publication date

  1999-03-01

• Fields of study

  Chemistry, Environmental Science

• Identifiers
  DOI 10.1023/A:1006179901037
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Ultraviolet-Visible Absorption Cross Sections of Gaseous HOI and Its Photolysis at 355 nm

  1998cited by this paper
• Ultraviolet—Visible Absorption Cross Sections of Gaseous HOI and Its Photolysis at 355 nm.

  1998cited by this paper
• Temperature dependence of UV absorption cross sections and atmospheric implications of several alkyl iodides

  1997cited by this paper
• The BrO + Ch3O2 reaction: Kinetics and role in the atmospheric ozone budget

  1997cited by this paper
• Absorption Cross Sections and Self-Reaction Kinetics of the IO Radical

  1997cited by this paper
• Bromine, iodine, and chlorine in single aerosol particles at Cape Grim

  1997cited by this paper
• Kinetics and Mechanism of the IO + ClO Reaction

  1997cited by this paper
• KINETICS OF DISPROPORTIONATION OF HYPOIODOUS ACID AT HIGH PH, WITH AN EXTRAPOLATION TO RAINWATER

  1997cited by this paper
• INVESTIGATION OF THE UPTAKE RATE OF OZONE AND METHYL HYDROPEROXIDE BY WATER SURFACES

  1997cited by this paper
• A mechanism for halogen release from sea-salt aerosol in the remote marine boundary layer

  1996influential reference
• RATE CONSTANTS FOR REACTIONS BETWEEN IODINE- AND CHLORINE-CONTAINING SPECIES : A DETAILED MECHANISM OF THE CHLORINE DIOXIDE/CHLORITE-IODIDE REACTION

  1996cited by this paper
• Kinetics and Mechanism of the Complex Bromate−Iodine Reaction1

  1996cited by this paper
• Potential impact of iodine on tropospheric levels of ozone and other critical oxidants

  1996influential reference
• Model study indicating halogen activation and ozone destruction in polluted air masses transported to the sea

  1996influential reference
• Determination of organic, inorganic and particulate iodine in the coastal atmosphere of Japan

  1995cited by this paper
• The atmospheric chemistry of iodine monoxide

  1995cited by this paper
• Iodine speciation in size fractionated atmospheric particles by isotope dilution mass spectrometry

  1995cited by this paper
• Absorption cross sections, kinetics of formation, and self-reaction of the IO radical produced via the laser photolysis of N2O/I2/N2 mixtures

  1995cited by this paper
• On the role of iodine in ozone depletion

  1994cited by this paper
• Ozone depletion and global warming potentials of CF3I

  1994cited by this paper
• GC determination of volatile organoiodine and organobromine compounds in Arctic seawater and air samples

  1993influential reference
• Determinations of methyl iodide in the Antarctic atmosphere and the South Polar Sea

  1992cited by this paper
• Inorganic gas-phase reactions of the nitrate radical: iodine + nitrate radical and iodine atom + nitrate radical

  1992cited by this paper
• Chemical kinetics and photochemical data for use in stratospheric modeling

  1992cited by this paper
• Inorganic Gas-Phase Reactions of the Nitrate Radical: I2 + NO3 and I + NO3.

  1992cited by this paper
• Non-metal redox kinetics: iodine monobromide reaction with iodide ion and the hydrolysis of IBr

  1991cited by this paper
• Non-metal redox kinetics: hypobromite and hypobromous acid reactions with iodide and with sulfite and the hydrolysis of bromosulfate

  1991cited by this paper
• Bifurcation analysis of chemical reaction mechanisms. I, Steady state bifurcation structure

  1991cited by this paper
• Are there interactions of iodine and sulfur species in marine air photochemistry

  1990cited by this paper
• On the disproportionate role of tropospheric ozone as a filter against solar UV‐B radiation

  1989cited by this paper
• Kinetics of hydrolysis of iodine monochloride measured by the pulsed-accelerated-flow method

  1989cited by this paper
• Nonmetal redox kinetics: oxidation of iodide by hypochlorous acid and by nitrogen trichloride measured by the pulsed-accelerated-flow method

  1988cited by this paper
• Non-Metal Redox Kinetics: Oxidation of Iodide by Hypochlorous Acid and by Nitrogen Trichloride Measured by the Pulsed-Accelerated-Flow Method.

  1988cited by this paper
• Systematic design of chemical oscillators. 43. Mechanistic study of a coupled chemical oscillator: the bromate-chlorite-iodide reaction

  1988cited by this paper
• Reactions of iodine intermediates in iodate-hydrogen peroxide oscillators

  1987cited by this paper
• Chemistry of organic traces in air

  1986influential reference
• Photochemical aspects of tropospheric iodine behaviour

  1985cited by this paper
• The hydrolysis of iodine: Equilibria at high temperatures

  1985cited by this paper
• Atmospheric methyl iodide

  1985cited by this paper
• Methyl halides in and over the eastern Pacific (40°N–32°S)

  1983influential reference
• Atmospheric methyl iodide (CH3I)

  1982cited by this paper
• A Fundamental Equation of State for Heavy Water

  1982cited by this paper
• The NBS tables of chemical thermodynamic properties : selected values for inorganic and C1 and C2 organic substances in SI units

  1982cited by this paper
• Halogens in the atmosphere

  1981cited by this paper
• Iodine - Its possible role in tropospheric photochemistry

  1980cited by this paper
• Diurnal fluctuations of Br and I in the tropical marine atmosphere

  1980influential reference
• Tropospheric Halogen Gases: Inorganic and Organic Components

  1976cited by this paper
• Resolution of the visible‐infrared absorption spectrum of I2 into three contributing transitions

  1973cited by this paper
• Gaseous and particulate iodine in the marine atmosphere

  1972cited by this paper
• The Continuous Absorption Spectra of Chlorine, Bromine, Bromine Chloride, Iodine Chloride, and Iodine Bromide

  1964influential reference
• The Kinetics of Halogen Hydrolysis

  1962influential reference

• Aerosol iodine recycling is a major control on tropospheric reactive iodine abundance

  2026cites this paper
• Reactive halogens in polluted atmospheres: Sources, processes, and impacts on secondary pollutants

  2026cites this paper
• Theoretical study on the excited states of ICl+ molecular ion including spin-orbit coupling

  2025cites this paper
• Halogenated Organic Compounds: A Massive Halogen Reservoir and an Intriguing Component of the Marine Dissolved Organic Matter Pool

  2025cites this paper
• Review of iodine behavior from nuclear fuel dissolution to environmental release

  2024influential citation
• Depletion of iodide in ageing aerosols and the role of humidity: A case study of mixed sodium iodide-malonic acid aerosol.

  2024cites this paper
• Inorganic iodine and bromine speciation in Arctic snow at picogram-per-grams levels by IC-ICP-MS

  2024cites this paper
• An improved estimate of inorganic iodine emissions from the ocean using a coupled surface microlayer box model

  2024cites this paper
• Observational Evidence of Unknown NOx Source and Its Perturbation of Oxidative Capacity in Bermuda's Marine Boundary Layer

  2023cites this paper
• Observations of iodine monoxide (IO) columns from satellite

  2023influential citation
• Iodide sources in the aquatic environment and its fate during oxidative water treatment - A critical review.

  2022cites this paper
• Role of Iodine Recycling on Sea‐Salt Aerosols in the Global Marine Boundary Layer

  2022cites this paper
• Computational chemistry of cluster: Understanding the mechanism of atmospheric new particle formation at the molecular level.

  2022cites this paper
• The influence of a single water molecule on the reaction of IO + HONO

  2022cites this paper
• Fundamental oxidation processes in the remote marine atmosphere investigated using the NO–NO2–O3 photostationary state

  2022cites this paper
• Formation of halogenated macromolecular organics induced by Br- and I- during plasma oxidation/chlorination of DOM: Highlighting competitive mechanisms.

  2022cites this paper
• Vertical profiles of trace gases in the troposphere over South Asia

  2022cites this paper
• Environmental iodine speciation quantification in seawater and snow using ion exchange chromatography and UV spectrophotometric detection.

  2022cites this paper
• On the Speciation of Iodine in Marine Aerosol

  2022cites this paper
• The gas-phase formation mechanism of iodic acid as an atmospheric aerosol source

  2022cites this paper
• Fundamental Oxidation Processes in the Remote 1 Marine Atmosphere Investigated Using the NO- 2 NO 2 -O 3 Photostationary State 3

  2022influential citation
• Verification of the Atmospheric Infrared Sounder (AIRS) and the Microwave Limb Sounder (MLS) ozone algorithms based on retrieved daytime and night-time ozone

  2021cites this paper
• Soluble Iodine Speciation in Marine Aerosols Across the Indian and Pacific Ocean Basins

  2021cites this paper
• Iodine chemistry in the chemistry-climate model SOCOL-AERv2-iodine

  2021cites this paper
• Direct field evidence of autocatalytic iodine release from atmospheric aerosol

  2021cites this paper
• On the speciation of iodine in aerosol

  2021influential citation
• Measurement report: Indirect evidence for the controlling influence of acidity on the speciation of iodine in Atlantic aerosols

  2021cites this paper
• Measurements of Line Intensities and Self-broadening Coefficients in the ν2 Band of CH3I

  2021cites this paper
• Marine aerosol properties over the Southern Ocean in relation to the wintertime meteorological conditions

  2021cites this paper
• Estimation of reactive inorganic iodine fluxes in the Indian and Southern Ocean marine boundary layer

  2020cites this paper
• This is a repository copy of Estimation of Reactive Inorganic Iodine Fluxes in the Indian and Southern Ocean Marine Boundary Layer

  2020cites this paper
• Quantitative detection of iodine in the stratosphere

  2020cites this paper
• Verification of the AIRS and MLS ozone algorithms based on retrieved daytime and nighttime ozone

  2020cites this paper
• Spatial and Temporal Variability of Iodine in Aerosol

  2020cites this paper
• Global high-resolution emissions of soil NOx, sea salt aerosols, and biogenic volatile organic compounds

  2020cites this paper
• Treatment of non-ideality in the SPACCIM multiphase model – Part 2: Impacts on the multiphase chemical processing in deliquesced aerosol particles

  2020cites this paper
• Transport of short-lived halocarbons to the stratosphere over the Pacific Ocean

  2020cites this paper
• on biogenically driven new particle formation in Svalbard ( SVALBAEROSOL ) 168

  2020cites this paper
• Unraveling the Tropospheric Microhydration Processes of Iodous Acid HOIO

  2020cites this paper
• Formation of highly excited iodine atoms from multiphoton excitation of CH3I.

  2020cites this paper
• Treatment of non-ideality in the multiphase model SPACCIM-Part2: Impacts on the multiphase chemical processing in deliquesced aerosol particles

  2019cites this paper
• Halogen activation and radical cycling initiated by imidazole-2-carboxaldehyde photochemistry

  2019cites this paper
• IO(X2Π)-Ar cluster: ab initio potential energy surface and dynamical computations.

  2019cites this paper
• Absorption spectra at the iodine 3d ionisation threshold following the CHxI+ (x = 0-3) cation sequence.

  2019cites this paper
• Nitrite-Induced Activation of Iodate into Molecular Iodine in Frozen Solution.

  2019cites this paper
• Photodissociation of CH2BrI using cavity ring-down spectroscopy: in search of a BrI elimination channel.

  2019cites this paper
• Volatile halocarbon measurements in the marine boundary layer at Cape Point, South Africa

  2019cites this paper
• Influence of collection substrate and extraction method on the speciation of soluble iodine in atmospheric aerosols

  2019cites this paper
• Evidence for renoxification in the tropical marine boundary layer

  2018cites this paper
• Review of Incoherent Broadband Cavity-Enhanced Absorption Spectroscopy (IBBCEAS) for Gas Sensing

  2018cites this paper
• Reactive nitrogen in the troposphere

  2017cites this paper
• Evidence for renoxification in the tropical marine boundary layer

  2017cites this paper
• Modelling of atmospheric chlorine and its effect on volatile organic compounds

  2017cites this paper
• From the measurement of halogenated species to iodine particle formation

  2017cites this paper
• Reactivity of Hydrogen Peroxide with Br and I Atoms.

  2017cites this paper
• Elemental mercury: Its unique properties affect its behavior and fate in the environment.

  2017cites this paper
• Investigation of the Halogenate-Hydrogen Peroxide Reactions Using the Electron Paramagnetic Resonance Spin Trapping Technique.

  2017cites this paper
• Thermochemistry of HIO2 Species and Reactivity of Iodous Acid with OH Radical: A Computational Study

  2017cites this paper
• Extending the Community Multiscale Air Quality (CMAQ) Modeling System to Hemispheric Scales: Overview of Process Considerations and Initial Applications.

  2017cites this paper
• Sulfate production by reactive bromine: Implications for the global sulfur and reactive bromine budgets

  2017cites this paper
• Impacts of bromine and iodine chemistry on tropospheric OH and HO 2 : Comparing observations with box and global model perspectives

  2017influential citation
• Impact of Wildfire Emissions on Chloride and Bromide Depletion in Marine Aerosol Particles.

  2017cites this paper
• Transport of very short-lived substances from the Indian Ocean to the stratosphere through the Asian monsoon

  2017cites this paper
• Concentrations of iodine isotopes ((129)I and (127)I) and their isotopic ratios in aerosol samples from Northern Germany.

  2016cites this paper
• Volcanic plume fingerprint in the groundwater of a persistently degassing basaltic volcano: Mt. Etna

  2016cites this paper
• Studies of Arctic Tropospheric Ozone Depletion Events Through Buoy-Borne Observations and Laboratory Studies

  2016cites this paper
• Complete Bibliography of the Writings of Paul J. Crutzen (1965–2015)

  2016cites this paper
• Study on variability of sea salt aerosol in the North Indian ocean

  2016cites this paper
• Photodissociation dynamics of ICH2Cl → CH2Cl + I*/I: photofragment translational spectroscopy at 304 and 277 nm.

  2016cites this paper
• The Linoleic-to-Linolenic Dietary Intake Ratio: The Fundamental Implications of Imbalance and Excess Looked at from Both a Functional and an Evolutionary Perspective: An Overview

  2016cites this paper
• Global impacts of tropospheric halogens (Cl, Br, I) on oxidants and composition in GEOS-Chem

  2016cites this paper
• State interactions, excitation dynamics, hidden states and photofragmentation pathways in hydrogen halides

  2016cites this paper
• Halogen Radical Chemistry at Aqueous Interfaces.

  2016cites this paper
• A Density Functional Theory and ab Initio Investigation of the Oxidation Reaction of CO by IO Radicals.

  2016cites this paper
• Development of single microdroplet techniques for fundamental chemical measurements

  2016cites this paper
• Space-based observation of volcanic iodine monoxide

  2016influential citation
• Understanding the impact of marine iodine chemistry on climate and air quality

  2016cites this paper
• The Background of an Ozone Researcher: A Brief Autobiography

  2016cites this paper
• A global model of tropospheric chlorine chemistry: Organic versus inorganic sources and impact on methane oxidation

  2016cites this paper
• Corrigendum to “Iodine’s impact on tropospheric oxidants: a global model study in GEOS-Chem” published in Atmos. Chem. Phys., 16, 1161–1186, 2016

  2016cites this paper
• Perspective: Spectroscopy and kinetics of small gaseous Criegee intermediates.

  2015cites this paper
• Impact of atmospheric species reactivity on radioactive gaseous iodine transport in severe accident conditions

  2015cites this paper
• Speciation of 127I and 129I in atmospheric aerosols at Risø, Denmark: insight into sources of iodine isotopes and their species transformations

  2015influential citation
• Infrared absorption of iodomethylperoxy (syn-ICH2OO) radical generated upon photolysis of CH2I2 and O2 in solid para-H2

  2015cites this paper
• Speciation of 127 I and 129 I in atmospheric aerosols at Risø, Denmark: insight into sources of iodine isotopes and their species transformations

  2015influential citation
• Iodine's impact on tropospheric oxidants: a global model study in GEOS-Chem

  2015influential citation
• Iodine speciation in aerosol particle samples collected over the sea between offshore China and the Arctic Ocean

  2015cites this paper
• Simultaneous infrared detection of the ICH2OO radical and Criegee intermediate CH2OO: the pressure dependence of the yield of CH2OO in the reaction CH2I + O2.

  2015cites this paper
• Specificity and Variation of Length Scale over Which Monovalent Halide Ions Neutralize a Charged Interface

  2015cites this paper
• A mechanism for biologically-induced iodine emissions from sea-ice

  2015cites this paper
• A mechanism for biologically-induced iodine emissions from sea-ice

  2015cites this paper
• Speciation Analysis of (129)I and (127)I in Aerosols Using Sequential Extraction and Mass Spectrometry Detection.

  2015cites this paper
• BIOGEOCHEMICAL CYCLES | Iodine

  2015cites this paper
• Chemistry and release of gases from the surface ocean.

  2015cites this paper
• 33. Atmospheric Chemistry of Iodine

  2014cites this paper
• Short-Lived Trace Gases in the Surface Ocean and the Atmosphere

  2014cites this paper
• A framework for the extraction and interpretation of organic molecules in speleothem carbonate.

  2014cites this paper
• Aircraft-borne DOAS limb observations of UV/visible absorbing trace gas species over Borneo:Implications for the photochemistry of iodine, volatile organic oxide degradation, and lightning-produced radicals

  2014cites this paper
• Extremely rapid self-reaction of the simplest Criegee intermediate CH2OO and its implications in atmospheric chemistry.

  2014cites this paper
• The distribution of iodide at the sea surface.

  2014cites this paper