A coordination compound of Ge(0) stabilized by a diiminopyridine ligand.

No abstract is available for this paper.

• Publication year

  2014

• Venue

  Angewandte Chemie

• Publication date

  2014-03-03

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1002/anie.201309421PMID 24488623
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• The role of 2,6-diaminopyridine ligands in the isolation of an unprecedented, low-valent tin complex.

  2013cited by this paper
• A stable singlet biradicaloid siladicarbene: (L:)2Si.

  2013cited by this paper
• Acyclic germylones: congeners of allenes with a central germanium atom.

  2013cited by this paper
• Ein cyclisches Silylon (“Siladicarben”) mit einem elektronenreichen Silicium(0)‐Atom

  2013cited by this paper
• Ein stabiles biradikaloides Singulett‐Siladicarben: (L:)2Si

  2013cited by this paper
• A cyclic silylone ("siladicarbene") with an electron-rich silicon(0) atom.

  2013cited by this paper
• A cyclic germadicarbene ("germylone") from germyliumylidene.

  2013cited by this paper
• Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes

  2012cited by this paper
• Lewis base mediated autoionization of GeCl2 and SnCl2.

  2012cited by this paper
• The syntheses and electrochemical studies of a ferrocene substituted diiminopyridine ligand and its P, S, Se, and Te complexes.

  2012cited by this paper
• Group 14 hydrides with low valent elements for activation of small molecules.

  2012cited by this paper
• An N-heterocyclic carbene adduct of diatomic tin, :Sn=Sn:.

  2012cited by this paper
• Carbodiphosphorane analogues E(PPh3)2 with E=C-Pb: a theoretical study with implications for ligand design.

  2012cited by this paper
• N-heterocyclic carbene analogues with low-valent group 13 and group 14 elements: syntheses, structures, and reactivities of a new generation of multitalented ligands.

  2011cited by this paper
• Synthesis and Striking Reactivity of an Isolable Tetrasilyl-Substituted Trisilaallene

  2011cited by this paper
• Substitution matters: isolating phosphorus diiminopyridine complexes.

  2011cited by this paper
• Synthesis and Characterization of a Neutral Tricoordinate Organoboron Isoelectronic with Amines

  2011cited by this paper
• A neutral, monomeric germanium(I) radical.

  2011cited by this paper
• An isolable dialkylsilylene and its derivatives. A step toward comprehension of heavy unsaturated bonds.

  2010cited by this paper
• Unusual bonding in trisilaallene and related heavy allenes.

  2009cited by this paper
• Divalent E(0) compounds (E = Si-Sn).

  2009cited by this paper
• Reversible Reactions of Ethylene with Distannynes Under Ambient Conditions

  2009cited by this paper
• N-heterocyclic carbene stabilized digermanium(0).

  2009cited by this paper
• Reactivity of the Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) toward Nitriles: Unexpected Formation of Triaza-1,4-disilabicyclo[2.2.2]octa-2,5,7-triene Derivatives

  2009cited by this paper
• Divalent silicon(0) compounds.

  2009cited by this paper
• Reactivity of the disilyne RSi[triple bond]SiR (R = Si(i)Pr[CH(SiMe3)2]2) toward silylcyanide: two pathways to form the bis-adduct [RSiSiR(CNSiMe3)2] with some silaketenimine character and a 1,4-diaza-2,3-disilabenzene analogue.

  2008cited by this paper
• A Stable Silicon(0) Compound with a Si=Si Double Bond

  2008cited by this paper
• Divalent carbon(0) chemistry, part 1: Parent compounds.

  2008cited by this paper
• Covalent radii revisited.

  2008cited by this paper
• C(NHC)2: zweibindige Kohlenstoff(0)‐Verbindungen mit N‐heterocyclischen Carbenliganden – theoretische Belege für eine Molekülklasse mit vielversprechenden Eigenschaften

  2007cited by this paper
• C(NHC)2: divalent carbon(0) compounds with N-heterocyclic carbene ligands-theoretical evidence for a class of molecules with promising chemical properties.

  2007cited by this paper
• Bonding and Reactivity of Heavier Group 14 Element Alkyne Analogues

  2007cited by this paper
• EasySpin, a comprehensive software package for spectral simulation and analysis in EPR.

  2006cited by this paper
• Trisilaallene and the Relative Stability of Si3H4 Isomers.

  2006cited by this paper
• Solid-state (29)Si NMR study of RSiSiR: a tool for analyzing the nature of the Si-Si bond.

  2006cited by this paper
• Trigermaallene and 1,3-Digermasilaallene

  2005cited by this paper
• A missing allene of heavy Group 14 elements: 2-germadisilaallene.

  2005cited by this paper
• Facile activation of dihydrogen by an unsaturated heavier main group compound.

  2005cited by this paper
• Reactions of the heavier group 14 element alkyne analogues Ar'EEAr' (Ar' = C6H3-2,6(C6H3-2,6-Pri2)2; E = Ge, Sn) with unsaturated molecules: probing the character of the EE multiple bonds.

  2005cited by this paper
• Preparation and molecular and electronic structures of iron(0) dinitrogen and silane complexes and their application to catalytic hydrogenation and hydrosilation.

  2004cited by this paper
• A Stable Compound Containing a Silicon-Silicon Triple Bond

  2004cited by this paper
• The Silicon Hydride Clusters Si3Hn (n ≤ 8) and Their Anions: Structures, Thermochemistry, and Electron Affinities

  2004cited by this paper
• A stable silicon-based allene analogue with a formally sp-hybridized silicon atom

  2003cited by this paper
• Synthesis and characterization of a digermanium analogue of an alkyne.

  2002cited by this paper
• Bindungen mit ungerader Elektronenzahl und Biradikale in der Chemie der Hauptgruppenelemente

  2002cited by this paper
• Odd-electron bonds and biradicals in main group element chemistry.

  2002cited by this paper
• Stable silylenes.

  2000cited by this paper
• Synthesis and Characterization of 2,6-Trip2H3C6PbPbC6H3-2,6-Trip2 (Trip = C6H2-2,4,6-i-Pr3): A Stable Heavier Group 14 Element Analogue of an Alkyne

  2000cited by this paper
• Tetrasupersilyl‐tristannaallene and ‐tristannacyclopropene (tBu3Si)4Sn3 – Isomers with the Shortest Sn=Sn Double Bonds to Date

  1999cited by this paper
• IRON AND COBALT ETHYLENE POLYMERIZATION CATALYSTS BEARING 2,6-BIS(IMINO)PYRIDYL LIGANDS : SYNTHESIS, STRUCTURES, AND POLYMERIZATION STUDIES

  1999cited by this paper
• Homonuclear multiple bonding in heavier main group elements

  1998cited by this paper

• Utilization of a Chelating Bis[(dialkylamino)cyclopropenimine] to Isolate a Series of Heavier Zero‐Valent Group 14 Tetracarbonyl Iron Complexes

  2025cites this paper
• Isolable zero-valent Ditin(0) and Diplumbum(0) complexes

  2025cites this paper
• Recent Advances in the Synthesis, Structural Characterization, and Reactivity of Zero-Valent Main Group Compounds ★

  2025cites this paper
• sp-Hybridized Seesaw Ge0 Complexes via Germylone-to-Seesaw Isomerization in a Four-Electron Cyclic N2Ge2 Ligand

  2025cites this paper
• Reductive Deamination of a Diaminogermylene Promoted by an Aluminyl Anion: Isolation of Ge(I), Ge(0) and Ge(-I) Products.

  2025cites this paper
• Conformational and electronic variability of N,N',O-ligand documented on its coordination to main group halides.

  2025cites this paper
• Carboranyl diphosphenes: synthesis, structure and reactivity.

  2025cites this paper
• Cationic ligands - from monodentate to pincer systems.

  2024cites this paper
• Reversible Redox Ligand-Centered Reactivity in 2,6-Bisiminopyridine Aluminum Systems

  2024cites this paper
• Bisgermylene-Stabilized Stannylone: Catalytic Reduction of Nitrous Oxide and Nitro Compounds via Element-Ligand Cooperativity.

  2024cites this paper
• Understanding How Metal–Ligand Coordination Enables Solvent Free Ionic Conductivity in PDMS

  2023cites this paper
• MOF Composites as high Potential Materials for Hazardous Organic Contaminants Removal in Aqueous Environments

  2023cites this paper
• Structural Diversity in Divalent Group 14 Triflate Complexes Involving Endocyclic Thia-Macrocyclic Coordination

  2023cites this paper
• Ligand-enforced geometric constraints and associated reactivity in p-block compounds.

  2023cites this paper
• Unveiling the Anomaly of Reduction of Carborane-bis-silylene Stabilized Silylone/Germylone leading to Unusual Oxidation of Si0/Ge0 to SiI/GeI with EDA-NOCV Analyses.

  2023cites this paper
• Germanium Analogue of the Parent Phosphine-Borane FLP compound.

  2023cites this paper
• A crystalline T-shaped planar group 14 anion

  2023cites this paper
• A Guanidine-Supported π-Complex of Germanium Amenable to Intramolecular C-C Cleavage in Arene and Ge Atom Transfer.

  2023cites this paper
• Synthesis, Structural Characterization and Coordination Chemistry of a NHC-stabilized Iminoborane.

  2023cites this paper
• An Isolable Bis(Germylene)-Stabilized Plumbylone.

  2022cites this paper
• Computational Insights into Hydroboration with Acyclic α-Borylamido-Germylene and Stannylene Catalysts: Cooperative Dual Catalysis the Key to System Efficiency

  2022cites this paper
• Investigating the Reactions of BiCl3, a Diiminopyridine Ligand, and Trimethylsilyl Trifluoromethanesulfonate

  2022cites this paper
• Oxidative Additions of C−F Bonds to the Silanide Anion [Si(C2F5)3]−

  2022cites this paper
• Base-stabilized formally zero-valent mono and diatomic molecular main-group compounds.

  2022cites this paper
• Stabilization of Interstellar CSi2 Species by Donor Base Ligands: L-CSi2-L; L = cAACMe, NHCMe, and PMe3.

  2022cites this paper
• Neutral and charged group 13–16 homologs of carbones EL2 (E = B−–In−; Si–Pb; N+–Bi+, O2+–Te2+)

  2022cites this paper
• Enabling Tunable Water‐Responsive Surface Adaptation of PDMS via Metal–Ligand Coordinated Dynamic Networks

  2022cites this paper
• Isolation and Reactivity of Tetrylene‐Tetrylone‐Iron Complexes Supported by Bis(N‐Heterocyclic Imine) Ligands

  2022cites this paper
• Unique reactivity of an α-ketiminopyridine ligand with metal–alkyls: Synthesis and ROP of ε-caprolactone

  2021cites this paper
• Complexes of Dichlorogermylene with Phosphine/Sulfoxide-Supported Carbone as Ligand †

  2021cites this paper
• New Types of Ge2 and Ge4 Assemblies Stabilized by a Carbanionic Dicarborandiyl-Silylene Ligand.

  2021cites this paper
• Changing the Reactivity of Zero‐ and Mono‐Valent Germanium with a Redox Non‐Innocent Bis(silylenyl)carborane Ligand

  2021cites this paper
• Coordination Chemistry of Methandiides and Related Ligands

  2021cites this paper
• Heavier element-containing aromatics of [4n+2]-electron systems.

  2021cites this paper
• Low‐Valent Germanylidene Anions: Efficient Single‐Site Nucleophiles for Activation of Small Molecules

  2021cites this paper
• Entering new chemical space with isolable complexes of single, zero-valent silicon and germanium atoms.

  2021cites this paper
• Compound with possible N → N coordination bond: Synthesis, crystal structure and electronic structure analysis

  2021cites this paper
• Antimony diiminopyridine complexes.

  2021cites this paper
• Valence Tautomerism of p‐Block Element Compounds – An Eligible Phenomenon for Main Group Catalysis?

  2021cites this paper
• A Non-innocent Ligand Supported Germylene and Its Diverse Reactions

  2020cites this paper
• (N),C,N-Coordinated Heavier Group 13-15 Compounds: Synthesis, Structure and Applications.

  2020cites this paper
• Reactions of BCl3 with Diiminopyridine Ligands

  2020cites this paper
• Ge(0) compound stabilized by a diimino-carbene ligand: synthesis and ambiphilic reactivity.

  2020cites this paper
• Isolation and Reactivity of Chlorotetryliumylidenes Using a Bidentate Bis(N-heterocyclic imine) Ligand

  2020cites this paper
• Diiminepyridine-Supported Phosphorus(I) and Phosphorus(III) Complexes: Synthesis, Characterization, and Electrochemistry

  2020cites this paper
• In-Depth Investigation of a Donor–Acceptor Interaction on the Heavy-Group-14@Group-13-Diyls in Transition-Metal Tetrylone Complexes: Structure, Bonding, and Property

  2020cites this paper
• Divalent NI Compounds: Identifying new Carbocyclic Carbenes to Design Nitreones using Quantum Chemical Methods

  2020cites this paper
• Stabilization of Linear C3 by Two Donor Ligands: A Theoretical Study of L‐C3‐L (L=PPh3, NHCMe, cAACMe)

  2020cites this paper
• Revisiting the Bonding Scenario of Two Donor Ligand Stabilized C2 Species.

  2020cites this paper
• Germylone-bridged bimetallic Ir and Rh complexes.

  2019cites this paper
• 2,6-Bis(benzimidazol-2-yl)pyridines as more electron-rich and sterically accessible alternatives to 2,6-bis(imino)pyridine for group 13 coordination chemistry.

  2019cites this paper
• Enols, Diamino Enols, and Breslow Intermediates: A Comparative Quantum Chemical Analysis

  2019cites this paper
• Structural characteristics of redox-active pyridine-1,6-diimine complexes: Electronic structures and ligand oxidation levels

  2019cites this paper
• 2,6-Bis(benzimidazol-2-yl)pyridine complexes of group 14 elements.

  2019cites this paper
• Carbones and Heavier Ylidones (EL2) in Frustrated Lewis Pair Chemistry: Influence of the Nature of EL2 on Dihydrogen Activation.

  2019cites this paper
• Donor→acceptor coordination interactions in 1,3‐bis(NHC)triazenyl Cations: An electronic structure analysis

  2019cites this paper
• 2,6-Bis(diazaboryl)pyridine - A Ligand with Hemilabile Donor and Lewis Acid Functionalities

  2019cites this paper
• Superhydrophobic/Superoleophilic MOF Composites for Oil-Water Separation.

  2019cites this paper
• Hafnocene-based Bicyclo[2.1.1]hexene Germylenes - Formation, Reactivity, and Structural Flexibility.

  2018cites this paper
• Mono- and Dicoordinate Germanium(0) as a Four-Electron Donor.

  2018cites this paper
• Neutral and anionic zinc compounds supported by a bis(imino)phenyl NCN ligand.

  2018cites this paper
• Oxidative Addition and Reductive Elimination at Main-Group Element Centers.

  2018cites this paper
• Can Remote N-Heterocyclic Carbenes Coordinate with Main Group Elements? Synthesis, Structure, and Quantum Chemical Analysis of N+ -Centered Complexes.

  2018cites this paper
• Dative versus electron-sharing bonding in N-oxides and phosphane oxides R3EO and relative energies of the R2EOR isomers (E = N, P; R = H, F, Cl, Me, Ph). A theoretical study.

  2018cites this paper
• Tetrylones: An Intriguing Class of Monoatomic Zero-valent Group 14 Compounds.

  2018cites this paper
• NL2+ Systems as New-Generation Phase-Transfer Catalysts.

  2018cites this paper
• Reversible Carbene Insertion into a Ge-N Bond and Insights into CO and Carbene Substitution Reactions Involving Amidinatogermylenes and Fischer Carbene Complexes.

  2018cites this paper
• Imino-stabilised phosphinidene (or azaphosphole?) and some of its derivatives.

  2018cites this paper
• An Isolable Bis(silylene)-Stabilized Germylone and Its Reactivity.

  2018cites this paper
• Nickel precursors based on diamagnetic and paramagnetic di(imine)pyridine ligands for magnetic materials: Synthesis, X-ray structures and magnetic studies

  2018cites this paper
• Isolation and Reactivity of a Chlorogermyliumylidene Featuring Two Ge–Cl Units

  2018cites this paper
• Bis(chlorogermyliumylidene) and its significant role in elusive reductive cyclization.

  2018cites this paper
• Ligand-Supported E3 Clusters (E=Si-Sn).

  2017cites this paper
• Carbones as Ligands in Novel Main-Group Compounds E[C(NHC)2 ]2 (E=Be, B+ , C2+ , N3+ , Mg, Al+ , Si2+ , P3+ ): A Theoretical Study.

  2017cites this paper
• A New Area in Main-Group Chemistry: Zerovalent Monoatomic Silicon Compounds and Their Analogues.

  2017cites this paper
• Compounds of potassium and tin(II) with diiminopyridine ligands: EPR spectroscopy and theoretical study

  2017cites this paper
• Biomimetic Superhydrophobic/Superoleophilic Highly Fluorinated Graphene Oxide and ZIF-8 Composites for Oil-Water Separation.

  2016cites this paper
• Synthesis, characterization, and electronic structures of a methyl germyliumylidene ion and germylone-group VI metal complexes.

  2016cites this paper
• Homolytic, Heterolytic, Mesolytic - As You Like It: Steering the Cleavage of a HC(sp3 )-C(sp3 )H Bond in Bis(1H-2,1-benzazaborole) Derivatives.

  2016cites this paper
• Biomimetische superhydrophobe/superoleophile hoch fluorierte Graphenoxid‐ZIF‐8‐Komposite für die Öl‐Wasser‐Trennung

  2016cites this paper
• Carbene →N+ Coordination Bonds in Drugs: A Quantum Chemical Study

  2016cites this paper
• On the nature of the dative bond: Coordination to metals and beyond. The carbon case

  2016cites this paper
• Design, Synthesis, and Structural Analysis of Divalent N(I) Compounds and Identification of a New Electron-Donating Ligand.

  2016cites this paper
• Computational Study of Formic Acid Dehydrogenation Catalyzed by Al(III)-Bis(imino)pyridine.

  2016cites this paper
• A theoretical study on the unusual square-planar structure of bis(imino)pyridine-ligated Group 13 complexes.

  2016cites this paper
• A Bis(silylenyl)pyridine Zero-Valent Germanium Complex and Its Remarkable Reactivity.

  2016cites this paper
• Bonding Analysis of Ylidone Complexes EL2 (E = C – Pb) with Phosphine and Carbene Ligands L

  2016cites this paper
• Unique molecular geometries of reduced 4- and 5-coordinate zinc complexes stabilised by diiminopyridine ligand.

  2016cites this paper
• Stabilization of heterodiatomic SiC through ligand donation: theoretical investigation of SiC(L)2 (L=NHC(Me) , CAAC(Me) , PMe3 ).

  2015cites this paper
• From Dibismuthenes to Three- and Two-Coordinated Bismuthinidenes by Fine Ligand Tuning: Evidence for Aromatic BiC3N Rings through a Combined Experimental and Theoretical Study.

  2015cites this paper
• Reactivity of N,C,N-Chelated Antimony(III) and Bismuth(III) Chlorides with Lithium Reagents: Addition vs Substitution

  2015cites this paper
• Progression of Diiminopyridines: From Single Application to Catalytic Versatility

  2015cites this paper
• Stabilisierung von heterodiatomarem SiC durch Donorliganden – theoretische Untersuchung von SiC(L)2 (L=NHCMe, CAACMe, PMe3)†

  2015cites this paper
• A Molecular Complex with a Formally Neutral Iron Germanide Motif (Fe2Ge2)

  2015cites this paper
• Eine mehrfach funktionalisierte Basen‐koordinierte GeII‐Verbindung und ihre reversible Dimerisierung zum Digermen

  2015cites this paper
• Antimony(III) and bismuth(III) amides containing pendant N-donor groups--a combined experimental and theoretical study.

  2015cites this paper
• The fate of NHC-stabilized dicarbon.

  2015cites this paper
• A multiply functionalized base-coordinated Ge(II) compound and its reversible dimerization to the digermene.

  2015cites this paper
• Spectroscopic Distinction of Different Carbon Bases: An Insight from Theory.

  2015cites this paper
• Silavinylidene stabilized by an N-heterocyclic carbene: a theoretically predicted stable molecule.

  2014cites this paper