3-Silylated cyclohexa-1,4-dienes as precursors for gaseous hydrosilanes: the B(C6 F5)3-catalyzed transfer hydrosilylation of alkenes.

No abstract is available for this paper.

• Publication year

  2013

• Venue

  Angewandte Chemie

• Publication date

  2013-11-04

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1002/anie.201305584PMID 24106061
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• B(C6F5)3-Catalyzed Transfer Hydrosilylation of Alkenes

  2014cited by this paper
• Si-H bond activation: bridging Lewis acid catalysis with Brookhart's iridium(III) pincer complex and B(C6F5)3.

  2013cited by this paper
• Si-H-Bindungsaktivierung: Parallelen der Lewis-Säure-Katalyse mit Brookharts Iridium(III)-Pincerkomplex und B(C6F5)3†

  2013cited by this paper
• Catalytic functionalization of methyl group on silicon: iridium-catalyzed C(sp3)-H borylation of methylchlorosilanes.

  2012cited by this paper
• Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view

  2011cited by this paper
• Facile catalytic hydrosilylation of pyridines.

  2011cited by this paper
• Mechanistic aspects of bond activation with perfluoroarylboranes.

  2011cited by this paper
• Schlüssiger Nachweis eines SN2‐Si‐Mechanismus in der B(C6F5)3‐ katalysierten Hydrosilylierung von Carbonylverbindungen: Einsichten in die verwandte Hydrierung

  2008cited by this paper
• Conclusive evidence for an S(N)2-Si mechanism in the B(C6F5)3-catalyzed hydrosilylation of carbonyl compounds: implications for the related hydrogenation.

  2008cited by this paper
• Tris(pentafluorophenyl)borane: a special boron Lewis acid for special reactions.

  2005cited by this paper
• The Chemistry of Perfluoroaryl Boranes

  2005cited by this paper
• The Hydrosilylation Reaction

  2004cited by this paper
• A metal-free catalytic intramolecular hydrosilylation

  2003cited by this paper
• Mechanistic studies on the B(C(6)F(5))(3) catalyzed allylstannation of aromatic aldehydes with ortho donor substituents.

  2002cited by this paper
• Silylated Cyclohexadienes in Radical Chain Hydrosilylations

  2002cited by this paper
• Highly efficient B(C(6)F(5))(3)-catalyzed hydrosilylation of olefins.

  2002cited by this paper
• Radical transfer hydrosilylation/cyclization using silylated cyclohexadienes.

  2001cited by this paper
• B(C6F5)3-catalyzed allylation of secondary benzyl acetates with allylsilanes.

  2001cited by this paper
• Studies on the mechanism of B(C(6)F(5))(3)-catalyzed hydrosilation of carbonyl functions

  2000cited by this paper
• β-Silyl and β-Germyl Carbocations Stable at Room Temperature

  1999cited by this paper
• beta-Silyl and beta-Germyl Carbocations Stable at Room Temperature.

  1999cited by this paper
• Lewis Acid-Catalyzed Regio- and Stereoselective Hydrosilylation of Alkenes with Trialkylsilanes

  1999cited by this paper
• Pentafluorophenylboranes: from obscurity to applications

  1998cited by this paper
• Crystal Structure of a Silyl Cation with No Coordination to Anion and Distant Coordination to Solvent

  1993cited by this paper
• Stereochemistry of Aluminum Chloride Catalyzed Hydrosilylation of Methylcyclohexenes

  1990cited by this paper
• Hydrosilylation of tetrasubstituted olefins

  1986cited by this paper

• Electroreductive Nickel-Catalyzed Intramolecular Hydrosilylation of Alkenes.

  2026cites this paper
• Oxygen, light, and mechanical force mediated radical polymerization toward precision polymer synthesis.

  2025cites this paper
• Base‐Catalyzed Remote Hydrogermylation of Olefins

  2025cites this paper
• Iodine as an efficient initiator for the transfer-hydrogenation from 1,4-cyclohexadiene to aryl-substituted alkenes and the deoxygenation of benzylic alcohols

  2025cites this paper
• B(C6F5)3-Catalyzed (5 + 1)-Annulation of Enynamides with Trihydrosilanes en Route to the Synthesis of 1,4-Azasilines.

  2025cites this paper
• Copper-Catalyzed Transfer Markovnikov Hydrothiolation of Alkenes.

  2025cites this paper
• Kinetic resolution of binols and biphenols via dehydrogenative coupling with hydrosilanes catalyzed by chiral FLPs.

  2025cites this paper
• Methoxide-Enabled Zirconium-Catalyzed Migratory Alkene Hydrosilylation.

  2024cites this paper
• Hydride Shuttle Catalysis: From Conventional to Inverse Mode

  2024cites this paper
• Pd/S cooperativity: from stoichiometric activation of Si−H bonds to catalytic hydrosilylation

  2024cites this paper
• Formoxyboranes as hydroborane surrogates for the catalytic reduction of carbonyls through transfer hydroboration

  2024cites this paper
• Siloxane-containing phosphine (oxide) ligands for enhanced catalytic activity of cobalt complexes for hydrosilylation reactions.

  2024cites this paper
• Borane-Catalyzed Intermolecular Aryl Transfer between Hydrosilanes: Shifting the Equilibrium by Removal of a Gaseous Hydrosilane.

  2024cites this paper
• Cobalt(I)-Catalyzed Transformation of Si–H Bonds: H/D Exchange in Hydrosilanes and Hydrosilylation of Olefins

  2023cites this paper
• Zeolites as equilibrium-shifting agents in shuttle catalysis

  2023cites this paper
• Recent Advances in Ionic Transfer Reactions

  2023cites this paper
• Visible-Light-Driven Silyl or Germyl Radical Generation via Si-C or Ge-C Bond Homolysis.

  2023cites this paper
• Mechanism of Silylation of Vinyl Arenes by Hydrodisiloxanes Driven by Stoichiometric Amounts of Sodium Triethylborohydride—A Combined DFT and Experimental Study

  2023cites this paper
• B(C6F5)3-Catalyzed Silylation of Unsaturated Hydrocarbons

  2023cites this paper
• Controllable Si-C Bond Formation from Trihydrosilanes En Route to Synthesis of 1,4-Azasilinanes with Diverse Silyl Functionalities.

  2023cites this paper
• Ruthenium-Catalyzed Activation of Nonpolar C-C Bonds via π-Coordination-Enabled Aromatization.

  2023cites this paper
• Nickel-Catalyzed Cross-Redistribution between Hydrosilanes and Silacyclobutanes.

  2022cites this paper
• Copper-catalyzed regio- and stereo-selective hydrosilylation of terminal allenes to access (E)-allylsilanes

  2022cites this paper
• Formal Hydrotrimethylsilylation of Styrenes with Anti-Markovnikov Selectivity Using Hexamethyldisilane.

  2022cites this paper
• Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones

  2022cites this paper
• Bicyclo[2.2.0]hexene derivatives as a proaromatic platform for group transfer and chemical sensing

  2021cites this paper
• Silylium Ions: From Elusive Reactive Intermediates to Potent Catalysts.

  2021cites this paper
• Metal-Free Hydrosilylation Polymerization by Merging Photoredox and Hydrogen Atom Transfer Catalysis.

  2021cites this paper
• Borane-catalysed S–H insertion reaction of thiophenols and thiols with α-aryl-α-diazoesters

  2021cites this paper
• 2,5‐Cyclohexadiene‐1‐Carbonitrile, 1‐(1‐Methylethyl)

  2021cites this paper
• Indium Tribromide‐Catalysed Transfer‐Hydrogenation: Expanding the Scope of the Hydrogenation and of the Regiodivergent DH or HD Addition to Alkenes

  2021cites this paper
• B(C6F5)3-Catalyzed cyclization of alkynes: direct synthesis of 3-silyl heterocyclic compounds.

  2020cites this paper
• Versatile Reaction Patterns of Phosphanylhydrosilylalkyne with B(C 6 F 5 ) 3 : A Remarkable Group Substitution Effect

  2020cites this paper
• Facile Synthesis of Sequence-Defined Oligo(Dimethylsiloxane-co-Diphenylsiloxane)s.

  2020cites this paper
• Di-tert-butyl Peroxide (DTBP)-Mediated Oxysilylation of Unsaturated Carboxylic Acids for the Synthesis of Silyl Lactones.

  2020cites this paper
• Regiodivergent DH or HD Addition to Alkenes: Deuterohydrogenation versus Hydrodeuterogenation.

  2020cites this paper
• Dual reactivity of B(C6F5)3 enables the silylative cascade conversion of N-aryl piperidines to sila-N-heterocycles: DFT calculations

  2020cites this paper
• Chemoselective Hydrosilylation of the α,β Site Double Bond in α,β- and α,β,γ,δ-Unsaturated Ketones Catalyzed by Macrosteric Borane Promoted by Hexafluoro-2-propanol.

  2020cites this paper
• Recent Advances in Catalytic Hydrosilylations: Developments beyond Traditional Platinum Catalysts

  2020cites this paper
• Regioselective Hydrosilylation of Olefins Catalyzed by a Molecular Calcium Hydride Cation

  2019cites this paper
• Lewis Acid Catalyzed Transfer Hydromethallylation for the Construction of Quaternary Carbon Centers

  2019cites this paper
• Functionalized polycarbonates via triphenylborane catalyzed polymerization-hydrosilylation

  2019cites this paper
• Lewis Säure‐katalysierte Transferhydromethallylierung für den Aufbau quartärer Kohlenstoffzentren

  2019cites this paper
• Ionic Transfer Reactions with Cyclohexadiene-Based Surrogates

  2019cites this paper
• Si ─ H Bond Activation by Main‐Group L ewis Acids

  2019cites this paper
• Hydrosilylation-Promoted Furan Diels-Alder Cycloadditions with Stereoselectivity Controlled by the Silyl Group.

  2019cites this paper
• Silicon(II) Cation Cp*Si:+ X–: A New Class of Efficient Catalysts in Organosilicon Chemistry

  2019cites this paper
• Regioselektive Hydrosilylierung von Olefinen katalysiert durch ein molekulares Calciumhydrid‐Kation

  2019cites this paper
• Catalytic Isofunctional Reactions-Expanding the Repertoire of Shuttle and Metathesis Reactions.

  2019cites this paper
• Transfer Hydrocyanation of α- and α,β-Substituted Styrenes Catalyzed by Boron Lewis Acids.

  2019cites this paper
• Magnesium hydride alkene insertion and catalytic hydrosilylation

  2019cites this paper
• Thioether-Facilitated Iridium-Catalyzed Hydrosilylation of Steric 1,1-Disubstituted Olefins

  2019cites this paper
• Bor-Lewis-Säure-katalysierte Transferhydrocyanierung α- und α,β-substituierter Styrole

  2019cites this paper
• Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of Ketones

  2019cites this paper
• Katalytische, isofunktionelle Reaktionen – Erweiterung des Repertoires an Shuttle‐ und Metathesereaktionen

  2019cites this paper
• Metal-Free Transfer Hydrobromination of C-C Triple Bonds.

  2019cites this paper
• Contra-thermodynamic Olefin Isomerization by Chain-Walking Hydrofunctionalization and Formal Retro-hydrofunctionalization.

  2019cites this paper
• Hydrosilane synthesis via catalytic hydrogenolysis of halosilanes using a metal-ligand bifunctional iridium catalyst

  2018cites this paper
• B(C6F5)3-catalyzed transfer hydrogenations of imines with Hantzsch esters.

  2018cites this paper
• A Neutral RuII Hydride Complex for the Regio- and Chemoselective Reduction of N-Silylpyridinium Ions.

  2018cites this paper
• Electrophilic Phosphonium Cation-Mediated Phosphane Oxide Reduction Using Oxalyl Chloride and Hydrogen.

  2018cites this paper
• Cooperative Palladium/Lewis Acid-Catalyzed Transfer Hydrocyanation of Alkenes and Alkynes Using 1-Methylcyclohexa-2,5-diene-1-carbonitrile.

  2018cites this paper
• Metal-Free Transfer Hydroiodination of C-C Multiple Bonds.

  2018cites this paper
• Intramolecular Cyclizations of Vinyl-Substituted N,N-Dialkyl Arylamines Enabled by Borane-Assisted Hydride Transfer

  2018cites this paper
• Reduktion von Phosphanoxiden mit Oxalylchlorid und Wasserstoff, vermittelt durch ein elektrophiles Phosphoniumkation

  2018cites this paper
• Custom Hydrosilane Synthesis Based on Monosilane

  2018cites this paper
• Disilanes as oxygen scavengers and surrogates of hydrosilanes suitable for selective reduction of nitroarenes, phosphine oxides and other valuable substrates

  2017cites this paper
• 3-tert-Butyl-Substituted Cyclohexa-1,4-dienes as Isobutane Equivalents in the B(C6 F5 )3 -Catalyzed Transfer Hydro-tert-Butylation of Alkenes.

  2017cites this paper
• Catalytic Formation of Silicon–Heteroatom (N, P, O, S) Bonds

  2017cites this paper
• Hidden Enantioselective Hydrogenation of N-Silyl Enamines and Silyl Enol Ethers in Net C═N and C═O Hydrosilylations Catalyzed by Ru–S Complexes with One Monodentate Chiral Phosphine Ligand

  2017cites this paper
• Utilization of a Trimethylsilyl Group as a Synthetic Equivalent of a Hydroxyl Group via Chemoselective C(sp3)-H Borylation at the Methyl Group on Silicon.

  2017cites this paper
• Sodium Diisopropylamide in Tetrahydrofuran: Selectivities, Rates, and Mechanisms of Alkene Isomerizations and Diene Metalations.

  2017cites this paper
• Access to Fully Alkylated Germanes by B(C6F5)3-Catalyzed Transfer Hydrogermylation of Alkenes.

  2017cites this paper
• Catalytic Reductive Pinacol-Type Rearrangement of Unactivated 1,2-Diols through a Concerted, Stereoinvertive Mechanism.

  2017cites this paper
• Fifty Years of Hydrosilylation in Polymer Science: A Review of Current Trends of Low-Cost Transition-Metal and Metal-Free Catalysts, Non-Thermally Triggered Hydrosilylation Reactions, and Industrial Applications

  2017influential citation
• Cyclohexa-1,4-dienes in transition-metal-free ionic transfer processes

  2017cites this paper
• B(C6 F5 )3 -Catalyzed Cascade Reduction of Pyridines.

  2017cites this paper
• Borane-Catalyzed Selective Hydrosilylation of Internal Ynamides Leading to β-Silyl (Z)-Enamides.

  2017cites this paper
• Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C6F5)3-catalysed transfer processes.

  2017cites this paper
• Accessing Two-Coordinate ZnII Organocations by NHC Coordination: Synthesis, Structure, and Use as π-Lewis Acids in Alkene, Alkyne, and CO2 Hydrosilylation.

  2017cites this paper
• Iron-Catalyzed Silylation of Alcohols by Transfer Hydrosilylation with Silyl Formates

  2017cites this paper
• Hydrosilylation of Carbon–Carbon Multiple Bonds—Application in Synthesis and Materials Science

  2017cites this paper
• Facile and highly selective silylation of vinylpyridines at the β-olefinic carbon by magnesium-promoted reduction

  2016cites this paper
• Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of 1,2-Dicarbonyl Compounds.

  2016cites this paper
• 3-(Dimethylphenylsilyl)-1,4-cyclohexadiene

  2016cites this paper
• 3‐(Trimethylsilyl)‐1,4‐cyclohexadiene

  2016cites this paper
• Merging Platinum-Catalyzed Alkene Hydrosilylation with SiH4 Surrogates: Salt-Free Preparation of Trihydrosilanes

  2016cites this paper
• Hydrosilylation of Olefins Catalyzed by Well-Defined Cationic Aluminum Complexes: Lewis Acid versus Insertion Mechanisms

  2016cites this paper
• Thermal properties of some organosilicon precursors for chemical vapor deposition

  2016cites this paper
• Catalytic Transfer Functionalization through Shuttle Catalysis

  2016cites this paper
• Directed evolution of cytochrome c for carbon–silicon bond formation: Bringing silicon to life

  2016cites this paper
• Borane-Catalyzed Reductive α-Silylation of Conjugated Esters and Amides Leaving Carbonyl Groups Intact.

  2016cites this paper
• Alkoxy Hydrosilanes As Surrogates of Gaseous Silanes for Hydrosilylation of Alkenes.

  2016cites this paper
• Tris(pentafluorophenyl)borane-Catalyzed Acceptorless Dehydrogenation of N-Heterocycles.

  2016cites this paper
• Transfer Hydrosilylation.

  2016cites this paper
• B(C6F5)3-Catalyzed transfer 1,4-hydrostannylation of α,β-unsaturated carbonyls using iPr-tricarbastannatrane.

  2016cites this paper
• Mechanistic insights into hydrogen generation for catalytic hydrolysis and alcoholysis of silanes with high-valent oxorhenium(V) complexes

  2015cites this paper
• B(C6F5)3‐katalysierter Diwasserstofftransfer von einem ungesättigten Kohlenwasserstoff auf einen anderen

  2015cites this paper
• B(C6F5)3 -catalyzed transfer of dihydrogen from one unsaturated hydrocarbon to another.

  2015cites this paper
• Direct and Transfer Hydrosilylation Reactions Catalyzed by Fully or Partially Fluorinated Triarylboranes: A Systematic Study

  2015cites this paper