Transition-metal-free diboration reaction by activation of diboron compounds with simple Lewis bases.

No abstract is available for this paper.

• Publication year

  2011

• Venue

  Angewandte Chemie

• Publication date

  2011-07-25

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1002/anie.201101941PMID 21688368
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Regio- and stereoselective copper-catalyzed β-borylation of allenoates by a preactivated diboron.

  2011cited by this paper
• Nucleophilie des Borzentrums in Base‐stabilisierten Borol‐Anionen

  2010cited by this paper
• Metal-free catalytic boration at the beta-position of alpha,beta-unsaturated compounds: a challenging asymmetric induction.

  2010cited by this paper
• Facile entry to 3d late transition metal boryl complexes.

  2010cited by this paper
• Nucleophilicity of a base-stabilized borole anion at the boron center.

  2010cited by this paper
• Asymmetric 1,4-dihydroxylation of 1,3-dienes by catalytic enantioselective diboration.

  2009cited by this paper
• sp2-sp3 hybridized mixed diboron: synthesis, characterization, and copper-catalyzed beta-boration of alpha,beta-unsaturated conjugated compounds.

  2009cited by this paper
• A facile route to aryl boronates: room-temperature, copper-catalyzed borylation of aryl halides with alkoxy diboron reagents.

  2009cited by this paper
• Boryl ligands and their roles in metal-catalysed borylation reactions.

  2009cited by this paper
• Pt-catalyzed enantioselective diboration of terminal alkenes with B2(pin)2.

  2009cited by this paper
• Efficient C-B bond formation promoted by N-heterocyclic carbenes: synthesis of tertiary and quaternary B-substituted carbons through metal-free catalytic boron conjugate additions to cyclic and acyclic alpha,beta-unsaturated carbonyls.

  2009cited by this paper
• Bifurkationen auf den Potentialenergiehyperflächen organischer Reaktionen

  2008cited by this paper
• Bifurcations on potential energy surfaces of organic reactions.

  2008cited by this paper
• DFT studies on the mechanism of the diboration of aldehydes catalyzed by copper(I) boryl complexes.

  2008cited by this paper
• Lithiumboryl--a synthon for a nucleophilic boryl anion.

  2007cited by this paper
• Lithiumboryl – ein Synthon für das nucleophile Borylanion

  2007cited by this paper
• Catalytic enantioselective diboration, disilation and silaboration: new opportunities for asymmetric synthesis.

  2007cited by this paper
• Boryllithium: Isolation, Characterization, and Reactivity as a Boryl Anion

  2006cited by this paper
• Chemistry. Boron goes on the attack.

  2006cited by this paper
• Boron Goes On the Attack

  2006cited by this paper
• Concatenated catalytic asymmetric allene diboration/allylation/functionalization.

  2005cited by this paper
• Rh-catalyzed enantioselective diboration of simple alkenes: reaction development and substrate scope.

  2005cited by this paper
• Metal promoted asymmetry in the 1,2-diboroethylarene synthesis: diboration versus dihydroboration

  2005cited by this paper
• Boronic acids : preparation and applications in organic synthesis and medicine

  2005cited by this paper
• Palladium-catalyzed enantioselective diboration of prochiral allenes.

  2004cited by this paper
• Metal-catalyzed reactions of diborons for synthesis of organoboron compounds.

  2004cited by this paper
• Recent developments in bisdiborane chemistry: B-C-B, B-C-C-B, B-C=C-B and B-C≡C-B compounds

  2003cited by this paper
• Rhodium-catalyzed enantioselective diboration of simple alkenes.

  2003cited by this paper
• A borylcopper species generated from bis(pinacolato)diboron and its additions to α,β-unsaturated carbonyl compounds and terminal alkynes

  2001cited by this paper
• Unusual diboration of allenes catalyzed by palladium complexes and organic iodides: a new efficient route to biboronic compounds.

  2001cited by this paper
• Highly efficient monophosphine platinum catalysts for alkyne diboration

  2001cited by this paper
• Chemistry with ADF

  2001cited by this paper
• Towards an order-N DFT method

  1998cited by this paper
• Transition metal catalysed diboration

  1998cited by this paper
• Towards an order

  1998cited by this paper
• 2,2′-Bipyridyl and 1,10-phenanthroline adducts of the diborane (4) compound B2 (1,2-S2C6H4)2

  1998cited by this paper
• Efficient olefin diboration by a base-free platinum catalyst

  1997cited by this paper
• Lewis-base adducts of the diborane(4) compounds B2(1,2-E2C6H4)2(E=O or S)

  1997cited by this paper
• Diboration of alkenes with bis(pinacolato)diboron catalysed by a platinum(0) complex

  1997cited by this paper
• Platinum(0)-Catalyzed Diboration of Alkynes with Tetrakis(alkoxo)diborons: An Efficient and Convenient Approach to cis-Bis(boryl)alkenes

  1996cited by this paper
• Transition Metal Catalyzed Diboration of Vinylarenes

  1995cited by this paper
• Lewis base adducts of diboron compounds: molecular structures of [B2(cat)2(4-picoline)] and B2(cat)2(4-picoline)2](cat = 1.2-O2C6H4)

  1995cited by this paper
• Die übergangsmetallkatalysierte Diborierung von Vinylarenen

  1995cited by this paper
• Reactivity of Organoplatinum Complexes with C6H4O2B-BO2C6H4: Syntheses of a Platinum Diboryl Complex with, and without, Metathesis of Boron-Boron and Metal-Carbon Bonds

  1995cited by this paper
• Oxidative addition of B-B bonds by rhodium(I) phosphine complexes: molecular structures of B2cat2 (cat = 1,2-O2C6H4) and its 4-But and 3,5-But2 analogs

  1994cited by this paper
• Platinum(0)-catalyzed diboration of alkynes

  1993cited by this paper

• Synthesis of 1,2-Bis- and 1,1,2-Tris-Borylalkanes under Transition Metal-Free and Solvent-Free Conditions.

  2025cites this paper
• Catalytic efficiency of Cu-MOFs: HKUST-1 and CuBDC for the protodeboronation of aryl boronic acids

  2025cites this paper
• Regioselective C(sp3)–H borylation via a diarylboryl anion surrogate in sp2–sp3 diboranes(5)

  2025cites this paper
• One-Pot Decarbonylative Borylation of Aliphatic Aldehydes.

  2025cites this paper
• Intramolecular Lithiation-Borylation for the Stereoselective Synthesis of Cyclopentyl and Cyclobutyl Bis-Boronic Esters.

  2025cites this paper
• Tetrahydronaphthalenes by Enantioselective Migratory Suzuki–Miyaura Cross-Coupling of meso Bis(Boronic Esters)

  2025cites this paper
• Synthesis and Characterization of Octa(aminophenyl) Silsesquioxane through Amination of Octa(nitrophenyl) Silsesquioxane Using B2(OH)4 at Room Temperature

  2025cites this paper
• Trifluoromethylborylation of Unactivated Alkenes via an Electron Donor-Acceptor (EDA) Complex.

  2025cites this paper
• Computational study on catalyst-free BCl3-promoted chloroboration of carbonyl compounds

  2025cites this paper
• Caylobolide B: Structure Revision, Total Synthesis, Biological Characterization, and Discovery of New Analogues

  2025cites this paper
• Nickel-catalyzed reductive coupling of α-haloboronates to access internal vicinal bis(boronate) esters.

  2025cites this paper
• Defective NiO Nanoparticles Supported on Nb 2 O 5 for Solid‐Catalyzed Markovnikov‐Selective Hydroboration of Styrenes

  2025cites this paper
• Synthesis of symmetrical and unsymmetrical cyclic diborenes via NHC-directed C–H borylation

  2025cites this paper
• Metal-Free Divergent Hydroboration/Multiboration of Terminal Alkynes via Markovnikov Pathway.

  2025cites this paper
• 2,3‐Diboratabutadiene Complexes of Group 4 Metals and their Donor‐Induced Oxidative Cleavage to Methyleneboranes

  2025cites this paper
• Total Synthesis and Structure Determination of Mycapolyol E Using Iterative Homologation of Boronic Esters

  2025cites this paper
• Catalyst-Free Diborylation and Silaboration of Azoarenes: A Simple Photoinduced Approach.

  2024cites this paper
• Photoelectrochemically driven iron-catalysed C(sp3)−H borylation of alkanes

  2024cites this paper
• Recent Advances in Catalytic Asymmetric Synthesis of Chiral 1,2-Bis(boronic) Esters

  2024cites this paper
• Alkoxide-Assisted Stereoselective Functionalization of 1,2-Bis-boronic Esters Under Photoredox Catalysis.

  2024cites this paper
• Coordination-Assisted Ni-Catalyzed Regio- and Enantioselective 1,2-Borylalkylation of Unactivated Alkenes.

  2024cites this paper
• Palladium-Catalyzed Desymmetric Coupling Reaction between Silacyclobutanes and Terminal Alkynes for the Synthesis of Silicon-Stereogenic Allyl Vinylsilanes

  2024cites this paper
• Low-Temperature Borylation of C(sp3)-O Bonds of Alkyl Ethers by Gold-Metal Oxide Cooperative Catalysis.

  2024cites this paper
• Enantioselective Total Synthesis of (-)-Cyathin B2: A Desymmetric Double-Allylboration Approach.

  2024cites this paper
• Uncatalyzed Diboron Activation by a Strained Hydrocarbon: Experimental and Theoretical Study of [1.1.1]Propellane Diborylation.

  2024cites this paper
• Regioselective Alkynylation and Alkenylation at the More Hindered C-B Bond of 1,2-Bis(Boronic) Esters.

  2024cites this paper
• Titanium-Catalyzed Synthesis of 1,1-Diborylalkanes from Aryl Alkenes

  2024cites this paper
• Optimization of Metal-Support Cooperation for Boosting the Performance of Supported Gold Catalysts for the Borylation of C-O and C-N Bonds.

  2024cites this paper
• Synthesis of Boronic Esters from Organometallic Reagents and Bis(pinacolato)diboron.

  2023cites this paper
• Ni-Catalyzed 1,2-Alkyl Borylation and Silylation of Allenes En Route to [1,3]-Bis-Organometallic Reagents.

  2023cites this paper
• Triboranate Derivatives of Calcium and Strontium

  2023cites this paper
• Defluorinative Alkylboration of Alkenes Enabled by Dual Photoredox and Copper Catalysis.

  2023cites this paper
• Base-mediated C–B bond activation of benzylic boronate for the rapid construction of β-silyl/boryl functionalized 1,1-diarylalkanes from aromatic alkenes

  2023cites this paper
• Cationic Symmetrically and Unsymmetrically Substituted Diboranes and Bis(diboranes) with Direct Boron‐Boron Bond: Synthesis by Substitution, Stability and Properties

  2023cites this paper
• Synthetic Element Chemistry based on Precise Designs of Reagents and Transition States

  2023cites this paper
• Catalyst-free diboration and silaboration of alkenes and alkynes using bis(9-heterofluorenyl)s

  2023cites this paper
• Enantioselective Suzuki cross-coupling of 1,2-diboryl cyclopropanes

  2023cites this paper
• Transition metal- and solvent-free anti-Markovnikov selective protoboration of alkenes with bis(pinacolato)diboron.

  2023cites this paper
• Metal-Free One-Pot Multi-Functionalization of Unsaturated Compounds with Interelement Compounds by Radical Process

  2023cites this paper
• Nickel(II)-catalyzed highly selective 1,2-diborylation of non-activated monosubstituted alkenes.

  2022cites this paper
• Bis(catecholatodiboron)

  2022cites this paper
• Enantioselective Copper-Catalyzed sp2/sp3 Diborylation of 1-Chloro-1-Trifluoromethylalkenes

  2022cites this paper
• Mechanistic Insights into the Metal-Free Deoxygenative Borylation of Ketones and Aldehydes with Bis(Catecholato)Diborane.

  2022cites this paper
• Dual Nickel/Photoredox‐Catalyzed Site‐Selective Cross‐Coupling of 1,2‐Bis‐Boronic Esters Enabled by 1,2‐Boron Shifts

  2022cites this paper
• Selective Coupling of 1,2‐Bis‐Boronic Esters at the more Substituted Site through Visible‐Light Activation of Electron Donor–Acceptor Complexes

  2022cites this paper
• A (μ-hydrido)diborane(4) anion and its coordination chemistry with coinage metals

  2022cites this paper
• Selective, Transition Metal‐free 1,2‐Diboration of Alkyl Halides, Tosylates, and Alcohols

  2022cites this paper
• Copper catalysed protoboration of allenyl-Bdans: efficient synthesis of β-boryl allyl-Bdans.

  2022cites this paper
• Synthesis, equilibrium, and biological study of a C-7 glucose boronic acid derivative as a potential candidate for boron neutron capture therapy.

  2022cites this paper
• Diastereoselective Diboration of Cyclic Alkenes: Application to the Synthesis of Aristeromycin.

  2021cites this paper
• B–B vs. B–H Bond Activation in a (μ‐Hydrido)diborane(4) Anion upon Cycloaddition with CO2, Isocyanates, or Carbodiimides

  2021cites this paper
• Iron-Catalyzed Diborylation of Unactivated Aliphatic gem-Dihalogenoalkenes: Synthesis of 1,2-Bis(boryl)alkanes.

  2021cites this paper
• Diphosphinoboranes as Intramolecular Frustrated Lewis Pairs: P–B–P Bond Systems for the Activation of Dihydrogen, Carbon Dioxide, and Phenyl Isocyanate

  2021cites this paper
• Stereoselective diboration of spirocyclobutenes: a platform for the synthesis of spirocycles with orthogonal exit vectors.

  2021cites this paper
• Nickel-Catalyzed Enantioselective Hydroboration of Vinylarenes.

  2021cites this paper
• Site-Fixed Hydroboration of Alkenes under Metal-Free Conditions: Scope and Mechanistic Studies

  2021cites this paper
• Three-component reaction of gem-difluorinated cyclopropanes with alkenes and B2pin2 for the synthesis of monofluoroalkenes.

  2021cites this paper
• Alkoxide activation of tetra-alkoxy diboron reagents in C-B bond formation: a decade of unpredictable reactivity.

  2021cites this paper
• sp3 Bis-Organometallic Reagents via Catalytic 1,1-Difunctionalization of Unactivated Olefins.

  2021cites this paper
• Transborylation of alkenylboranes with diboranes.

  2021cites this paper
• Construction of Azacycles by Intramolecular Amination of Organoboronates and Organobis(boronates).

  2021cites this paper
• Scalable Synthesis of β-Lactamase Inhibitor QPX7728 by Sequential Nickel-Catalyzed Boron Insertion into a Benzofuran Substrate and Enantioselective Cyclopropanation of the Resulting Vinylboronate

  2021cites this paper
• Homolytic cleavage of diboron(4) compounds using diazabutadiene derivatives.

  2021cites this paper
• Mechanistic study on the reaction of pinB-BMes2 with alkynes based on experimental investigation and DFT calculations: gradual change of mechanism depending on the substituent†

  2021cites this paper
• Synthesis of Multi-Substituted Bicycloalkyl Boronates: An Intramolecular Coupling Approach to Alkyl Bioisosteres

  2021cites this paper
• An intramolecular coupling approach to alkyl bioisosteres for the synthesis of multisubstituted bicycloalkyl boronates

  2021cites this paper
• Electrochemical Hydroboration of Alkynes

  2021cites this paper
• Inter‐Element Boration Reactions of Carbon‐Carbon Multiple Bonds via Lewis‐Basic Activation of Boron Reagents

  2021cites this paper
• A site-selective and stereospecific cascade Suzuki-Miyaura annulation of alkyl 1,2-bisboronic esters and 2,2'-dihalo 1,1'-biaryls.

  2021cites this paper
• 1,2-Arylboration of aliphatic alkenes by cooperative palladium/copper catalysis

  2021cites this paper
• Dendrimeric and Corresponding Monometallic Iridium(III) Catalysts Bound to Carbon Nanotubes Used in Hydroamination Transformations

  2021cites this paper
• Reactions of Diboron Reagents with Unsaturated Compounds

  2021cites this paper
• Tetracoordinate Boron Intermediates Enable Unconventional Transformations.

  2021cites this paper
• Diboration of alkenes and alkynes with a carborane-fused four-membered boracycle bearing an electron-precise B-B bond.

  2021cites this paper
• Site-Fixed Hydroboration of Terminal and Internal Alkenes using BX3/iPr2NEt.

  2021cites this paper
• Reactivity of a magnesium diboranate with organic nitriles.

  2020cites this paper
• Direct Synthesis of Multi(boronate) Esters from Alkenes and Alkynes via Hydroboration and Boration Reactions

  2020cites this paper
• DFT Study on the Mechanism of 4,4'-Bipyridine-Catalyzed Nitrobenzene Reduction by Diboron(4) Compounds.

  2020cites this paper
• Ligand-Free Iron-Catalyzed Regioselectivity-Controlled Hydroboration of Aliphatic Terminal Alkenes

  2020cites this paper
• Diboration of 3-substituted propargylic alcohols using a bimetallic catalyst system: access to (Z)-allyl, vinyldiboronates.

  2020cites this paper
• Stereospecific Access to Allylboronic Esters Within Acyclic Systems Bearing Distant Tetrasubstituted Stereocenters.

  2020cites this paper
• Bottleable NiCl2(dppe) as a catalyst for the Markovnikov-selective hydroboration of styrenes with bis(pinacolato)diboron.

  2020cites this paper
• Transition metal-free synthesis of alkyl pinacol boronates.

  2020cites this paper
• Base-promoted domino-borylation-protodeboronation strategy.

  2020cites this paper
• Selective Synthesis of Secondary Alkylboronates: Markovnikov-Selective Hydroboration of Vinylarenes with Bis(pinacolato)diboron Catalyzed by a Nickel Pincer Complex.

  2020cites this paper
• Tri(boryl)alkanes and Tri(boryl)alkenes: The Versatile Reagents

  2020cites this paper
• Neutral cyclic sp2-sp3 and sp3-sp3 diboranes from N,N'-dicyclohexylcarbodiimide insertion into 1,2-dichlorodiboranes(4).

  2020cites this paper
• Methodologies and Strategies for Selective Borylation of C-Het and C-C Bonds.

  2020cites this paper
• B−B Bond Nucleophilicity in a Tetraaryl μ‐Hydridodiborane(4) Anion

  2020cites this paper
• Construction of Silicon-Containing Seven-Membered Rings by Catalytic [4 + 2 + 1] Cycloaddition through Rhodium Silylenoid.

  2020cites this paper
• Stereospecific Reactions Leading to Allylboronic Esters Within Acyclic Systems Bearing Distant Stereocenters

  2020cites this paper
• Hexahalodiborate Dianions: A New Family of Binary Boron Halides

  2019cites this paper
• 1,2-Boron Shifts of β-Boryl Radicals Generated from Bis-Boronic Esters using Photoredox Catalysis.

  2019cites this paper
• Iron-catalyzed boration of cinnamyl carbonates: a highly stereoselective approach to cyclopropylboronates

  2019cites this paper
• Palladium-Catalyzed Amide-Directed Enantioselective Carboboration of Unactivated Alkenes Using a Chiral Monodentate Oxazoline Ligand

  2019cites this paper
• Pyridine‐Based Organocatalysts for Regioselective syn ‐1,2‐Silaboration of Terminal Alkynes and Allenes

  2019cites this paper
• Hexahalogendiborat‐Dianionen: Eine neue Klasse binärer Borhalogenide

  2019cites this paper
• Vicinal Diboration of Alkyl Bromides via Tandem Catalysis.

  2019cites this paper
• Transition-Metal-Free Allylic Borylation of 1,3-Dienes.

  2019cites this paper
• Direct Synthesis of Free α-Amino Acids by Telescoping Three-Step Process from 1,2-Diols.

  2019cites this paper