Porphyrinoids as a platform of stable radicals

This review surveys four types of stable porphyrinoid radical and covers their synthetic methods and properties. The remarkable radical-stabilizing abilities of porphyrinoid stem from their unique macrocyclic conjugated systems with high electronic and structural flexibilities.

• Publication year

  2018

• Venue

  Chemical Science

• Publication date

  2018-01-08

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1039/c7sc05210cPMID 29675188PMCID 5892410
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Porphyrin-Based Air-Stable Helical Radicals.

  2018cited by this paper
• Metalation Control of Open-Shell Character in meso-meso Linked Porphyrin meso-Oxy Radical Dimers.

  2018cited by this paper
• Bicyclic Baird-type aromaticity.

  2017cited by this paper
• Flexible Porphyrinoids.

  2017cited by this paper
• The Planar Cyclooctatetraene Bridge in Bis-Metallic Macrocycles: Isolating or Conjugating?

  2017cited by this paper
• Stable NiII Porphyrin meso-Oxy Radical with a Quartet Ground State.

  2017cited by this paper
• Electronic Delocalization in the Radical Cations of Porphyrin Oligomer Molecular Wires

  2017cited by this paper
• Conformationally Flexible Bis(9-fluorenylidene)porphyrin Diradicaloids.

  2017cited by this paper
• Hetero Cu(III)-Pd(II) Complex of a Dibenzo[g,p]chrysene-Fused Bis-dicarbacorrole with Stable Organic Radical Character.

  2017cited by this paper
• Stable Subporphyrin meso-Aminyl Radicals without Resonance Stabilization by a Neighboring Heteroatom.

  2017cited by this paper
• Chemistry of meso-Aryl-Substituted Expanded Porphyrins: Aromaticity and Molecular Twist.

  2017cited by this paper
• Syntheses, Properties, and Catalytic Activities of Metal(II) Complexes and Free Bases of Redox-Switchable 20π, 19π, and 18π 5,10,15,20-Tetraaryl-5,15-diazaporphyrinoids.

  2017cited by this paper
• Recent Advances in Subporphyrins and Triphyrin Analogues: Contracted Porphyrins Comprising Three Pyrrole Rings.

  2017cited by this paper
• Thienylquinonoidal Porphyrins and Hexaphyrins with Singlet Diradical Ground States.

  2017cited by this paper
• Reversible Carbon-Carbon Bond Breaking and Spin Equilibria in Bis(pyrimidinenorcorrole).

  2016cited by this paper
• Electronic Structure of Copper Corroles.

  2016cited by this paper
• Redox-Switchable 20π-, 19π-, and 18π-Electron 5,10,15,20-Tetraaryl-5,15-diazaporphyrinoid Nickel(II) Complexes.

  2016cited by this paper
• Magnetic Bistability in a Discrete Organic Radical.

  2016cited by this paper
• Synthesis of Di-peri-dinaphthoporphyrins by PtCl2 -Mediated Cyclization of Quinodimethane-type Porphyrins.

  2016cited by this paper
• Triply Linked Corrole Dimers.

  2016cited by this paper
• Chemo- and Regioselective Reduction of 5,15-Diazaporphyrins Providing Antiaromatic Azaporphyrinoids.

  2016cited by this paper
• Thermally controlling the singlet–triplet energy gap of a diradical in the solid state

  2016cited by this paper
• Electrochemical Behavior of meso-Substituted Porphyrins: The Role of Cation Radicals to the Half-Wave Oxidation Potential Splitting.

  2016cited by this paper
• A quinoidal bis-phenalenyl-fused porphyrin with supramolecular organization and broad near-infrared absorption.

  2016cited by this paper
• meso-meso-Linked Diarylamine-Fused Porphyrin Dimers.

  2016cited by this paper
• Directly Diphenylborane-Fused Porphyrins.

  2016cited by this paper
• meso-Nitro- and meso-Aminosubporphyrinatoboron(III)s and meso-to-meso Azosubporphyrinatoboron(III)s.

  2016cited by this paper
• Corrigendum: Nickel(II) meso-Hydroxyporphyrin Complexes Revisited: Palladium-Catalysed Synthesis, Electronic Structures of Derived Oxy Radicals, and Oxidative Coupling to a Dioxoporphodimethene Dyad.

  2016cited by this paper
• The influence of protonation on the structure and spectral properties of porphine: UV-vis, 1H NMR and ab initio studies

  2016cited by this paper
• Spontaneous Formation of an Air-Stable Radical upon the Direct Fusion of Diphenylmethane to a Triarylporphyrin.

  2016cited by this paper
• Stable π Radical from a Contracted Doubly N-Confused Hexaphyrin by Double Palladium Metalation.

  2015cited by this paper
• A Stable Organic π-Radical of a Zinc(II)-Copper(I)-Zinc(II) Complex of Decaphyrin.

  2015cited by this paper
• Pro-aromatic and anti-aromatic π-conjugated molecules: an irresistible wish to be diradicals.

  2015cited by this paper
• Formation of Ground State Triplet Diradicals from Annulated Rosarin Derivatives by Triprotonation.

  2015cited by this paper
• Triarylporphyrin meso-Oxy Radicals: Remarkable Chemical Stabilities and Oxidation to Oxophlorin π-Cations.

  2015cited by this paper
• Designs of Functional π-Electron Materials Based on the Characteristic Features of Boron

  2015cited by this paper
• Experimental and Theoretical Investigations of the Existence of Cu(II), Cu(III), and Cu(IV) in Copper Corrolato Complexes.

  2015cited by this paper
• Phenalenyl-fused porphyrins with different ground states

  2015cited by this paper
• The Corrole Radical.

  2015cited by this paper
• meso-Hydroxysubporphyrins: A Cyclic Trimeric Assembly and a Stable meso-Oxy Radical.

  2015cited by this paper
• Extreme electron polaron spatial delocalization in π-conjugated materials

  2015cited by this paper
• An Extremely Air-Stable 19π Porphyrinoid.

  2015cited by this paper
• Phenalenyl-based open-shell polycyclic aromatic hydrocarbons.

  2015cited by this paper
• Ligand Noninnocence in Coinage Metal Corroles: A Silver Knife-Edge.

  2015cited by this paper
• An amphoteric switch to aromatic and antiaromatic states of a neutral air-stable 25π radical.

  2014cited by this paper
• Subphthalocyanines, subporphyrazines, and subporphyrins: singular nonplanar aromatic systems.

  2014cited by this paper
• Diradicals.

  2013cited by this paper
• Protonation-coupled redox reactions in planar antiaromatic meso-pentafluorophenyl-substituted o-phenylene-bridged annulated rosarins.

  2013cited by this paper
• Description of aromaticity in porphyrinoids.

  2013cited by this paper
• Hidden non-innocence in an expanded porphyrin: electronic structure of the Siamese-twin porphyrin's dicopper complex in different oxidation states.

  2013cited by this paper
• Oxidative fusion reactions of meso-(diarylamino)porphyrins.

  2013cited by this paper
• Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

  2012cited by this paper
• The structural chemistry of metallocorroles: combined X-ray crystallography and quantum chemistry studies afford unique insights.

  2012cited by this paper
• Light-driven coordination-induced spin-state switching: rational design of photodissociable ligands.

  2012cited by this paper
• A Crystalline Singlet Phosphinonitrene: A Nitrogen Atom–Transfer Agent

  2012cited by this paper
• Macrocyclic aromaticity of porphyrin units in fully conjugated oligoporphyrins.

  2012cited by this paper
• Synthesis, characterization, and spectroscopic analysis of antiaromatic benzofused metalloporphyrins.

  2012cited by this paper
• Siamese-twin porphyrin: a pyrazole-based expanded porphyrin providing a bimetallic cavity.

  2011cited by this paper
• Expanded porphyrins: intriguing structures, electronic properties, and reactivities.

  2011cited by this paper
• Neutral radical and singlet biradical forms of meso-free, -keto, and -diketo hexaphyrins(1.1.1.1.1.1): effects on aromaticity and photophysical properties.

  2011cited by this paper
• Expanded porphyrins and aromaticity.

  2011cited by this paper
• Preface: Forum on redox-active ligands.

  2011cited by this paper
• Subporphyrins: A Legitimate Ring-Contracted Porphyrin with Versatile Electronic and Optical Properties

  2011cited by this paper
• Protonation-induced formation of a stable singlet biradicaloid derived from a modified sapphyrin analogue.

  2010cited by this paper
• A porphyrin-related macrocycle with an embedded 1,10-phenanthroline moiety: fluorescent magnesium(II) ion sensor.

  2010cited by this paper
• Copper corroles: the question of noninnocence.

  2010cited by this paper
• Synthesis, reactions, and electronic properties of 16 pi-electron octaisobutyltetraphenylporphyrin.

  2010cited by this paper
• A stable organic radical delocalized on a highly twisted pi system formed upon palladium metalation of a Möbius aromatic hexaphyrin.

  2010cited by this paper
• Cytochrome P450 Compound I: Capture, Characterization, and C-H Bond Activation Kinetics

  2010cited by this paper
• P450 enzymes: their structure, reactivity, and selectivity-modeled by QM/MM calculations.

  2010cited by this paper
• A stable non-Kekulé singlet biradicaloid from meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1).

  2010cited by this paper
• Macrocyclic aromaticity in Hückel and Möbius conformers of porphyrinoids.

  2009cited by this paper
• A stable radical species from facile oxygenation of meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1).

  2008cited by this paper
• Macrocyclic conjugation pathways in porphyrins.

  2008cited by this paper
• Revisiting the electronic ground state of copper corroles.

  2007cited by this paper
• Synthesis and Reactions of 20 π-Electron β-Tetrakis(trifluoromethyl)-meso-tetraphenylporphyrins

  2007cited by this paper
• What's new in stable radical chemistry?

  2007cited by this paper
• Synthesis and reactions of 20 pi-electron beta-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrins.

  2007cited by this paper
• Synthesis and biradicaloid character of doubly linked corrole dimers.

  2006cited by this paper
• Water-splitting chemistry of photosystem II.

  2006cited by this paper
• New palladium catalysed reactions of bromoporphyrins: synthesis and crystal structures of nickel(ii) complexes of primary 5-aminoporphyrin, 5,5'-bis(porphyrinyl) secondary amine, and 5-hydroxyporphyrin.

  2006cited by this paper
• Highly nonplanar, electron deficient, N-substituted tetra-oxocyclohexadienylidene porphyrinogens: structural, computational, and electrochemical investigations.

  2004cited by this paper
• Models and mechanisms of O-O bond activation by cytochrome P450. A critical assessment of the potential role of multiple active intermediates in oxidative catalysis.

  2004cited by this paper
• A triplet carbene surviving a week in solution at room temperature.

  2003cited by this paper
• Fusion and planarization of a quinoidal porphyrin dimer.

  2002cited by this paper
• Assignment of the optical spectrum of metal porphyrin and phthalocyanine radical anions

  2001cited by this paper
• Fully Conjugated Porphyrin Tapes with Electronic Absorption Bands That Reach into Infrared

  2001cited by this paper
• Coordination chemistry with meso-hydroxylated porphyrins (oxophlorins), intermediates in heme degradation

  2000cited by this paper
• meso-Aryl smaragdyrins: novel anion and metal receptors.

  2000cited by this paper
• New chemistry of oxophlorins (oxyporphyrins) and their π-radicals

  1999cited by this paper
• Stabilization of neutral oxophlorin π-radicals by bulkymeso-alkyl groups

  1997cited by this paper
• Configurational Multiplicity of Porphyrin π Cation Radicals: Nickel π−π Dimers

  1997cited by this paper
• NICKEL AND COPPER CORROLES : WELL-KNOWN COMPLEXES IN A NEW LIGHT

  1997cited by this paper
• Oxygen and One Reducing Equivalent Are Both Required for the Conversion of -Hydroxyhemin to Verdoheme in Heme Oxygenase

  1996cited by this paper
• Metalloporphyrin Mixed-Valence π-Cation Radicals: Solid-State Structures

  1996cited by this paper
• Catabolism of Tetrapyrroles

  1995cited by this paper
• Time-Domain Electron Paramagnetic Resonance as a Probe of Electron-Electron Spin-Spin Interaction in Spin-Labeled Low-Spin Iron Porphyrins

  1995cited by this paper
• Metallocorroles with Formally Tetravalent Iron

  1994cited by this paper
• Nickel(II) complexes of the octaethyloxophlorin dianion and octaethyloxophlorin radical dianion

  1993cited by this paper
• Rat liver heme oxygenase. High level expression of a truncated soluble form and nature of the meso-hydroxylating species.

  1993cited by this paper

• Insight into catalytic performance of chlorobenzene over phosphate-modified MnCeOx catalysts and suppression mechanism of polychlorinated byproducts

  2026cites this paper
• 5-Aminolevulinic Acid-Based Radiodynamic Therapy for Malignant Gliomas: A Conceptual Framework for Mitochondria-Centered Mechanisms, Target Cell States and Translational Perspectives.

  2026cites this paper
• Reversible Ring Oxidation of 48π Planar Nonaphyrins to Open Shell 46π dications.

  2025cites this paper
• The physicochemical and biochemical mechanisms of porphyrinoid-mediated radiodynamic therapy.

  2025cites this paper
• Cationic Magnetically Active Nitrogen-Doped Polycyclic Aromatic Hydrocarbon with Record Low Band Gap.

  2025cites this paper
• Electrochemical Reduction of CO2 to CH3OH Catalyzed by an Iron Porphyrinoid.

  2025cites this paper
• Synthesis, Photophysical and Redox Properties of Highly Stable Radicals of Nickel(II) Bis(2-aminophenyl)-azadipyrromethene.

  2025cites this paper
• Switchable Closed-Shell and Open-Shell Biradical States in Bis-Palladium Complexes of Tetrathiadodecaphyrin via Coordination Rearrangement.

  2025cites this paper
• NHC‐Terphenyl Radicals and Anions: Tuning Stability and Redox Properties via Substituent Patterning

  2025cites this paper
• Synthesis of nickel(II)-containing meso-edited phthalocyanine derivatives

  2025cites this paper
• Features of 1H NMR spectra of structurally related open-chain oligopyrroles and their coordination compounds

  2025cites this paper
• Redox Active Ligands for Catalyzing the Hydrogen Evolution Reaction.

  2024cites this paper
• Stabilizing Diketopyrrolopyrrole Radical Cations Through Carbazoles: Substitution Pattern vs Spin Delocalization.

  2024cites this paper
• Trends in Methanol-Solvated Actinide Ions and Actinide Expanded Porphyrin Complexes.

  2024cites this paper
• Rapidly Generated, Ultra-Stable, and Switchable Photoinduced Radicals: A Solid-State Photochromic Paradigm for Reusable Paper Light-Writing.

  2024cites this paper
• Combining two relatively weak bases (Zn(TMP)2 and KOtBu) for the regioselective metalation of non-activated arenes and heteroarenes

  2024cites this paper
• Assembling Fe4 single-molecule magnets on a TiO2 monolayer.

  2024cites this paper
• Insight into Stable, Concentrated Radicals from Sulfur-functionalized Alkyne-rich Crystalline Frameworks and Application in Solar-to-vapor Conversion

  2024cites this paper
• Unusual S = 1 Four-Coordinate Fe(IV) Complexes Supported by Bisamide Ligands: Syntheses, Characterization, and Electronic Structures.

  2024cites this paper
• Synthesis of NiII porphyrin—NiII 5,15-diazaporphyrin hybrid tapes

  2024cites this paper
• On-Surface Synthesis of Polyene-Linked Porphyrin Cooligomer.

  2024cites this paper
• [22]Pentaphyrins(2.0.1.1.0) Displaying N-Fusion, Pyrrole-Rearrangement, and Dimerization Reactions Upon Oxidation and Metalation.

  2024cites this paper
• Stabilization of the Neutral [25]Hexaphyrin(1.0.1.0.1.0) Radical by Hetero-Bimetal-Coordination.

  2024cites this paper
• N-Heterocyclic Carbene Analogues of Wittig Hydrocarbon.

  2024cites this paper
• A Nanographene‐Porphyrin Hybrid for Near‐Infrared‐Ii Phototheranostics

  2024cites this paper
• Breaking Global Diatropic Current to Tame Diradicaloid Character: Thiele's Hydrocarbon Under Macrocyclic Constraints.

  2024cites this paper
• Organic radicals in single-molecule junctions

  2024cites this paper
• Multicenter interactions and ligand field effects in platinum(II) tripyrrindione radicals.

  2023cites this paper
• Altering the Site of Electron Abstraction in Cobalt Corroles via meso-Trifluoromethyl Substituents.

  2023cites this paper
• Theoretical Study of Hydroxylation of α- and β-Pinene by a Cytochrome P450 Monooxygenase Model

  2023cites this paper
• Cyclic iron tetra N-heterocyclic carbenes: synthesis, properties, reactivity, and catalysis.

  2023cites this paper
• Di(p-dibenzi)[40]decaphyrin(1.0.0.0.0.1.0.0.0.0) PdII Complex: A Weakly Hückel 38π-Aromatic Macrocycle.

  2023cites this paper
• Irradiation of ZnPPIX Complexed with Bovine β-Lactoglobulin Causes Chemical Modifications and Conformational Changes of the Protein

  2023cites this paper
• Molecular Engineering of Corrole Radicals by Polycyclic Aromatic Fusion: Towards Open-Shell Near-Infrared Materials for Efficient Photothermal Therapy.

  2023cites this paper
• Oxa-TriQuinoline: A New Entry to Aza-Oxa-Crown Architectures.

  2023cites this paper
• Synthesis and Studies of Di(p-Benzi)Decaphyrin and Di(9,10-Anthracenyl)Decaphyrin.

  2022cites this paper
• Quantum nanomagnets in on-surface metal-free porphyrin chains

  2022cites this paper
• High-Spin S = 3/2 Ground-State Aminyl Triradicals: Toward High-Spin Oligo-Aza Nanographenes.

  2022cites this paper
• Interplay between π-Conjugation and Exchange Magnetism in One-Dimensional Porphyrinoid Polymers

  2022cites this paper
• Magnetic Interplay between π‐Electrons of Open‐Shell Porphyrins and d‐Electrons of Their Central Transition Metal Ions

  2022cites this paper
• Organic radicals stabilization above 300 °C in Eu-based coordination polymers for solar steam generation

  2022cites this paper
• An Alternative Proposal for the Reaction Mechanism of Light-Dependent Protochlorophyllide Oxidoreductase

  2022cites this paper
• Highly Stable Neutral Corrole Radical: Amphoteric Aromatic-Antiaromatic Switching and Efficient Photothermal Conversion.

  2022cites this paper
• In pursuit of novel pyriporphyrin—a porphyrin ring expansion congener containing a built-in pyridine moiety by CH radical: a DFT investigation

  2022cites this paper
• Stable Organic Radicals Participation in Charge Transfer: A New Strategy toward Molecular Functional Materials.

  2022cites this paper
• Electronic Coupling and Electrocatalysis in Redox Active Fused Iron Corroles

  2022cites this paper
• Tailoring diradicaloid properties of expanded isophlorinoids with systematic core-modification.

  2022cites this paper
• One Carbon Ring Expansion of Bipyrrole to Bipyridine Enables Access to a π-Extended, Non-innocent, Corrole-like Ligand.

  2022cites this paper
• Facile Formation of Stable Neutral Radicals and Cations from [22]Smaragdyrin BF2 Complexes.

  2022cites this paper
• Novel Lanthanide(III) Porphyrin-Based Metal–Organic Frameworks: Structure, Gas Adsorption, and Magnetic Properties

  2021cites this paper
• A Robust Triplet Porphyrin-Stabilized Carbon Diradical.

  2021cites this paper
• Doubly Strapped Redox-Switchable 5,10,15,20-Tetraaryl-5,15-diazaporphyrinoids: Promising Platforms for the Evaluation of Paratropic and Diatropic Ring-Current Effects.

  2021cites this paper
• Metalloradical Cations and Dications Based on Divinyldiphosphene and Divinyldiarsene Ligands

  2021cites this paper
• Metallocorrole-based porous organic polymers as a heterogeneous catalytic nanoplatform for efficient carbon dioxide conversion

  2021cites this paper
• Stabilization of a Triplet Diradical on a Binuclear palladium(II) Dipyrrindione

  2021cites this paper
• Realization of quantum nanomagnets in metal-free porphyrins

  2021cites this paper
• Ligand-Centered Triplet Diradical Supported by a Binuclear Palladium(II) Dipyrrindione

  2021cites this paper
• Development of Peripheral Functionalization Chemistry of meso-Free Corroles.

  2021cites this paper
• Air-/Heat-Stable Crystalline Carbon-Centered Radicals Derived from an Annelated N-Heterocyclic Carbene.

  2021cites this paper
• Here’s looking at the reduction of noninnocent copper corroles via anion induced electron transfer

  2021cites this paper
• Functional nitrogen science based on plasma processing: quantum devices, photocatalysts and activation of plant defense and immune systems

  2021cites this paper
• Variational Energy Decomposition Analysis of Charge-Transfer Interactions between Metals and Ligands in Carbonyl Complexes.

  2021cites this paper
• Benzo[1,2‐c;4,5‐cʹ]bis[1,2,5]thiadiazole‐porphyrin‐based near‐infrared dyes

  2021cites this paper
• Biopyrrin Pigments: From Heme Metabolites to Redox-Active Ligands and Luminescent Radicals.

  2021cites this paper
• Redox of Dual-Radical Intermediates in a Methylene-Linked Covalent Triazine Framework for High-Performance Lithium-Ion Batteries.

  2020cites this paper
• Solvent and Anion Effects on the Electrochemistry of Manganese Dipyrrin-Bisphenols.

  2020cites this paper
• 2,6-/1,5-Naphthoquinodimethane bridged porphyrin dimer diradicaloids

  2020cites this paper
• Inducing Open-shell Character in Porphyrins through Surface-assisted Phenalenyl π-Extension.

  2020cites this paper
• PtCl2 mediated peripheral transformation of carbatriphyrin(3.1.1) into a meso-fused β-β' dimer and its monomer analogue.

  2020cites this paper
• Precise Control of Pi-electron Magnetism in Metal-free Porphyrins.

  2020cites this paper
• Helicene Radicals: Molecules Bearing a Combination of Helical Chirality and Unpaired Electron Spin.

  2020cites this paper
• Metallated Porphyrin Stable Free Radicals: Exploration of Electron-Spin Communication and Dynamics.

  2020cites this paper
• Near-Infrared (>1000 nm) Light-Harvesters: Design, Synthesis and Applications.

  2020cites this paper
• Molecular design of ambipolar redox-active open-shell molecules: Principles and implementations

  2020cites this paper
• Near-Infrared-III Absorbing and Emitting Dyes: Energy Gap Engineering of Expanded Porphyrinoids via Metallation.

  2020cites this paper
• Propeller-shaped Semi-fused Porphyrin Trimers: Molecular-symmetry-dependent Chiroptical Response.

  2020cites this paper
• π-Extended chalcogenoviologens with stable radical state enable enhanced visible-light-driven hydrogen evolution and static/dynamic electrochromic displays

  2020cites this paper
• Highly Stable Radical Cations of N,N'-Diarylated Tetrabenzotetraaza[8]circulene.

  2020cites this paper
• Tuning the stability of organic radicals: from covalent approaches to non-covalent approaches

  2020cites this paper
• Hidden ligand noninnocence: A combined spectroscopic and computational perspective

  2020cites this paper
• Stable meso-meso Linked 2NH-Corrole Radical Dimers as a Key Intermediate to Corrole Tape.

  2020cites this paper
• Synthesis and Aromaticity of Benzene-Fused Doubly N-Confused Porphyrins.

  2020cites this paper
• Isolation of singlet carbene derived 2-arsa-1,3-butadiene radical cations and dications.

  2020cites this paper
• A Stable All-thiophene-based Core-modified [38]Octaphyrin Diradicaloid: Conformation and Aromaticity Switch at Different Oxidation States.

  2020cites this paper
• Stable radical versus reversible σ-bond formation of (porphyrinyl)dicyanomethyl radicals

  2019cites this paper
• 2,3-Dicyano-5,6-dichlorobenzoquinone-Mediated and Selective C-O and C-C Cross-Couplings of Phenols and Porphyrins.

  2019cites this paper
• Propentdyopents: Brief history of a family of dipyrrolic pigments

  2019cites this paper
• Trendbericht Organische Chemie

  2019cites this paper
• Phenylene-bridged Porphyrin meso-Oxy Radical Dimers.

  2019cites this paper
• π-Radical Formation by Pyrrolic H Abstraction of Phthalocyanine Molecules on Molybdenum Disulfide.

  2019cites this paper
• Synthesis of Hydroxyisooxophlorins by Oxidative Degradation of meso-Hydroxyporphyrins.

  2019cites this paper
• meta- and para-Phenylenediamine-Fused Porphyrin Dimers: Synthesis and Magnetic Interactions of Their Dication Diradicals.

  2019cites this paper
• Synthesis of Redox-switchable 5,15-Dialkyl-10,20-diaryl-5,15-diazaporphyrins and Diversification of their N -Alkyl Groups

  2019cites this paper
• Coordination-Induced Spin-State Switching of an Aminyl-Radical-Bridged Nickel(II) Porphyrin Dimer between Doublet and Sextet States.

  2019cites this paper
• Platforms for Stable Carbon-Centered Radicals.

  2019cites this paper
• Stable (BIII -Subporphyrin-5-yl)dicyanomethyl Radicals.

  2019cites this paper
• Stable Diporphyrinylaminyl Radical and Nitrenium Ion.

  2018cites this paper
• A Stable Trimethylenemethane Triplet Diradical Based on a Trimeric Porphyrin Fused π-System.

  2018cites this paper
• Synthesis of (bis)Silicon Complexes of [38], [37], and [36]Octaphyrins: Aromaticity Switch and Stable Radical Cation.

  2018cites this paper
• Paramagnetism and Fluorescence of Zinc(II) Tripyrrindione: A Luminescent Radical Based on a Redox-Active Biopyrrin.

  2018cites this paper