Alkylgold complexes by the intramolecular aminoauration of unactivated alkenes.

No abstract is available for this paper.

• Publication year

  2010

• Venue

  Chemical Science

• Publication date

  2010-07-12

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1039/C0SC00255KPMID 24358445PMCID PMC3866133
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Hydroamination reactions by metal triflates: Brønsted acid vs. metal catalysis?

  2010cited by this paper
• Relative Kinetic Basicities of Organogold Compounds

  2010cited by this paper
• Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynes.

  2010cited by this paper
• Homogeneous gold-catalyzed oxidative carboheterofunctionalization of alkenes.

  2010cited by this paper
• A bonding model for gold(I) carbene complexes

  2009cited by this paper
• Synthesis, structure and reactivity of stable homoleptic gold(i) alkene cations.

  2009cited by this paper
• Syntheses, X-ray crystal structures, and solution behavior of monomeric, cationic, two-coordinate gold(I) pi-alkene complexes.

  2009cited by this paper
• Syntheses and X-ray crystal structures of cationic, two-coordinate gold(I) pi-alkene complexes that contain a sterically hindered o-biphenylphosphine ligand.

  2009cited by this paper
• Oxidative interception of the hydroamination pathway: a gold-catalyzed diamination of alkenes.

  2009cited by this paper
• Palladium-Catalyzed Carboauration of Alkynes and Palladium/Gold Cross-Coupling

  2009cited by this paper
• Reactions of cationic gold(I) with allenoates: synthesis of stable organogold(I) complexes and mechanistic investigations on gold-catalyzed cyclizations.

  2009cited by this paper
• Gold catalysis: isolation of vinylgold complexes derived from alkynes.

  2009cited by this paper
• Gold and platinum catalysis--a convenient tool for generating molecular complexity.

  2009cited by this paper
• Synthesis and structural characterisation of stable cationic gold(I) alkene complexes.

  2009cited by this paper
• Mechanistic studies of a palladium-catalyzed intramolecular hydroamination of unactivated alkenes: protonolysis of a stable palladium alkyl complex is the turnover-limiting step.

  2008cited by this paper
• Gold-catalyzed organic transformations.

  2008cited by this paper
• Mechanistic studies of the hydroamination of norbornene with electrophilic platinum complexes: the role of proton transfer.

  2008cited by this paper
• Ligand effects in homogeneous Au catalysis.

  2008cited by this paper
• Density functionals with broad applicability in chemistry.

  2008cited by this paper
• Synthesis and structural characterization of isolable phosphine coinage metal π-complexes

  2008cited by this paper
• Reactivity of Low-Valent Iridium, Rhodium, and Platinum Complexes with Di- and Tetrasubstituted Hydrazines

  2008cited by this paper
• Recent advances in syntheses of heterocycles and carbocycles via homogeneous gold catalysis. Part 1: Heteroatom addition and hydroarylation reactions of alkynes, allenes, and alkenes

  2008cited by this paper
• Gold(I)-catalyzed intermolecular hydroarylation of alkenes with indoles under thermal and microwave-assisted conditions.

  2008cited by this paper
• Hydroamination: direct addition of amines to alkenes and alkynes.

  2008cited by this paper
• Synthesis and structural characterization of stable organogold(I) compounds. Evidence for the mechanism of gold-catalyzed cyclizations.

  2008cited by this paper
• Intramolecular Hydroaminations Mediated by Reductive Mercuration or n‐Butyllithium To Afford 3‐Methyl‐ and 3,4‐Dimethyl‐1,2,3,4‐tetrahydroisoquinolines

  2007cited by this paper
• Platinum‐Catalyzed Intermolecular Hydroamination of Alkenes: Halide‐Anion‐Promoted Catalysis

  2007cited by this paper
• Intramolecular aminopalladation of alkenes as a key step to pyrrolidines and related heterocycles.

  2007cited by this paper
• Highly Efficient Au(I)-catalyzed intramolecular addition of beta-ketoamide to unactivated alkenes.

  2007cited by this paper
• Reversible C-F bond formation and the Au-catalyzed hydrofluorination of alkynes.

  2007cited by this paper
• Platinum-catalyzed hydrofunctionalization of unactivated alkenes with carbon, nitrogen and oxygen nucleophiles.

  2007cited by this paper
• Gold(I)-catalyzed intramolecular hydroamination of alkenyl carbamates.

  2006cited by this paper
• Brønsted acid catalyzed addition of phenols, carboxylic acids, and tosylamides to simple olefins.

  2006cited by this paper
• Alkene Coupling through Triflic Acid Elimination on Platinum(II)

  2006cited by this paper
• Gold-Catalyzed Hydroamination of C–C Multiple Bonds

  2006cited by this paper
• Phosphine gold(I)-catalyzed hydroamination of alkenes under thermal and microwave-assisted conditions.

  2006cited by this paper
• Room temperature hydroamination of N-alkenyl ureas catalyzed by a gold(i) N-heterocyclic carbene complex.

  2006cited by this paper
• Hydroamination and hydroalkoxylation catalyzed by triflic acid. Parallels to reactions initiated with metal triflates.

  2006cited by this paper
• Gold(I)-catalyzed intramolecular hydroamination of unactivated alkenes with carboxamides.

  2006cited by this paper
• Gold(I)-catalyzed intra- and intermolecular hydroamination of unactivated olefins.

  2006cited by this paper
• Room temperature palladium-catalyzed intramolecular hydroamination of unactivated alkenes.

  2006cited by this paper
• Gold(I)-catalyzed intermolecular addition of phenols and carboxylic acids to olefins.

  2005cited by this paper
• Valency and Bonding: A Natural Bond Orbital Donor-Acceptor Perspective

  2005cited by this paper
• Platinum-catalyzed intramolecular hydroamination of unactivated olefins with secondary alkylamines.

  2005cited by this paper
• Gold(I)-Catalyzed Conia-Ene Reaction of β-Ketoesters with Alkynes

  2004cited by this paper
• Gold(I)-catalyzed Conia-ene reaction of beta-ketoesters with alkynes.

  2004cited by this paper
• Gold catalysis: mild conditions for the synthesis of oxazoles from N-propargylcarboxamides and mechanistic aspects.

  2004cited by this paper
• Platinum-Catalyzed Intermolecular Hydroamination of Unactivated Olefins with Carboxamides

  2004cited by this paper
• Brønsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines.

  2002cited by this paper
• Transition Metals in the Synthesis and Functionalization of Indoles [New Synthesis Methods (72)]

  1988cited by this paper
• Nucleophilic attack on olefins co-ordinated to platinum. Part 4. Formation of neutral and cationic σ-adducts and of ring compounds: studies of stability

  1984cited by this paper
• Tetrahydropyridones via intramolecular ureidomercuration

  1983cited by this paper
• Palladium-catalyzed cyclization of .omega.-olefinic tosamides. Synthesis of nonaromatic nitrogen heterocycles

  1982cited by this paper
• Methyl(triphenylphosphine)gold

  1977cited by this paper
• Chloro(triphenylphosphine)gold(I)

  1976cited by this paper
• The Platinum‐Promoted Cyclization of 4‐Pentenylamine

  1975cited by this paper
• Palladium-promoted addition of amines to isolated double bonds

  1974cited by this paper
• NUCLEOPHILIC ATTACK ON OLEFINS COORDINATED TO PLATINUM

  1973cited by this paper
• Reaction d'aminomercuration—VII: Heterocyclisation intramoleculaire d'amines ethyleniques: Etude des differents parametres

  1972cited by this paper
• Addition reactions on coordinated olefinic ligands. II. Reaction between amines and monoolefins coordinated in cis-dichloro(olefin) (tert-phosphine)platinum(II) complexes

  1969cited by this paper
• 678. Olefin co-ordination compounds. Part V. Some diene complexes of palladium(II) and their alkoxy-derivatives

  1957cited by this paper
• 486. Olefin co-ordination compounds. Part IV. Diene complexes of platinum(II). The structure of Hofmann and von Narbutt's [dicyclopentadiene(RO)PtCl]

  1957cited by this paper
• The addition compounds of olefins with mercuric salts.

  1951cited by this paper
• Ueber das Verhalten von Mercurisalzen gegen Olefine

  year unknowncited by this paper

• Structure, synthesis and catalysis of ligated Au3 and Au4 species

  2026cites this paper
• Nitrogen-Centered Radical Cyclization Initiated by Proton-Coupled Electron Transfer: A Mechanistic Study of 5-Exo-trig and 6-Endo-trig Cyclization Pathways.

  2025cites this paper
• Ligand effects, solvent cooperation, and large kinetic solvent deuterium isotope effects in gold(I)-catalyzed intramolecular alkene hydroamination

  2024cites this paper
• Diborylmethyl Group as a Transformable Building Block for the Diversification of Nitrogen-Containing Molecules.

  2022cites this paper
• 1,1-Enediamines as highly polarized olefin ligands

  2022cites this paper
• 2‐Aminoalkylgold Complexes: The Putative Intermediate in Au‐Catalyzed Hydroamination of Alkenes Does Not Protodemetalate

  2022cites this paper
• DFT Studies of Au(I) Catalysed Reactions: Anion Effects and Reaction Selectivity

  2022cites this paper
• Cycloisomerization of π‐Coupled Heteroatom Nucleophiles by Gold Catalysis: En Route to Regiochemically Defined Heterocycles

  2021cites this paper
• Potassium Carbonate to Unlock a GaCl3-Catalyzed C–H Propargylation of Arenes

  2021cites this paper
• Catalysis with a Skip: Dynamically Coupled Addition, Proton Transfer, and Elimination During Au- and Pd-Catalyzed Diol Cyclization

  2021cites this paper
• Synthesis of Five‐Membered N ‐Heterocycles by Enantioselective, Metal‐Catalyzed, Intramolecular Hydroamination of Alkenes

  2020cites this paper
• PCET-Enabled Olefin Hydroamidation Reactions with N-Alkyl Amides.

  2019cites this paper
• The mechanism of Au(III) mediated alkoxycyclization of a 1,6-enyne.

  2019cites this paper
• Improving Homogeneous Cationic Gold Catalysis through a Mechanism-Based Approach.

  2019cites this paper
• Gold(i) catalysed regio- and stereoselective intermolecular hydroamination of internal alkynes: towards functionalised azoles.

  2019cites this paper
• Gold and Palladium Mediated Bimetallic Catalysis: Mechanistic Investigation through the Isolation of the Organogold(I) Intermediates

  2019cites this paper
• Proton supplier role of binuclear gold complexes in promoting hydrofunctionalisation of nonactivated alkenes

  2019cites this paper
• Gold Catalysis: Fundamentals and Recent Developments

  2019cites this paper
• Synthesis of five-membered N-heterocycles using silver metal

  2019cites this paper
• Intramolecular alkene hydroamination and degradation of amidines: divergent behavior of rare earth metal amidinate intermediates

  2018cites this paper
• Gold‐Katalyse für die Heterocyclenchemie: eine repräsentative Fallstudie zu Naturstoffen der Pyron‐Reihe

  2018cites this paper
• Gold Catalysis for Heterocyclic Chemistry: A Representative Case Study on Pyrone Natural Products.

  2018cites this paper
• [Reaction Development Utilizing the Features of Chemical Elements and Synthesis of Marine Natural Products].

  2018cites this paper
• Direct Evidence for the Origin of Bis-Gold Intermediates: Probing Gold Catalysis with Mass Spectrometry.

  2018cites this paper
• Testing the veracity of claims of Lewis acid catalysis

  2018cites this paper
• Intramolecular Hydroamidation of ortho‐Vinyl Benzamides Promoted by Potassium tert‐Butoxide/N,N‐Dimethylformamide

  2017cites this paper
• Gold(I)-Catalysed Asymmetric Hydroamination of Alkenes: A Silver- and Solvent-Dependent Enantiodivergent Reaction.

  2017cites this paper
• Intramolecular Hydroamination by a Primary Amine of an Unactivated Alkene on Gold Nanoclusters: A DFT Study

  2017cites this paper
• Gold(I)-Catalyzed Intramolecular Hydroamination of Unactivated Terminal and Internal Alkenes with 2-Pyridones.

  2017cites this paper
• Recent metal-catalysed asymmetric hydroaminations of alkenes

  2017cites this paper
• Oxidative Intramolecular 1,2-Amino-Oxygenation of Alkynes under AuI /AuIII Catalysis: Discovery of a Pyridinium-Oxazole Dyad as an Ionic Fluorophore.

  2017cites this paper
• Dual Gold and Visible Light Photoredox-Catalyzed Heteroarylations of Non-activated Alkenes

  2017cites this paper
• Gold(I)-Catalyzed N-Desulfonylative Amination versus N-to-O 1,5-Sulfonyl Migration: A Versatile Approach to 1-Azabicycloalkanes.

  2016cites this paper
• Gold‐Catalyzed Cycloisomerizations of 1,n‐Diyne Carbonates and Esters

  2016cites this paper
• Assessing Ligand and Counterion Effects in the Noble Metal Catalyzed Cycloisomerization Reactions of 1,6-Allenynes: a Combined Experimental and Theoretical Approach

  2016cites this paper
• Alkyne Difunctionalization by Dual Gold/Photoredox Catalysis.

  2016cites this paper
• Gold-catalyzed tandem synthesis of bioactive spiro-dipyrroloquinolines and its application in the one-step synthesis of incargranine B aglycone and seneciobipyrrolidine (I)

  2016cites this paper
• Recent advances in enantioselective gold catalysis.

  2016cites this paper
• Enantioselective synthesis of Iboga alkaloids and vinblastine via rearrangements of quaternary ammoniums

  2016cites this paper
• Insights into Alkene Activation by Gold: Nucleophile Activation with Base as a Trigger for Generation of Lewis Acidic Gold

  2016cites this paper
• Catalytic C–N Bond-Forming Reactions Enabled by Proton-Coupled Electron Transfer Activation of Amide N–H Bonds

  2016cites this paper
• Strong Electron-Donating Ligands Accelerate the Protodeauration Step in Gold(I)-Catalyzed Reactions: A Quantitative Understanding of the Ligand Effect

  2016cites this paper
• MP2 study on the selectivity of gold catalysis with alkene and furan activation

  2016cites this paper
• Mechanism of the Platinum(II)-Catalyzed Hydroamination of 4‑Pentenylamines

  2016cites this paper
• Determining the Impact of Ligand and Alkene Substituents on Bonding in Gold(I)-Alkene Complexes Supported by N-Heterocyclic Carbenes: A Computational Study.

  2016cites this paper
• Cross-Coupling of Meyer-Schuster Intermediates under Dual Gold-Photoredox Catalysis.

  2016cites this paper
• Mechanistic Study on Gold-Catalyzed Highly Selective Hydroamination of Alkylidenecyclopropanes.

  2016cites this paper
• Gold π-Complexes as Model Intermediates in Gold Catalysis.

  2016cites this paper
• Nucleophilic T-Shaped (LXL)Au(I)-Pincer Complexes: Protonation and Alkylation.

  2016cites this paper
• Catalytic Olefin Hydroamidation Enabled by Proton-Coupled Electron Transfer

  2015cites this paper
• Recent advances in metal free- and late transition metal-catalysed hydroamination of unactivated alkenes

  2015cites this paper
• Gold‐Catalyzed and Gold‐Mediated Synthesis of Heterocycles

  2015cites this paper
• Gold-Catalyzed Synthesis of Nitrogen Heterocyclic Compounds via Hydroamination Reactions

  2015cites this paper
• Late transition metal-catalyzed hydroamination and hydroamidation.

  2015cites this paper
• Enantioselective gold catalyzed dearomative [2+2]-cycloaddition between indoles and allenamides.

  2015cites this paper
• Cationic gold(III) alkyl complexes: generation, trapping, and insertion of norbornene.

  2015cites this paper
• Reaktivität von Goldkomplexen in metallorganischen Elementarreaktionen

  2015cites this paper
• Gold(I)-Catalyzed Dearomative [2+2]-Cycloaddition of Indoles with Activated Allenes: A Combined Experimental-Computational Study.

  2015cites this paper
• Stereoselective gold(I) domino catalysis of allylic isomerization and olefin cyclopropanation: mechanistic studies.

  2015cites this paper
• Gold(I)-catalyzed selective heterocyclization of propargylic thioureas: mechanistic study of competitive gold-activation mode.

  2015cites this paper
• Gold-catalyzed transformation of unsaturated alcohols.

  2015cites this paper
• Enantioselective [4 + 2] Cycloaddition Reaction of α,β‐Unsaturated Imine and Methyl Vinyl Ketone Catalyzed by Chiral Phosphine.

  2015cites this paper
• Reactivity of Gold Complexes towards Elementary Organometallic Reactions.

  2015cites this paper
• Methyl-, Ethenyl-, and Ethynyl-Bridged Cationic Digold Complexes Stabilized by Coordination to a Bulky Terphenylphosphine Ligand.

  2015cites this paper
• Gold-catalyzed oxidative reactions of propargylic carbonates involving 1,2-carbonate migration: stereoselective synthesis of functionalized alkenes.

  2014cites this paper
• The mechanism of gold(I)-catalyzed hydroalkoxylation of alkynes: an extensive experimental study.

  2014cites this paper
• Kinetics and mechanism of the racemization of aryl allenes catalyzed by cationic gold(I) phosphine complexes.

  2014cites this paper
• Gallium-assisted transfer hydrogenation of alkenes.

  2014cites this paper
• Synthesis of polycyclic indole skeletons by a gold(I)-catalyzed cascade reaction.

  2014cites this paper
• Enantioselective Intramolecular Hydroamination of Unactivated Alkenes Catalyzed by Mono‐ and Bis(gold) Phosphine Complexes.

  2014cites this paper
• Taming gold(I)-counterion interplay in the de-aromatization of indoles with allenamides.

  2014cites this paper
• Mechanisms of syn-insertion of alkynes and allenes into gold-silicon bonds: a comprehensive experimental/theoretical study.

  2014cites this paper
• A gold exchange: a mechanistic study of a reversible, formal ethylene insertion into a gold(III)-oxygen bond.

  2014cites this paper
• Axially chiral allenyl gold complexes.

  2014cites this paper
• Mononuclear gold catalysts for the asymmetric intramolecular hydroamination of alkenes

  2014cites this paper
• Intermediates and Elementary Reactions in Gold Catalysis

  2014cites this paper
• Synthesis and Reactivity of Gold–Olefin Complexes

  2014cites this paper
• Organometallic Intermediates of Gold Catalysis

  2014cites this paper
• Expanding the frontier of gold-catalyzed cyclizations and rational ligand design.

  2014cites this paper
• Asymmetric Intramolecular Hydroamination of Alkenes in Mild and Wet Conditions—Structure and Reactivity of Cationic Binuclear Gold(I) Catalysts

  2014cites this paper
• Mechanistic insights and functionalization of alkynes in homogeneous gold catalysis.

  2014cites this paper
• Dual Photoredox and Gold Catalysis: Intermolecular Multicomponent Oxyarylation of Alkenes

  2014cites this paper
• Synthesis of gem-diaurated species from alkynols.

  2013cites this paper
• Synthesis and study of cationic, two-coordinate triphenylphosphine-gold-π complexes.

  2013cites this paper
• Mechanistic insights into the gold(I)-catalyzed activation of glycosyl ortho-alkynylbenzoates for glycosidation.

  2013cites this paper
• Copper salts as additives in gold(I)-catalyzed reactions.

  2013cites this paper
• New developments in gold-catalyzed manipulation of inactivated alkenes

  2013cites this paper
• Gold(I)-catalyzed enantioselective bromocyclization reactions of allenes

  2013cites this paper
• Cationic, two-coordinate gold π complexes.

  2013cites this paper
• Gold-catalyzed cycloisomerization of 1,7-enyne esters to structurally diverse cis-1,2,3,6-tetrahydropyridin-4-yl ketones.

  2013cites this paper
• Gold(I)-catalyzed divergence in the preparation of bicyclic enol esters: from exclusively [3C+2C]-cycloaddition reactions to exclusive formation of vinylcyclopropanes.

  2013cites this paper
• Development of intramolecular vicinal diamination of alkenes: from palladium to bromine catalysis.

  2013cites this paper
• Gold and BINOL-Phosphoric Acid Catalyzed Enantioselective Hydroamination/N-Sulfonyliminium Cyclization Cascade

  2013cites this paper
• Synthesis of Saturated Heterocycles via Metal-Catalyzed Alkene Hydroamination or Hydroalkoxylation Reactions

  2013cites this paper
• GOLD‐CATALYZED CASCADE REACTIONS

  2013cites this paper
• Stereoselective Intramolecular Cyclopropanation through Catalytic Olefin Activation

  2013cites this paper
• Kationische, zweifach koordinierte Gold‐π‐Komplexe

  2013cites this paper
• Organogold(I) Phosphanes in Palladium‐Catalyzed Cross‐Coupling Reactions in Aqueous Media

  2013cites this paper
• Preparation and reactivity of terminal gold(I) amides and phosphides

  2013cites this paper
• Synthesis of Heterocycles via Metal-Catalyzed Reactions that Generate One or More Carbon-Heteroatom Bonds

  2013influential citation