Electronic absorption and ground state structure of carotenoid molecules.

No abstract is available for this paper.

• Publication year

  2013

• Venue

  Journal of Physical Chemistry B

• Publication date

  2013-01-15

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1021/jp309908rPMID 23294447
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Absorption shifts in carotenoids - Influence of index of refraction and submolecular electric fields

  2011cited by this paper
• Molecular factors controlling photosynthetic light harvesting by carotenoids.

  2010cited by this paper
• Ultrafast dynamics and excited state spectra of open-chain carotenoids at room and low temperatures.

  2007cited by this paper
• Function of two beta-carotenes near the D1 and D2 proteins in photosystem II dimers.

  2007cited by this paper
• Two stereoisomers of spheroidene in the Rhodobacter sphaeroides R26 reaction center: a DFT analysis of resonance Raman spectra.

  2007cited by this paper
• Function of two β-carotenes near the D1 and D2 proteins in photosystem II dimers

  2007cited by this paper
• Identification of a mechanism of photoprotective energy dissipation in higher plants

  2007cited by this paper
• Solvent effects on the S0(1(1)Ag-) --> S2(1(1)Bu+) transition of beta-carotene, echinenone, canthaxanthin, and astaxanthin in supercritical CO2 and CF3H.

  2006cited by this paper
• Solvent Effects on the S0(11Ag-) S2(11Bu+) Transition of β-Carotene, Echinenone, Canthaxanthin, and Astaxanthin in Supercritical CO2 and CF3H

  2006cited by this paper
• Molecular basis of photoprotection and control of photosynthetic light-harvesting

  2005cited by this paper
• Low-lying singlet states of carotenoids having 8-13 conjugated double bonds as determined by electronic absorption spectroscopy

  2005cited by this paper
• Linear polyenes: models for the spectroscopy and photophysics of carotenoids.

  2004cited by this paper
• Raman spectra of carotenoids in natural products.

  2003cited by this paper
• An alternative carotenoid-to-bacteriochlorophyll energy transfer pathway in photosynthetic light harvesting

  2002cited by this paper
• Xanthophylls of the major photosynthetic light‐harvesting complex of plants: identification, conformation and dynamics

  2000cited by this paper
• Effect of the Solvent Environment on the Spectroscopic Properties and Dynamics of the Lowest Excited States of Carotenoids

  2000cited by this paper
• Characterization of the different peripheral light-harvesting complexes from high- and low-light grown cells from Rhodopseudomonas palustris.

  1999cited by this paper
• The roles of specific xanthophylls in photoprotection.

  1997cited by this paper
• REGULATION OF LIGHT HARVESTING IN GREEN PLANTS.

  1996cited by this paper
• Quenching of chlorophyll fluorescence in the major light-harvesting complex of photosystem II: a systematic study of the effect of carotenoid structure.

  1996cited by this paper
• Crystal structure of an integral membrane light-harvesting complex from photosynthetic bacteria

  1995cited by this paper
• Shifts of the 1A−g→1B+u electronic absorption of carotenoids in nonpolar and polar solvents

  1994cited by this paper
• Carotenoids as accessory light-harvesting pigments

  1994cited by this paper
• Application of near-IR Fourier transform resonance Raman spectroscopy to the study of photosynthetic proteins

  1993cited by this paper
• Antioxidant effects of carotenoids in vivo and in vitro: an overview.

  1992cited by this paper
• ABSORPTION SPECTRAL SHIFTS OF CAROTENOIDS RELATED TO MEDIUM POLARIZABILITY

  1991cited by this paper
• Normal-coordinate analysis of retinal isomers and assignments of Raman and infrared bands

  1983cited by this paper
• Electronic structure of polyenes related to the visual chromophore. A simple model for the observed band shapes.

  1977cited by this paper
• Vibrational spectra of some carotenoids and related linear polyenes. A Raman spectroscopic study.

  1973cited by this paper
• THE IN VITRO PHOTOCHEMISTRY OF BIOLOGICAL MOLECULES‐III. ABSORPTION SPECTRA, LIFETIMES AND RATES OF OXYGEN QUENCHING OF THE TRIPLET STATES OF β‐CAROTENE, RETINAL AND RELATED POLYENES

  1973cited by this paper
• On the origin of a low-lying forbidden transition in polyenes and related molecules

  1972cited by this paper
• π-Electronic Structure and Absorption Spectra of Carotenoids

  1964cited by this paper
• Absorption Spectra and Chemical Structures. I. Conjugated Polyenes and p-Polyphenyls

  1955cited by this paper
• Empirical Relationships of the Minor Bands in the Absorption Spectra of Polyenes.

  1954cited by this paper
• Molecular Structure and Absorption Spectra of Carotenoids

  1952cited by this paper
• An Investigation of Certain Solvent Effect in Absorption Spectra

  1952cited by this paper

• Reassessing carotenoid photophysics -- new light on dark states

  2026influential citation
• Singlet fission in heterogeneous lycopene aggregates

  2025cites this paper
• Vibrational signature of 11B+u and hot 21A-g excited states of carotenoids revisited by femtosecond stimulated Raman spectroscopy.

  2025cites this paper
• Exploring the solvent regulated electron status properties of astaxanthin by Raman spectroscopy and DFT simulation.

  2025cites this paper
• Single-cell pigment analysis of phototrophic and phyllosphere bacteria using simultaneous detection of Raman and autofluorescence spectra

  2025cites this paper
• Structural integrity and near-infrared absorption of the LH1 complex of Thermochromatium tepidum: Influence from the C-terminal lysine residues of LH1 α-polypeptide.

  2025cites this paper
• Exploring the Local Environment Effect on Properties of all-Trans-Retinal by Two-Dimensional Correlation Resonance Raman Spectroscopy

  2024cites this paper
• Target Analysis Resolves the Ground and Excited State Properties from Femtosecond Stimulated Raman Spectra

  2024cites this paper
• Femtosecond Stimulated Raman Spectroscopy of Linear Carotenoids.

  2024cites this paper
• Chick sexing based on the blood analysis using Raman spectroscopy

  2024cites this paper
• Raman vibrational signatures of excited states of echinenone in the Orange Carotenoid Protein (OCP) and implications for its photoactivation mechanism.

  2024cites this paper
• Predicting Solvatochromism of Chromophores in Proteins through QM/MM and Machine Learning

  2024cites this paper
• The presence of free palmitic acid modulates the effects of lutein on structural and dynamic properties of lipid membranes.

  2024cites this paper
• Interaction mechanism of carotenoids and polyphenols in mango peels.

  2023cites this paper
• Isomerization of carotenoids in photosynthesis and metabolic adaptation

  2023cites this paper
• Quasi-classical simulations of resonance Raman spectra based on path integral linearization.

  2023cites this paper
• Raman Spectroscopy of Carotenoid Compounds for Clinical Applications—A Review

  2022cites this paper
• Ultrafast laser spectroscopy uncovers mechanisms of light energy conversion in photosynthesis and sustainable energy materials

  2022cites this paper
• Lutein/β-carotene ratio in extra virgin olive oil: An easy and rapid quantification method by Raman spectroscopy.

  2022cites this paper
• Intramolecular charge-transfer enhances energy transfer efficiency in carotenoid-reconstituted light-harvesting 1 complex of purple photosynthetic bacteria

  2022cites this paper
• Nanoarchitectonics of n-type organic semiconductors polymerized by Cu(0)-mediated RDRP of acrylates based monomers

  2022cites this paper
• Resonance Raman: A powerful tool to interrogate carotenoids in biological matrices.

  2022cites this paper
• Micrococcus lylae MW407006 Pigment: Production, Optimization, Nano-Pigment Synthesis, and Biological Activities

  2022cites this paper
• Modulated excited state geometry and Electron-Phonon coupling of lutein by temperature and solvent polarizability.

  2022cites this paper
• Electronic and Vibrational Properties of Allene Carotenoids

  2022cites this paper
• Simulation of Ab Initio Optical Absorption Spectrum of β-Carotene with Fully Resolved S0 and S2 Vibrational Normal Modes.

  2022cites this paper
• Third- and fifth-order optical nonlinearities of Norbixin

  2021cites this paper
• Photostability of apocarotenoids on surface of TiO2 semiconductor nanoparticles

  2021cites this paper
• Nanoarchitecturing hybridized metal-organic framework/graphene nanosheet for removal of an organic pollutant

  2021cites this paper
• Estimation of conjugated C = C bonds effective number and conjugation energy of carotenoids

  2021cites this paper
• Structure elucidation of the novel carotenoid gemmatoxanthin from the photosynthetic complex of Gemmatimonas phototrophica AP64

  2021cites this paper
• Mechanisms shaping the synergism of zeaxanthin and PsbS in photoprotective energy dissipation in the photosynthetic apparatus of plants

  2021cites this paper
• Singlet fission in naturally-organized carotenoid molecules.

  2021cites this paper
• Pigment structure in the light-harvesting protein of the siphonous green alga Codium fragile.

  2021cites this paper
• A new, unquenched intermediate of LHCII

  2021cites this paper
• Modeling Dynamic Conformations of Organic Molecules: Alkyne Carotenoids in Solution

  2020cites this paper
• Effect of pH on fluorescence and absorption of aggregates of chlorophyll a and carotenoids

  2020cites this paper
• The diversity of linear conjugated polyenes and colours in nature: Raman spectroscopy as a diagnostic tool.

  2020cites this paper
• Photoreduction of carotenoids in the aerobic anoxygenic photoheterotrophs probed by real time Raman spectroscopy.

  2020cites this paper
• Excited state geometry of β-carotene influenced by environments: the nature and decisive role of solvent revealing by two-dimensional resonance Raman correlation spectroscopy.

  2020cites this paper
• Spectroscopy and excited state dynamics of nearly infinite polyenes.

  2020cites this paper
• Raman spectroscopic signatures of carotenoids and polyenes enable label-free visualization of microbial distributions within pink biofilms

  2020cites this paper
• Photophysics of deinoxanthin, the keto-carotenoid bound to the main S-layer unit of Deinococcus radiodurans

  2020cites this paper
• A photosynthetic antenna complex foregoes unity carotenoid-to-bacteriochlorophyll energy transfer efficiency to ensure photoprotection

  2020cites this paper
• How carotenoid distortions may determine optical properties: lessons from the Orange Carotenoid Protein.

  2019cites this paper
• Resonance Raman features all-trans-β-carotene during phase transition and theoretical investigation analysis

  2019cites this paper
• Carotenoid composition and conformation in retinal oil droplets of the domestic chicken*

  2019cites this paper
• Spectral and structural properties of carotenoids - DFT and thermochemical calculations

  2019cites this paper
• Raman spectroscopy of natural and cultured pearls and pearl producing mollusc shells

  2019cites this paper
• The origin of the dark S1 state in carotenoids: a comprehensive model

  2019cites this paper
• Structural peculiarities of keto-carotenoids in water-soluble proteins revealed by simulation of linear absorption.

  2019cites this paper
• Vibrational relaxation dynamics of β-carotene and its derivatives with substituents on terminal rings in electronically excited states as studied by femtosecond time-resolved stimulated Raman spectroscopy in the near-IR region.

  2018cites this paper
• Binding of pigments to the cyanobacterial high-light-inducible protein HliC

  2018cites this paper
• External Field Effect on Electronic and Vibrational Properties of Carotenoids

  2018cites this paper
• Cooperative Photoprotection by Multicompositional Carotenoids in the LH1 Antenna from a Mutant Strain of Rhodobacter sphaeroides.

  2018cites this paper
• Pigment configuration in the light-harvesting protein of the xanthophyte alga Xanthonema debile

  2018cites this paper
• Effects of carotenoids on the absorption and fluorescence spectral properties and fluorescence quenching of Chlorophyll a.

  2018cites this paper
• Unified analysis of optical absorption spectra of carotenoids based on a stochastic model.

  2018cites this paper
• Molecular Origin of Photoprotection in Cyanobacteria Probed by Watermarked Femtosecond Stimulated Raman Spectroscopy

  2018cites this paper
• Side Methyl Groups Control the Conformation and Contribute to Symmetry Breaking of Isoprenoid Chromophores.

  2018cites this paper
• All-trans-β-carotene absorption shift and electron-phonon coupling modulated by solvent polarizability

  2018cites this paper
• Lycopene crystalloids exhibit singlet exciton fission in tomatoes.

  2018cites this paper
• Photoreaction dynamics of functional photoreceptor proteins

  2018cites this paper
• Identification of a consistent polyene component of purple pigment in diseased sclerites of Caribbean corals across region, species, and insult agent.

  2017cites this paper
• Electronic and vibrational properties of carotenoids: from in vitro to in vivo

  2017cites this paper
• Pigment structure in the violaxanthin–chlorophyll-a-binding protein VCP

  2017cites this paper
• Dependence of the hydration status of bacterial light-harvesting complex 2 on polyol cosolventsf

  2017cites this paper
• Contribution of the transition moments, form of the absorption band, exciton, and the correlation effects in the linear and nonlinear optical properties of conjugated polymers

  2017cites this paper
• Unveiling the Aggregation of Lycopene in Vitro and in Vivo: UV-Vis, Resonance Raman, and Raman Imaging Studies.

  2017cites this paper
• Localization and Orientation of Xanthophylls in a Lipid Bilayer

  2017cites this paper
• Carotenoid Singlet Fission Reactions in Bacterial Light Harvesting Complexes As Revealed by Triplet Excitation Profiles.

  2017cites this paper
• Twisting a (cid:2) -Carotene, an Adaptive Trick from Nature for Dissipating Energy during Photoprotection *

  2017influential citation
• Concentration Effect on Quenching of Chlorophyll a Fluorescence by All-Trans-β-Carotene in Photosynthesis

  2017cites this paper
• Triplet–triplet energy transfer in artificial and natural photosynthetic antennas

  2017cites this paper
• Binding of pigments to the cyanobacterial high-light-inducible protein HliC

  2017cites this paper
• Computational study on the color change of 3′-hydroxyechinenone in the orange carotenoid protein

  2016cites this paper
• Twisting a β-Carotene, an Adaptive Trick from Nature for Dissipating Energy during Photoprotection*

  2016influential citation
• Biophysical Characterization of Carotenoids and Carotenoid Containing Proteins Using Resonance Raman Spectroscopy

  2016cites this paper
• Pigment structure in the FCP-like light-harvesting complex from Chromera velia.

  2016cites this paper
• A Unified Picture of S* in Carotenoids

  2016cites this paper
• New insights into the photochemistry of carotenoid spheroidenone in light-harvesting complex 2 from the purple bacterium Rhodobacter sphaeroides

  2016cites this paper
• Combining classical molecular dynamics and quantum mechanical methods for the description of electronic excitations: The case of carotenoids

  2016cites this paper
• Quenching Capabilities of Long-Chain Carotenoids in Light-Harvesting-2 Complexes from Rhodobacter sphaeroides with an Engineered Carotenoid Synthesis Pathway

  2016cites this paper
• Assembly of photoactive orange carotenoid protein from its domains unravels a carotenoid shuttle mechanism

  2016cites this paper
• How do surrounding environments influence the electronic and vibrational properties of spheroidene?

  2015cites this paper
• Resonance Raman spectra of carotenoid molecules: influence of methyl substitutions.

  2015cites this paper
• Structure and Conformation of the Carotenoids in Human Retinal Macular Pigment

  2015cites this paper
• Ultrafast Dynamics of Long Homologues of Carotenoid Zeaxanthin.

  2015cites this paper
• Spectroscopic studies of neutral and chemically oxidized species of β-carotene, lycopene and norbixin in CH2Cl2: Fluorescence from intermediate compounds

  2015cites this paper
• Echinenone vibrational properties: From solvents to the orange carotenoid protein.

  2015cites this paper
• Ultrafast Triplet Generation and its Sensitization Drives Efficient Photoisomerization of Tetra-cis-lycopene to All-trans-lycopene.

  2015cites this paper
• Tuning the spectroscopic properties of aryl carotenoids by slight changes in structure.

  2015cites this paper
• Different Response of Carbonyl Carotenoids to Solvent Proticity Helps To Estimate Structure of the Unknown Carotenoid from Chromera velia.

  2015cites this paper
• Vibrational techniques applied to photosynthesis: Resonance Raman and fluorescence line-narrowing.

  2015cites this paper
• Functional characteristics of spirilloxanthin and keto-bearing Analogues in light-harvesting LH2 complexes from Rhodobacter sphaeroides with a genetically modified carotenoid synthesis pathway.

  2015cites this paper
• Diversity, physiology, and evolution of avian plumage carotenoids and the role of carotenoid-protein interactions in plumage color appearance.

  2015cites this paper
• Excited state properties of 3'-hydroxyechinenone in solvents and in the orange carotenoid protein from Synechocystis sp. PCC 6803.

  2014cites this paper
• Etude des propriétés électroniques des caroténoïdes dans la photosynthèse naturelle et artificielle

  2014cites this paper
• Aus den Universitätsstandorten: Martin‐Luther‐Universität Halle‐Wittenberg

  2014cites this paper
• Resonance Raman spectra and electronic transitions in carotenoids: a density functional theory study.

  2014cites this paper