Molecular engineering of the internal charge transfer in thiophene-triphenylamine hybrid pi-conjugated systems.

Introduction of electroaccepting groups at the periphery of triphenylamine-based derivatives leads to an internal charge-transfer band. Syntheses and spectroscopic, electrochemical, and theoretical studies of various derivatives which differ by the strength and the number of electroacceptor groups are presented. These various results show that the ICT band and the acceptor/donor abilities of derivatives can be finely tuned.

• Publication year

  2007

• Venue

  Journal of Organic Chemistry

• Publication date

  2007-10-03

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1021/JO701390YPMID 17914845
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

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