Low-temperature catalytic H2 oxidation over Au nanoparticle/TiO2 dual perimeter sites.

No abstract is available for this paper.

• Publication year

  2011

• Venue

  Angewandte Chemie

• Publication date

  2011-10-17

• Fields of study

  Medicine, Materials Science, Chemistry

• Identifiers
  DOI 10.1002/anie.201101612PMID 21630401
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Vibrational Spectroscopic Observation of Weakly Bound Adsorbed Molecular Oxygen on Powdered Titanium Dioxide

  2010cited by this paper
• Hydrogen loading of oxide powder particles: a transmission IR study for the case of zinc oxide.

  2010cited by this paper
• Partial and complete reduction of O2 by hydrogen on transition metal surfaces

  2010cited by this paper
• On the mechanism of hydrogen-promoted gold-catalyzed CO oxidation

  2009cited by this paper
• Promotional effect of H2 on CO oxidation over Au/TiO2 studied by operando infrared spectroscopy

  2009cited by this paper
• Hydrogen dissociation by gold clusters.

  2009cited by this paper
• Direct Spectroscopic Observation of the Role of Humidity in Surface Diffusion through an Ionic Adsorbent Powder. The Behavior of Adsorbed Pyridine on Nanocrystalline MgO

  2009cited by this paper
• Imaging of the hydrogen subsurface site in rutile TiO2.

  2009cited by this paper
• Geometric and electronic characteristics of active sites on TiO2-supported Au nano-catalysts: insights from first principles.

  2009cited by this paper
• Gold particle size effects in the gas-phase hydrogenation of m-dinitrobenzene over Au/TiO2

  2009cited by this paper
• Reactive oxygen on a Au/TiO2 supported catalyst

  2009cited by this paper
• Diffusion versus desorption: complex behavior of H atoms on an oxide surface.

  2008cited by this paper
• Oxidation of CO and H2 by O2 and N2O on Au/TiO2 catalysts in microreactors

  2008cited by this paper
• Spectroscopic Detection of Hydrogen Atom Spillover from Au Nanoparticles Supported on TiO2: Use of Conduction Band Electrons

  2007cited by this paper
• Theoretical Investigation of the Formation of Hydrogen Peroxide from H2 and O2 over Anionic Gold Clusters Aun- (n = 1−4)

  2007cited by this paper
• n-Type doping of TiO2 with atomic hydrogen-observation of the production of conduction band electrons by infrared spectroscopy

  2007cited by this paper
• Effects of Hydrogen on the Reactivity of O2 toward Gold Nanoparticles and Surfaces

  2007cited by this paper
• Activity of CeOx and TiOx Nanoparticles Grown on Au(111) in the Water-Gas Shift Reaction

  2007cited by this paper
• Insights into activation, deactivation and hydrogen-induced promotion of a Au/TiO2 reference catalyst in CO oxidation

  2006cited by this paper
• The adsorption of triethylenediamine on Al(2)O(3)-I: a vibrational spectroscopic and desorption kinetic study of surface bonding.

  2005cited by this paper
• Comparison of the catalytic activity of Au3, Au4+, Au5, and Au5- in the gas-phase reaction of H2 and O2 to form hydrogen peroxide: a density functional theory investigation.

  2005cited by this paper
• Kinetic study of a direct water synthesis over silica-supported gold nanoparticles.

  2005cited by this paper
• Depletion of conduction band electrons in TiO2 by water chemisorption – IR spectroscopic studies of the independence of Ti–OH frequencies on electron concentration

  2005cited by this paper
• Adsorption of O2 and oxidation of CO at Au nanoparticles supported by TiO2(110).

  2004cited by this paper
• The Structure of Catalytically Active Gold on Titania

  2004cited by this paper
• The nature of the surface species formed on Au/TiO2 during the reaction of H2 and O2: an inelastic neutron scattering study.

  2004cited by this paper
• Kinetics, mechanism, and the influence of H2 on the CO oxidation reaction on a Au/TiO2 catalyst

  2004cited by this paper
• On the origin of the catalytic activity of gold nanoparticles for low-temperature CO oxidation

  2004cited by this paper
• Fuel processing for low-temperature and high-temperature fuel cells

  2002cited by this paper
• Alternative Methods for the Preparation of Gold Nanoparticles Supported on TiO2

  2002cited by this paper
• Mechanism of dihydrogen cleavage by high-valent metal oxo compounds: experimental and computational studies.

  2001cited by this paper
• Onset of catalytic activity of gold clusters on titania with the appearance of nonmetallic properties

  1998cited by this paper
• Novel Gold Catalysts for the Oxidation of Carbon Monoxide at a Temperature far Below 0 °C

  1987cited by this paper

• Dual Au-Ti perimeter site engineering enables cooperative N2 activation for efficient electrochemical nitrogen fixation

  2026cites this paper
• Directional white-light emission from sintered carbon dot titanium dioxide structures based on near-field confinement

  2025cites this paper
• Assembling a Metastable Electron Fence within Gold-Zeolite Interfaces for Boosted Propylene Epoxidation.

  2025cites this paper
• Catalytic consequences of vanadium-oxygen coordination on alkanol oxidative dehydrogenation

  2025cites this paper
• Distinct Site Motifs Activate O2 and H2 on Supported Au Nanoparticles in Liquid Water

  2024cites this paper
• Improving Charge Transfer under Strong Coupling Conditions via Interfacial Modulation

  2024cites this paper
• Upside-Down Adsorption: The Counterintuitive Influences of Surface Entropy and Surface Hydroxyl Density on Hydrogen Spillover.

  2024cites this paper
• Strategies to improve hydrogen activation on gold catalysts

  2024cites this paper
• Influence of Time Scale on the Reaction Mechanism of CO Oxidation over a Au/TiO2 Catalystt.

  2023cites this paper
• Calcium silicate hydrate decorated by Fe, Ti co-modified birnessite direct multi-component photocatalyst: Design, preparation and photocatalytic performance under visible light irradiation

  2023cites this paper
• Research Progress of Ce-Based Catalysts in Catalytic Oxidation of HCl

  2023cites this paper
• Probing active sites for carbon oxides hydrogenation on Cu/TiO2 using infrared spectroscopy

  2022cites this paper
• Spectroscopic Evidence for the Involvement of Interfacial Sites in O–O Bond Activation over Gold Catalysts

  2022cites this paper
• In situ UV–vis plasmon resonance spectroscopic assessment of oxygen and hydrogen adsorption location on supported gold catalysts

  2021cites this paper
• Water-Gas Shift Reaction over Supported Au Nanoparticles

  2021cites this paper
• Hydrogen Adsorption at the Au/TiO2 Interface: Quantitative Determination and Spectroscopic Signature of the Reactive Interface Hydroxyl Groups at the Active Site

  2021cites this paper
• Low-Temperature Heterogeneous Oxidation Catalysis and Molecular Oxygen Activation

  2021cites this paper
• Combining trace Pt with surface silylation to boost Au/uncalcined TS-1 catalyzed propylene epoxidation with H2 and O2

  2021cites this paper
• Recent progress in single-atom alloys: Synthesis, properties, and applications in environmental catalysis.

  2021cites this paper
• Operando DRIFTS-MS investigation on plasmon-thermal coupling mechanism of CO2 hydrogenation on Au/TiO2: The enhanced generation of oxygen vacancies

  2021cites this paper
• Kinetics of H2 Adsorption at the Metal-Support Interface of Au/TiO2 Catalysts probed by Broad Background IR Absorbance.

  2021cites this paper
• Controlling hot electron flux and catalytic selectivity with nanoscale metal-oxide interfaces

  2021cites this paper
• Dilute Pd/Au Alloys Replace Au/TiO2 Interface for Selective Oxidation Reactions

  2020cites this paper
• Aspects of the interaction between Au and Fe in supported catalysts applied to the preferential CO oxidation

  2020cites this paper
• TiO2 Ultrathin Coating of SBA-15/Au by Atomic Layer Deposition for Enhanced Catalytic Performance in Epoxidation of Styrene

  2020cites this paper
• Combining Benzyl Alcohol Oxidation Saturation Kinetics and Hammett Studies as Mechanistic Tools for Examining Supported Metal Catalysts

  2020cites this paper
• Globally Optimized Equilibrium Shapes of Zirconia-Supported Rh and Pt Nanoclusters: Insights into Site Assembly and Reactivity

  2019cites this paper
• On the Limited Role of Electronic Support Effects in Selective Alkyne Hydrogenation: A Kinetic Study of Au/MOx Catalysts Prepared from Oleylamine‐Capped Colloidal Nanoparticles

  2019cites this paper
• Colloidal Nanocrystals as Building Blocks for Well-Defined Heterogeneous Catalysts

  2019cites this paper
• Abundant Ce3+ Ions in Au-CeOx Nanosheets to Enhance CO2 Electroreduction Performance.

  2019cites this paper
• Deactivation of Pt-Au/TiO2-CeO2 catalyst for co-oxidation of HCHO, H2 and CO at room temperature: Degradations of active sites and mutual influence between reactants

  2019cites this paper
• Temperature‐Dependent Study of Catalytic Ag Nanoparticles Entrapped Resin Nanocomposite towards Reduction of 4‐Nitrophenol

  2019cites this paper
• Boosting hot electron flux and catalytic activity at metal–oxide interfaces of PtCo bimetallic nanoparticles

  2018cites this paper
• Solvation-Induced Changes in the Mechanism of Alcohol Oxidation at Gold/Titania Nanocatalysts in the Aqueous Phase versus Gas Phase.

  2018cites this paper
• Synthesis of a mononuclear Ti complex: A molecular precursor strategy for control of silica supported single site Ti decorated Au catalysts for cyclooctene epoxidation

  2018cites this paper
• Dynamic surface composition in a Mars-van Krevelen type reaction: CO oxidation on Au/TiO2

  2018cites this paper
• Approaches for Understanding and Controlling Interfacial Effects in Oxide-Supported Metal Catalysts

  2018cites this paper
• Consecutive Oxidation of Three H2 Molecules by a Gold-Vanadium Oxide Cluster Cation AuVO4+

  2018cites this paper
• H2 dissociation by Au1-doped closed-shell titanium oxide cluster anions

  2018cites this paper
• Synthesis of Colloidal Pd/Au Dilute Alloy Nanocrystals and Their Potential for Selective Catalytic Oxidations.

  2018cites this paper
• Theoretical Studies on the Direct Propylene Epoxidation Using Gold-Based Catalysts: A Mini-Review

  2018cites this paper
• Atomic-Scale Explanation of O2 Activation at the Au-TiO2 Interface.

  2018cites this paper
• Opportunities and Challenges in the Synthesis, Characterization, and Catalytic Properties of Controlled Nanostructures

  2017cites this paper
• Catalysis and Photocatalysis by Nanoscale Au/TiO2: Perspectives for Renewable Energy

  2017cites this paper
• Pt-Au/MOx-CeO2 (M = Mn, Fe, Ti) Catalysts for the Co-Oxidation of CO and H2 at Room Temperature

  2017cites this paper
• Mechanism of hydrogen adsorption on gold nanoparticles and charge transfer probed by anisotropic surface plasmon resonance.

  2017cites this paper
• MoS2-supported gold nanoparticle for CO hydrogenation

  2017cites this paper
• Adsorption Energy Correlations at the Metal–Support Boundary

  2017cites this paper
• Importance of metal-oxide interfaces in heterogeneous catalysis: A combined DFT, microkinetic, and experimental study of water-gas shift on Au/MgO

  2017cites this paper
• Promoting effect of TiO 2 on the catalytic performance of Pt-Au/TiO 2 (x)-CeO 2 for the co-oxidation of CO and H 2 at room temperature

  2017cites this paper
• Metal-mediated catalysis in the gas phase: A review

  2017cites this paper
• Feasible and Clean Solid-Phase Synthesis of LiNbO3 by Microwave-Induced Combustion and Its Application as Catalyst for Low-Temperature Aniline Oxidation

  2017cites this paper
• H2 Oxidation Mediated by Au1-Doped Vanadium Oxide Cluster Cation AuV2O5+: A Comparative Study with AuCe2O4.

  2017cites this paper
• Pt–Au/CeO2 catalysts for the simultaneous removal of carbon monoxide and formaldehyde

  2016cites this paper
• Reactive Structural Motifs of Au Nanoclusters for Oxygen Activation and Subsequent CO Oxidation

  2016cites this paper
• Theoretical mechanistic insights into propylene epoxidation on Au-based catalysts: Surface O versus OOH as oxidizing agents

  2016cites this paper
• A heterostructured TiO2–C3N4 support for gold catalysts: a superior preferential oxidation of CO in the presence of H2 under visible light irradiation and without visible light irradiation

  2016cites this paper
• Interfacial Cu+ promoted surface reactivity: Carbon monoxide oxidation reaction over polycrystalline copper–titania catalysts

  2016cites this paper
• Infrared studies of propene and propene oxide adsorption on nanoparticulate Au/TiO2

  2016cites this paper
• On the activity of supported Au catalysts in the liquid phase hydrogenation of CO2 to formates

  2016cites this paper
• Formation, Migration, and Reactivity of Au-CO Complexes on Gold Surfaces.

  2016cites this paper
• Generation of Hydroxyl Radicals in the Reaction of Dihydrogen with AuNbO4+ Cluster Cations.

  2016cites this paper
• Long-Circulating Au-TiO2 Nanocomposite as a Sonosensitizer for ROS-Mediated Eradication of Cancer.

  2016cites this paper
• Surface chemistry of Au/TiO2: Thermally and photolytically activated reactions

  2016cites this paper
• New materials for catalysis and energy storage devices

  2016cites this paper
• Consecutive H2 Oxidation Mediated by Au2VO4+ Clusters

  2016cites this paper
• Highly Efficient Catalysis of Preferential Oxidation of CO in H2-Rich Stream by Gold Single-Atom Catalysts

  2015cites this paper
• Carbon nanotube-supported gold nanoparticles as efficient catalyst for the selective hydrogenation of nitroaromatic derivatives to anilines

  2015cites this paper
• Mechanistic Insights into the Catalytic Oxidation of Carboxylic Acids on Au/TiO2: Partial Oxidation of Propionic and Butyric Acid to Gold Ketenylidene through Unsaturated Acids

  2015cites this paper
• A facile approach to fabricate halloysite/metal nanocomposites with preformed and in situ synthesized metal nanoparticles: a comparative study of their enhanced catalytic activity.

  2015cites this paper
• Electric field changes on Au nanoparticles on semiconductor supports--the molecular voltmeter and other methods to observe adsorbate-induced charge-transfer effects in Au/TiO2 nanocatalysts.

  2015cites this paper
• Rapid removal and decomposition of gaseous acetaldehyde by the thermo- and photo-catalysis of gold nanoparticle-loaded anatase titanium(IV) oxide.

  2015cites this paper
• Reactivity of Gold Clusters in the Regime of Structural Fluxionality

  2015cites this paper
• Rapid removal and subsequent low-temperature mineralization of gaseous acetaldehyde by the dual thermocatalysis of gold nanoparticle-loaded titanium(IV) oxide

  2015cites this paper
• Nanocatalysis: size- and shape-dependent chemisorption and catalytic reactivity

  2015cites this paper
• Metallic Nanostructures for Catalytic Applications

  2015cites this paper
• Tailoring metal-oxide interfaces of inverse catalysts of TiO2/nanoporous-Au under hydrogen oxidation.

  2015cites this paper
• Cooperative H2 Activation at Ag Cluster/θ-Al2O3(110) Dual Perimeter Sites: A Density Functional Theory Study

  2014cites this paper
• Nature and Role of Activated Molecular Oxygen Species at the Gold/Titania Interface in the Selective Oxidation of Alcohols

  2014cites this paper
• Insights into catalytic oxidation at the Au/TiO(2) dual perimeter sites.

  2014cites this paper
• Selective catalytic oxidative-dehydrogenation of carboxylic acids-acrylate and crotonate formation at the Au/TiO2 interface.

  2014cites this paper
• Engineering nanointerfaces for nanocatalysis.

  2014cites this paper
• Insight into active sites of Pd–Au/TiO2 catalysts in hydrogen peroxide synthesis directly from H2 and O2

  2014cites this paper
• New advances in the use of infrared absorption spectroscopy for the characterization of heterogeneous catalytic reactions.

  2014cites this paper
• Direct Formation of Acetate from the Partial Oxidation of Ethylene on a Au/TiO2 Catalyst

  2013cites this paper
• O2 Adsorption and Oxidative Activity on Gold-Based Catalysts with and without a Ceria Support

  2013cites this paper
• Rationale for the higher reactivity of interfacial sites in methanol decomposition on Au13/TiO2(110).

  2013cites this paper
• CO oxidation on h-BN supported Au atom.

  2013cites this paper
• Enhancement of Catalyst Performance in the Direct Propene Epoxidation: A Study into Gold–Titanium Synergy

  2013cites this paper
• Catalysis from First Principles: Towards Accounting for the Effects of Nanostructuring

  2013cites this paper
• Organic Synthesis Catalyzed by Supported Gold Nanoparticles

  2013cites this paper
• Catalytic properties of supported gold nanoparticles in organic syntheses

  2013cites this paper
• How metallic is gold in the direct epoxidation of propene: an FTIR study

  2013cites this paper
• CO Oxidation at the Interface of Au Nanoclusters and the Stepped-CeO2(111) Surface by the Mars-van Krevelen Mechanism.

  2013cites this paper
• Effect of MgO(100) support on structure and properties of Pd and Pt nanoparticles with 49-155 atoms.

  2013cites this paper
• On the synergetic catalytic effect in heterogeneous nanocomposite catalysts.

  2013cites this paper
• Mechanistic insights into the partial oxidation of acetic acid by O2 at the dual perimeter sites of a Au/TiO2 catalyst.

  2013cites this paper
• First Combined Electron Paramagnetic Resonance and FT-IR Spectroscopic Evidence for Reversible O2 Adsorption on In2O3-x Nanoparticles

  2013cites this paper
• Edge-induced active sites enhance the reactivity of large aluminum cluster anions with alcohols.

  2012cites this paper
• Inhibition at perimeter sites of Au/TiO2 oxidation catalyst by reactant oxygen.

  2012cites this paper