Study of the Synthesis, Crystallization, and Morphology of Poly(ethylene glycol)−Poly(ε-caprolactone) Diblock Copolymers

No abstract is available for this paper.

• Publication year

  2004

• Venue

  Biomacromolecules

• Publication date

  2004-08-18

• Fields of study

  Materials Science

• Identifiers
  DOI 10.1021/BM049720E
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• No references are available for this paper.

• The effect of cryoprotectant and storage conditions on the aggregation of poly(ethylene glycol)-poly(α-benzyl carboxylate-ε-caprolactone) nanoparticles.

  2026cites this paper
• Double emulsion-based encapsulation of iron in amphiphilic block copolymer nanocarriers for controlled release.

  2025cites this paper
• Surface Morphology and Degradation of Poly[(R)-3-Hydroxybutyrate]-block-Poly(ε-Caprolactone) and Poly[(R)-3-Hydroxybutyrate]-block-Poly(l-Lactide) Biodegradable Diblock Copolymers

  2025cites this paper
• Synthetic Biopolymers–Assisted Polycaprolactone Blends for Pharmacology: A Comprehensive Review With Recent Insights

  2025cites this paper
• Synthesis of PEGylated amphiphilic block copolymers with pendant linoleic moieties by combining ring‐opening polymerization and click chemistry

  2024cites this paper
• Accelerated Phase Transition of Polybutene-1 in Polybutene-1/Polypropylene Blends Induced by Poly((butene-1)-block-propylene) Copolymers

  2024cites this paper
• Synthesis of Polyesters Containing Long Aliphatic Methylene Units by ADMET Polymerization and Synthesis of ABA-Triblock Copolymers by One-Pot End Modification and Subsequent Living Ring-Opening Polymerization

  2024cites this paper
• Synthesis of poly(ethylene glycol)-co-poly(caprolactone) di- and triblock copolymers and effect of architecture, dispersity and end-functionalisation on their aqueous self-assembly

  2023cites this paper
• Stress-Free Two-Way Shape Memory Effect of Poly(ethylene glycol)/Poly(ε-caprolactone) Semicrystalline Networks

  2022cites this paper
• Lactobionic Acid-Navigated Gold Nanorods With Light-Triggered “on-Demand” Drug Release for Synergistic Photothermal-Chemotherapy

  2022cites this paper
• Microstructure—Thermal Property Relationships of Poly (Ethylene Glycol-b-Caprolactone) Copolymers and Their Micelles

  2022influential citation
• Physical structure contributions in pH degradation of PEO-b-PCL films

  2021cites this paper
• Amphiphilic copolymers modified with oleic acid and cholesterol by combining ring opening polymerization and click chemistry with improved amphotericin B loading capacity

  2021cites this paper
• Crystallization and Morphology of Triple Crystalline Polyethylene-b-poly(ethylene oxide)-b-poly(ε-caprolactone) PE-b-PEO-b-PCL Triblock Terpolymers

  2021cites this paper
• Phase transitions of poly(oligo(ethylene glycol) methyl ether methacrylate)-water systems

  2021cites this paper
• Development of a semi-crystalline hybrid polyurethane nanocomposites for hMSCs cell culture and evaluation of body- temperature shape memory performance and isothermal crystallization kinetics

  2021influential citation
• Polyolefins based crystalline block copolymers: Ordered nanostructures from control of crystallization

  2020cites this paper
• pH-responsive polymer micelles for methotrexate delivery at tumor microenvironments

  2020cites this paper
• Nanoformulation-by-design: an experimental and molecular dynamics study for polymer coated drug nanoparticles

  2020cites this paper
• Solubility considerations in relative block crystallization and morphology of PEO‐ b ‐PCL films

  2020cites this paper
• Epitaxial orientation and localized microphase separation prior to formation of nanohybrid shish-kebabs induced by one-dimensional nanofiller in miscible diblock copolymers with selective interaction

  2019cites this paper
• Competition Between Interfacial Interaction and Microphase Separation in Crystallization of Filled Block Copolymers

  2019cites this paper
• Confined crystallization morphology of poly(ϵ‐caprolactone) block within poly(ϵ‐caprolactone)–poly(l‐lactide) copolymers

  2019cites this paper
• Physiochemical properties and paclitaxel release behaviors of dual-stimuli responsive copolymer-magnetite superparamagnetic nanocomposites

  2019cites this paper
• Reconstruction of calvarial bone defects using poly(amino acid)/hydroxyapatite/calcium sulfate composite

  2019cites this paper
• Hierarchical structure microspheres of PCL block copolymers via electrospraying as coatings for fabric with mechanical durability and self‐cleaning ability

  2019cites this paper
• Controlled synthesis of polymethylene-b-poly(ethylene glycol) as well as its crystallization and self-assembly behavior

  2019cites this paper
• Crystallisation and spherulite morphology of polylactide stereocomplex

  2018cites this paper
• Y-shaped copolymers of poly(ethylene glycol)-poly(ε-caprolactone) with ketal bond as the branchpoint for drug delivery.

  2018cites this paper
• Crystallization Behavior of Crystalline–Amorphous and Crystalline–Crystalline Block Copolymers Containing Poly(l-lactide)

  2018cites this paper
• Influence of soft block crystallization on microstructural variation of double crystalline poly(ether‐ mb ‐amide) multiblock copolymers

  2018cites this paper
• Crystallization and Morphology of Block Copolymers and Terpolymers With More Than One Crystallizable Block

  2018cites this paper
• Thermo thickening behavior of MPEG-b-PCL grafted Poly(acrylic acid): A molecular insight

  2018cites this paper
• Crystalline and Spherulitic Morphology of Polymers Crystallized in Confined Systems

  2017cites this paper
• A comprehensive review on polymer single crystals—From fundamental concepts to applications

  2017cites this paper
• Poly(ε-caprolactone) with pendant natural peptides: an old polymeric biomaterial with new properties

  2017cites this paper
• Complex Self-Assembly Behavior of Bis-hydrophilic PEO-b-PCL-b-PMOXA Triblock Copolymers in Aqueous Solution

  2017cites this paper
• Poly(ε-caprolactone) (PCL) hybrid sheets containing polymeric micelles: Effects of inner structures on the material properties of the sheets.

  2017cites this paper
• Nanostructured Morphologies by Self-Assembly of Diblock Copolymers: A Review

  2017cites this paper
• pH responsive micelles based on copolymers mPEG-PCL-PDEA: The relationship between composition and properties.

  2017cites this paper
• Multi-Crystalline polymer systems: Biodegradable triblock terpolymers and nanostructured blends. Morphology, Crystallization and properties

  2017influential citation
• Oriented Microstructures of Crystalline–Crystalline Block Copolymers Induced by Epitaxy and Competitive and Confined Crystallization

  2016cites this paper
• Well defined nanoparticles through controlled non-equilibrium micellization of block copolymers

  2016cites this paper
• Influence of a low content of PEO segment on the thermal, surface and morphological properties of triblock and diblock PCL copolymers

  2016cites this paper
• Molecular simulations of confined crystallization in the microdomains of diblock copolymers

  2016cites this paper
• Sequential crystallization and morphology of triple crystalline biodegradable PEO-b-PCL-b-PLLA triblock terpolymers

  2016cites this paper
• Synthesis and characterization of novel barbwire-like graft polymers poly(ethylene oxide)-g-poly(ε-caprolactone)4 by the ‘grafting from’ strategy

  2015cites this paper
• An enzyme-catalysed access to amphiphilic triblock copolymer of PCL-b-PEG-b-PCL: synthesis, characterization and self-assembly properties

  2015cites this paper
• Unusual crystallization and melting behavior induced by microphase separation in MPEG-b-PLLA diblock copolymer

  2015cites this paper
• Magnesium and Calcium Complexes in Homogeneous Catalysis

  2015cites this paper
• Cold Crystallization of PDMS and PLLA in Poly(l-lactide-b-dimethylsiloxane-b-l-lactide) Triblock Copolymer and Their Effect on Nanostructure Morphology

  2015cites this paper
• Recent Development of Chitosan Nanocomposites with Multiple Potential Uses

  2015cites this paper
• , and Margaritis Kostoglou Novel Approaches in Designing Natural / Synthetic Materials for Environmental Applications

  2015cites this paper
• Nano-ordered surface morphologies by stereocomplexation of the enantiomeric polylactide chains: specific interactions of surface-immobilized poly(D-lactide) and poly(ethylene glycol)-poly(L-lactide) block copolymers.

  2014cites this paper
• Towards the development of polycaprolactone based amphiphilic block copolymers: molecular design, self-assembly and biomedical applications.

  2014cites this paper
• Luminescent nanoparticles with lanthanide-containing poly(ethylene glycol)-Poly(ε-caprolactone) block copolymers.

  2014cites this paper
• Synthesis and Characterization of Star-Shaped Block Copolymer sPCL-b-PEG-GA

  2014cites this paper
• Crystallization Behavior of Copolyesterurethanes Containing Different Weight Contents of Crystallizable Poly(ε‐caprolactone) Segments

  2014cites this paper
• Double-crystalline PLLA-b-PVDF-b-PLLA triblock copolymers: preparation and crystallization

  2014cites this paper
• Engineering Nanoparticles for Pharmaceutical Applications: Formulation and Freeze-Drying Techniques

  2014cites this paper
• Synthesis and pH‐responsive assembly of methoxy poly(ethylene glycol)‐b‐poly(ε‐caprolactone) with pendant carboxyl groups

  2014cites this paper
• Synthesis and characterization of crystalline graft polymer poly(ethylene oxide)‐g‐poly(ɛ‐caprolactone)2 with modulated grafting sites

  2014cites this paper
• Solvent micro-evaporation and concentration gradient synergistically induced crystallization of poly(L-lactide) and ring banded supra-structures with radial periodic variation of thickness

  2014cites this paper
• Synthesis and characterization of resorcinarene-centered amphiphilic A8B4 miktoarm star copolymers based on poly(ε-caprolactone) and poly(ethylene glycol) by combination of CROP and “click” chemistry

  2013cites this paper
• Alkaline-Earth Metal Complexes in Homogeneous Polymerization Catalysis

  2013cites this paper
• Confined lamella formation in crystalline-crystalline poly(ethylene oxide)-b-poly(ɛ-caprolactone) diblock copolymers

  2013cites this paper
• Bioinspired assembly of functional block-copolymer nanotemplates.

  2013cites this paper
• Crystallization and melting of poly(glycerol adipate)‐based graft copolymers with single and double crystallizable side chains

  2013cites this paper
• Evolution of concentric spherulites in crystalline-crystalline poly(3-hydroxybutyrate-co-3-hydroxyvalerate)-b-poly(ethylene glycol) copolymers

  2013cites this paper
• Shape memory properties of polycaprolactone-based polyurethanes prepared by reactive extrusion

  2013cites this paper
• Crystallization behavior and morphology of double crystalline poly(trimethylene terephthalate)/poly(ethylene oxide terephthalate) copolymers

  2013cites this paper
• Gold nanorod-cored biodegradable micelles as a robust and remotely controllable doxorubicin release system for potent inhibition of drug-sensitive and -resistant cancer cells.

  2013cites this paper
• Poly(ethylene glycol)-poly(tetrahydrofuran)-poly(ethylene glycol) triblock copolymer: Synthesis, crystallization behavior and novel morphology

  2013influential citation
• In Situ synthesis of multiblock copolymers of poly(ϵ‐caprolactone) with different poly(ether diols) based polyurethane by reactive extrusion

  2012cites this paper
• From miscible to partially miscible biodegradable double crystalline poly(ethylene succinate)-b-poly(butylene succinate) multiblock copolymers

  2012cites this paper
• Poly(ethyleneglycol)-b-poly(ε-caprolactone-co-γ-hydroxyl-ε- caprolactone) bearing pendant hydroxyl groups as nanocarriers for doxorubicin delivery.

  2012cites this paper
• Peptide‐poly(ε‐caprolactone) biohybrids by grafting‐from ring‐opening polymerization: Synthesis, aggregation, and crystalline properties

  2012cites this paper
• Effects of block copolymer properties on nanocarrier protection from in vivo clearance.

  2012cites this paper
• Hierarchical mesostructures of biodegradable triblock copolymers via evaporation-induced self-assembly directed by alkali metal ions

  2012cites this paper
• Crystallization behavior and morphology of double crystalline poly(butylene succinate)-poly(ethylene glycol) multiblock copolymers

  2012cites this paper
• A new approach for modular polymer–polymer conjugations via Heck coupling

  2012cites this paper
• Soft nanoconfinement effects on the crystallization behavior of asymmetric poly(ethylene oxide)‐block‐poly(ε‐ caprolactone) diblock copolymers

  2012cites this paper
• Tensegrity-inspired nanocomposite structures

  2012cites this paper
• Solid-State Structure and Crystallization in Double-Crystalline Diblock Copolymers of Linear Polyethylene and Hydrogenated Polynorbornene

  2011cites this paper
• Amphiphilic Block Co-polyesters Bearing Pendant Cyclic Ketal Groups as Nanocarriers for Controlled Release of Camptothecin

  2011cites this paper
• Biodegradable Blend Nanoparticles of Amphiphilic Diblock Copolymers Prepared by Nano-Precipitation Method

  2011cites this paper
• The crystallization behavior of poly(ethylene glycol)-poly(ε-caprolactone) diblock copolymers with asymmetric block compositions

  2011cites this paper
• Brain delivery and cellular internalization mechanisms for transferrin conjugated biodegradable polymersomes.

  2011cites this paper
• Synthesis, characterization, and properties of poly(ester‐phosphoester)s by lanthanum triphenolate‐catalyzed ring‐opening copolymerization

  2011cites this paper
• Single crystals morphology of biodegradable double crystalline PLLA-b-PCL diblock copolymers

  2011cites this paper
• Amphiphilic Triblock Copolymer Bioconjugates with Biotin Groups at the Junction Points: Synthesis, Self-Assembly, and Bioactivity

  2011cites this paper
• Self-assembly of an A–B diblock copolymer blended with a C homopolymer and a C–D diblock copolymer through hydrogen bonding interaction

  2010cites this paper
• Influence of chemical structure on enzymatic degradation of single crystals of PCL-b-PEO amphiphilic block copolymer

  2010cites this paper
• Preparation of solvent-free gold nanofluids with facile self-assembly technique.

  2010cites this paper
• Chemoenzymatic Synthesis of a Pentablock Copolymer and Its Self-Assembly Behavior Study: Chemoenzymatic Synthesis of a Pentablock Copolymer and Its Self-Assembly Behavior Study

  2010cites this paper
• Synthesis and characterization of PEG–PCL–PEG triblock copolymers as carriers of doxorubicin for the treatment of breast cancer

  2010cites this paper
• Chemoenzymatic synthesis amphiphilic H-shaped copolymer and its self-assembly behavior

  2009cites this paper
• Crystallization and morphology of biodegradable or biostable single and double crystalline block copolymers

  2009cites this paper
• Functionalized star-shaped polymers having PEO and/or polyglycidyl arms and their properties

  2009cites this paper
• Synthesis and characterization of fluorescein isothiocyanate (FITC)-labeled PEO–PCL–PEO triblock copolymers for topical delivery

  2009cites this paper