Thermochemical sulphate reduction (TSR): experimental determination of reaction kinetics and implications of the observed reaction rates for petroleum reservoirs

No abstract is available for this paper.

• Publication year

  2004

• Venue

  Organic Geochemistry

• Publication date

  2004-04-01

• Fields of study

  Geology, Chemistry, Engineering, Environmental Science

• Identifiers
  DOI 10.1016/J.ORGGEOCHEM.2004.01.005
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Assessment of anhydrite dissolution as the rate-limiting step during thermochemical sulfate reduction

  2001cited by this paper
• Bacterial and thermochemical sulfate reduction in diagenetic settings — old and new insights

  2001cited by this paper
• Products and Depth Limits of Microbial Activity in Petroliferous Subsurface Settings

  2000cited by this paper
• The Influence of Rock Fabric and Mineralogy on Thermochemical Sulfate Reduction: Khuff Formation, Abu Dhabi

  2000cited by this paper
• Advances in Organic Geochemistry.

  1999cited by this paper
• Experimental Determination of the Kinetics and Mechanisms of Thermochemical Sulphate Reduction (TSR) Reactions at Reservoir Conditions of Pressure and Temperature

  1998cited by this paper
• The Role of Burial Diagenesis in Hydrocarbon Destruction and H2S Accumulation, Upper Jurassic Smackover Formation, Black Creek Field, Mississippi

  1997cited by this paper
• Gas Souring by Thermochemical Sulfate Reduction at 140¡C: Reply

  1997cited by this paper
• H2S-producing reactions in deep carbonate gas reservoirs: Khuff Formation, Abu Dhabi

  1996cited by this paper
• Devonian Nisku Sour Gas Play, Canada: A Unique Natural Laboratory for Study of Thermochemical Sulfate Reduction

  1995cited by this paper
• Products and distinguishing criteria of bacterial and thermochemical sulfate reduction

  1995cited by this paper
• Geochemical transformations of sedimentary sulfur.

  1995cited by this paper
• ABSTRACT: Thermochemical Sulfate Reduction as a Source of Sedimentary H2S

  1995cited by this paper
• Thermal decomposition of acetate: III. Catalysis by mineral surfaces

  1994cited by this paper
• Appraisal of the use of experimental and analogue studies in the assessment of the role of organic acid anions in diagenesis

  1994cited by this paper
• Hydrosulphide complexes of gold (I) at high pressures and temperatures: equilibrium and kinetic problems

  1994cited by this paper
• Thermochemical sulfate reduction a review

  1994cited by this paper
• Applied Petroleum Geochemistry

  1993cited by this paper
• Thermochemical reduction and sulfur isotopic behavior of sulfate by acetic acid in the presence of native sulfur

  1993cited by this paper
• Thermochemical sulfate reduction at steam flooding processes―a chemical approach

  1993cited by this paper
• Regional trends in water chemistry, Smackover Formation, southwest Arkansas: Geochemical and physical controls

  1992cited by this paper
• Bacterial Sulfate Reduction Above 100�C in Deep-Sea Hydrothermal Vent Sediments

  1992cited by this paper
• Feldspar dissolution in the presence of organic acid anions under diagenetic conditions: an experimental study

  1992cited by this paper
• Origin and evolution of formation waters, Alberta Basin, Western Canada sedimentary Basin. I. Chemistry

  1990cited by this paper
• The role of organic acid in the abiogenic reduction of sulfate and the sulfur isotope effect

  1990cited by this paper
• Carbon Isotope Fractionation during Oxidation of Light Hydrocarbon Gases: Relevance to Thermochemical Sulfate Reduction in Gas Reservoirs

  1990cited by this paper
• Carbon isotope effect during abiogenic oxidation of methane

  1989cited by this paper
• Geochemical relationships of petroleum in Mesozoic reservoirs to carbonate source rocks of Jurassic Smackover Formation, southwestern Alabama

  1989cited by this paper
• Solubility of gold in aqueous sulfide solutions from 150 to 350°C

  1989cited by this paper
• Chemical and isotopic evidence of thermochemical sulphate reduction by light hydrocarbon gases in deep carbonate reservoirs

  1988cited by this paper
• Late burial diagenesis driven by thermal degradation of hydrocarbons and thermochemical sulfate reduction

  1988cited by this paper
• Geochemistry of metal-rich brines from central Mississippi Salt Dome basin, U.S.A.

  1987cited by this paper
• Hydrothermal experimental techniques

  1987cited by this paper
• Thermal decarboxylation of acetate. Part I. The kinetics and mechanism of reaction in aqueous solution

  1986cited by this paper
• Kinetics of reactions between aqueous sulfates and sulfides in hydrothermal systems

  1982cited by this paper
• The Origin and Evolution of Saline Formation Water, Lower Cretaceous Carbonates, South-Central Texas, U.S.A.

  1981cited by this paper
• Chemical reduction and sulfur-isotope effects of sulfate by organic matter under hydrothermal conditions

  1980cited by this paper
• A new reaction cell for hydrothermal solution equipment

  1979cited by this paper
• Aliphatic Acid Anions in Oil-Field Waters--Implications for Origin of Natural Gas

  1978cited by this paper
• Geologic and geochemical controls on the distribution of hydrogen sulfide in natural gas

  1975cited by this paper
• Changes in Sulfur Content and Isotopic Ratios of Sulfur during Petroleum Maturation--Study of Big Horn Basin Paleozoic Oils

  1974cited by this paper
• Sulphur isotope equilibrium during sulphur hydrolysis at high temperatures

  1973cited by this paper
• Isotopic behaviour of sulphate oxygen in the bacterial reduction of sulphate

  1973cited by this paper
• The solubility of anhydrite (CaSO4) in NaCl-H2O from 100 to 450°C and 1 to 1000 bars

  1969cited by this paper
• Oxygen isotope behavior in the sulfate-water system

  1968cited by this paper
• Oxidation of Organic Compounds with Aqueous Sulfate

  1960cited by this paper

• Interfacial properties of produced water – a review

  2025cites this paper
• Kinetics of thermochemical sulfate reduction based on pyrolysis gold-tube experiments on lacustrine oil: Implications for H2S prediction in Brazilian pre-salt reservoirs

  2025cites this paper
• Unraveling Hydrogen Induced Geochemical Reaction Mechanisms through Coupled Geochemical Modeling and Machine Learning

  2025cites this paper
• Molecular and carbon isotopic geochemistry of oils with different fluorescence color from the Upper Jurassic Qigu formation and oil accumulation process in Yongjin area, Junggar Basin in China.

  2024cites this paper
• Predicting thermochemical sulfate reduction reaction process and H2S generation in carbonate reservoirs using comprehensive kinetics modeling

  2024cites this paper
• Reaction pathway, mechanism and kinetics of thermochemical sulfate reduction: insights from in situ Raman spectroscopic observations at elevated temperatures and pressures

  2024cites this paper
• Microbial influence in Spanish bentonite slurry microcosms: unveiling a-year long geochemical evolution and early-stage copper corrosion related to nuclear waste repositories.

  2024cites this paper
• Differential fault-fluid alterations and reservoir properties in ultra-deep carbonates in the Tarim Basin, NW China

  2024cites this paper
• A quantitative analysis on thermochemical sulfate reduction products of two model compounds: Implications for reaction mechanism and alteration process of hydrocarbons

  2024cites this paper
• Integrated stable S isotope, microbial and hydrochemical analysis of hydrogen sulphide origin in groundwater from the Legnica-Głogów copper District, Poland

  2024cites this paper
• Mechanism of using magnetic susceptibility to predict hydrogen sulfide abnormal zone in coalfield

  2024cites this paper
• The effect of Ni- and Mo-based materials on thermochemical sulfate reduction by glycerol under hydrothermal process conditions

  2024cites this paper
• Effects of Al3+ on thermochemical sulphate reduction (TSR) at 250 °C to 350 °C under vapour-saturated pressures: A Raman spectroscopic investigation

  2024cites this paper
• The initiation stage of thermochemical sulfate reduction: an isotopic and computational study

  2023cites this paper
• Identification of sulfur-containing isoprenoids with non-adamantane cage structures in crude oil

  2023cites this paper
• URANIUM AND MOLYBDENUM ISOTOPE EVIDENCE FOR GLOBALLY EXTENSIVE MARINE EUXINIA ON CONTINENTAL MARGINS AND IN EPICONTINENTAL SEAS DURING THE DEVONIAN-CARBONIFEROUS HANGENBERG CRISIS

  2023cites this paper
• Origin of Breccia Dolomites in the Middle Devonian Guanwushan Formation, Nw Sichuan Basin, China: Implications for Ultra-Deep Carbonate Reservoirs

  2023cites this paper
• Hydrothermal fluid alteration of the Ordovician epigenetic karstification reservoir in the Tahe Oilfield, Tarim Basin, NW China.

  2023cites this paper
• Hydrothermal reduction of sulfates by ferrous carbonate: Implications for the origin of reduced sulfur in carbonate-hosted Pb-Zn deposits associated spatially with basalts

  2023cites this paper
• Fluid Flow, Alteration, and Timing of Cu-Ag Mineralization at the White Pine Sediment-Hosted Copper Deposit, Michigan, USA

  2023cites this paper
• Study on the Generation Mechanism of Hydrogen Sulfide by Thermochemical Sulfate Reduction in Heavy Oil Hot Water Flooding at Low Temperature

  2023cites this paper
• Impact of compacted bentonite microbial community on the clay mineralogy and copper canister corrosion: a multidisciplinary approach in view of a safe Deep Geological Repository of nuclear wastes.

  2023cites this paper
• Crude oil cracking in deep reservoirs: A review of the controlling factors and estimation methods

  2023cites this paper
• Thermochemical sulfate reduction in sedimentary basins and beyond: A review

  2022cites this paper
• Review of natural origin, distribution, and long-term conservation of CO2 in sedimentary basins of China

  2022cites this paper
• Constraining the redox landscape of Mesoproterozoic mat grounds: A possible oxygen oasis in the ‘Boring Billion’ seafloor

  2022cites this paper
• Causes of variation in the concentration and distribution of H2S in carbonate reservoirs of the Feixianguan Formation, Lower Triassic in the eastern Sichuan Basin

  2022cites this paper
• The effect of thermochemical sulfate reduction of n-pentane and condensate on the chemical and isotopic compositions of gases: Implications for the organic reactant and reaction extent

  2022cites this paper
• Structural and textural control of high-pressure hydrogen adsorption on expandable and non-expandable clay minerals in geologic conditions

  2022cites this paper
• Genetic Type and Source Analysis of Natural Gas in the Leikoupo Formation of the Sichuan Basin in China

  2022cites this paper
• Geochemical characterization of natural gases in the pre-salt section of the Santos Basin (Brazil) focused on hydrocarbons and volatile organic sulfur compounds

  2022cites this paper
• Geochemical characteristics comparison of primary gas with producing gas and its significance for depleted ethane carbon isotopic values in the Southeastern gas field of the Ordos Basin, China

  2021cites this paper
• Formation of Zn and Pb sulfides in a redox-sensitive modern system due to high atmospheric fallout

  2021cites this paper
• Nature of the Lower–Middle Ordovician reservoir bitumen in the Shunnan area, Tarim Basin, northwestern China

  2021cites this paper
• Mineralogical and geochemical research on Pengyang deposit:A peculiar eolian sandstone-hosted uranium deposit in the southwest of Ordos Basin

  2021cites this paper
• Origin and Geochemical Implications of Hopanoids in Saline Lacustrine Crude Oils from Huanghekou East Sag and Laizhouwan Northeastern Sag, Bohai Bay Basin

  2021cites this paper
• A critical review of molybdenum sequestration mechanisms under euxinic conditions: Implications for the precision of molybdenum paleoredox proxies

  2021cites this paper
• Anhydrite replacement reaction in nodular pyrite breccia and its geochemical controls on the δ34S signature of pyrite in the TAG hydrothermal mound, 26° N Mid Atlantic Ridge

  2021cites this paper
• Diamondoids and thiadiamondoids generated from hydrothermal pyrolysis of crude oil and TSR experiments

  2021cites this paper
• Ferrocene addition for suppression of hydrogen sulfide formation during thermal recovery of oil sand bitumen

  2021cites this paper
• TSR-derived hydrogen sulfide and organic sulfur compounds: New insights from chemical thermodynamic investigation

  2021cites this paper
• Simulation Experiment of TSR Promotes Cracking of Coal Generation H2S

  2021cites this paper
• A significant seawater sulfate reservoir at 2.0 Ga determined from multiple sulfur isotope analyses of the Paleoproterozoic Degrussa Cu-Au volcanogenic massive sulfide deposit, Western Australia

  2021cites this paper
• Species of Sulfur in Sour Gas Reservoir: Insights from In Situ Raman Spectroscopy of S–H2S–CH4–H2O System and Its Subsystems from 20 to 250°C

  2021cites this paper
• The role of hydrothermal sulfate reduction in the sulfur cycles within Europa: Laboratory experiments on sulfate reduction at 100 MPa

  2021cites this paper
• Hydrothermal experiments involving methane and sulfate: Insights into carbon isotope fractionation of methane during thermochemical sulfate reduction

  2020cites this paper
• Hydrocarbon generation from lacustrine shales with retained oil during thermal maturation

  2020cites this paper
• Fractionation of carbon and hydrogen isotopes of TSR-altered gas products under closed system pyrolysis

  2020cites this paper
• Elemental proxies for paleosalinity analysis of ancient shales and mudrocks

  2020cites this paper
• Effects of Mississippi valley-type minerogenetic metal sulfates on thermochemical sulfate reduction, studied by hydrous pyrolysis

  2020cites this paper
• Occurrence and Origin of H 2 S from Volcanic Reservoirs in Niudong Area of the Santanghu Basin , NW China

  2019cites this paper
• HYDROGEN SULFIDE ACCUMULATION FACTORS IN COAL MINE OF SOUTHEASTERN MARGIN OF JUNGGAR BASIN IN CHINA

  2019cites this paper
• First evidence of the trisulfur radical ion S 3-and other sulfur 1 polymers in natural fluid inclusions 2

  2019cites this paper
• Bacterial presence and activity in compacted bentonites

  2019cites this paper
• Pyrite Morphology as an Indicator of Paleoredox Conditions and Shale Gas Content of the Longmaxi and Wufeng Shales in the Middle Yangtze Area, South China

  2019cites this paper
• Thermal simulation experiment and research on the system of coal/coal and water/coal and water and MgSO4/coal and water and CaSO4

  2019cites this paper
• Origin of Short-Chain Organic Acids in Serpentinite Mud Volcanoes of the Mariana Convergent Margin

  2019cites this paper
• DISTRIBUTION CHARACTERISTICS AND CONTROL FACTORS OF HYDROGEN SULFIDE IN XISHAN COAL MINE OF SOUTHERN MARGIN OF JUNGGAR BASIN IN CHINA

  2019cites this paper
• Isolation and characterization of sulfur compounds in a lacustrine crude oil

  2019cites this paper
• Occurrence and Origin of H2S from Volcanic Reservoirs in Niudong Area of the Santanghu Basin, NW China

  2019cites this paper
• Study of thermochemical sulfate reduction of different organic matter: Insight from systematic TSR simulation experiments

  2019cites this paper
• Constraining the Fluid History of a CO2‐H2S Reservoir: Insights From Stable Isotopes, REE, and Fluid Inclusion Microthermometry

  2019cites this paper
• Experimental and theoretical studies on kinetics for thermochemical sulfate reduction of oil, C2–5 and methane

  2019cites this paper
• Underground hydrogen storage: application of geochemical modelling in a case study in the Molasse Basin, Upper Austria

  2019cites this paper
• Super-deep, TSR-controlled Phanerozoic MVT type Zn-Pb deposits hosted by Zechstein-2 gas reservoir carbonate (Ca2), Lower Saxony Basin, Germany

  2019cites this paper
• The paleolimnologist's guide to compound-specific stable isotope analysis – An introduction to principles and applications of CSIA for Quaternary lake sediments

  2019cites this paper
• Kinetics of elemental sulfur reduction by petroleum hydrocarbons and the implications for hydrocarbon thermal chemical alteration

  2019cites this paper
• Hydrous heating experiments at 130 °C yield insights into the occurrence of hydrogen sulfide and light alkanes in natural gas reservoirs

  2019cites this paper
• The Chemical Remagnetization of Ediacaran Dolomite in the Taishan Paleo‐Reservoir, South China

  2018cites this paper
• Comamonadaceae OTU as a Remnant of an Ancient Microbial Community in Sulfidic Waters

  2018cites this paper
• Thermal alteration of biomarkers in the presence of elemental sulfur and sulfur-bearing minerals during hydrous and anhydrous pyrolysis

  2018cites this paper
• Influence cinétique de H2S sur la pyrolyse des hydrocarbures aromatiques aux pressions de réservoirs géologiques (700 bar) : étude expérimentale du système n-butylbenzène – H2S comparée au n-butylbenzène pur

  2018cites this paper
• Modeling High‐Temperature, High‐Pressure, High‐Salinity and Highly Reducing Geochemical Systems in Oil and Gas Production

  2018cites this paper
• Geochemical characteristics of natural gases from different petroleum systems in the Longgang gas field, Sichuan Basin, China

  2018influential citation
• Geochemical characteristics of water-dissolved gases and implications on gas origin of Sinian to Cambrian reservoirs of Anyue gas field in Sichuan Basin, China

  2018cites this paper
• In situ geochemical characterization of pyrite crystals in burial dolomites of St. George Group carbonates

  2018cites this paper
• The role of hydrocarbons in ore formation at the Pillara Mississippi Valley-type Zn-Pb deposit, Canning Basin, Western Australia

  2018cites this paper
• Petroleum reservoir quality prediction: overview and contrasting approaches from sandstone and carbonate communities

  2018cites this paper
• Toward an integrated genetic model for vent-distal SEDEX deposits

  2018cites this paper
• Analysis of mechanical and permeability properties of mudstone interlayers around a strategic petroleum reserve cavern in bedded rock salt

  2018cites this paper
• Numerical and Experimental Characterization of Dissolution and Precipitation Processes in Deep Geothermal Reservoirs

  2018cites this paper
• Sulfur isotope of pyrite response to redox chemistry in organic matter-enriched shales and implications for components of shale gas

  2018cites this paper
• Experimental investigation on thermochemical sulfate reduction in the presence of 1-pentanethiol at 200 and 250 °C: Implications for in situ TSR processes occurring in some MVT deposits

  2017cites this paper
• Novel Techniques in Organic Geochemistry applied to Australian Resources

  2017cites this paper
• Mobility and reactivity of sulphide in bentonite clays – Implications for engineered bentonite barriers in geological repositories for radioactive wastes

  2017cites this paper
• Microbial sulphide production during consumption of H 2 and organic compounds released from stationary borehole equipment

  2017cites this paper
• Origin and Distribution of Grain Dolostone Reservoirs in the Cambrian Longwangmiao Formation, Sichuan Basin, China

  2017cites this paper
• First evidence of the trisulfur radical ion S 3 - and other sulfur polymers in natural fluid inclusions

  2017cites this paper
• Pore-scale simulation of transport properties of carbonate rocks using FIB-SEM 3D microstructure: Implications for field scale solute transport simulations

  2017cites this paper
• Corrosion Problems and Solutions at Oil Refinery and Petrochemical Units

  2017cites this paper
• Rôle de la spéciation du soufre dans les fluides géologiques en contexte orogénique : application aux processus d’oxydoréduction affectant la Nappe des Gypses (Alpes françaises)

  2017influential citation
• Hydrolysis of Pyrite: a Possible Pathway for Generation of High Concentrations of H2S Gas in Deep-buried Reservoirs?

  2017cites this paper
• In situ optical and Raman spectroscopic observations of the effects of pressure and fluid composition on liquid–liquid phase separation in aqueous cadmium sulfate solutions (≤400 °C, 50 MPa) with geological and geochemical implications

  2017cites this paper
• Release of H2 and organic compounds from metallic and polymeric materials used to construct stationary borehole equipment

  2016cites this paper
• Hydrogen sul fi de formation , fate , and behavior in anhydrite-sealed carbonate gas reservoirs : A three-dimensional reactive mass transport modeling approach

  2016cites this paper
• New insights into the formation mechanism of high hydrogen sulfide–bearing gas condensates: Case study of Lower Ordovician dolomite reservoirs in the Tazhong uplift, Tarim Basin

  2016cites this paper
• Hydrogen sulfide formation, fate, and behavior in anhydrite-sealed carbonate gas reservoirs: A three-dimensional reactive mass transport modeling approach

  2016cites this paper
• Origin and distribution of hydrogen sulfide in the Yuanba gas field, Sichuan Basin, Southwest China

  2016cites this paper
• Sources of environmental sulfur in the groundwater system, southern New Zealand

  2016cites this paper
• Scale and distribution of marine carbonate burial dissolution pores

  2016cites this paper