The reactivity of allylic organometallic compounds of lithium, sodium, magnesium, zinc, cadmium and aluminium: Recent advances

No abstract is available for this paper.

• Publication year

  1974

• Venue

  Journal of Organometallic Chemistry

• Publication date

  1974-04-02

• Fields of study

  Chemistry

• Identifiers
  DOI 10.1016/S0022-328X(00)92983-8
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• Addition and metalations reactions of small ring olefinic hydrocarbons with butyllithium.

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• Generation of allyllithium reagents by lithium-tetrahydrofuran reduction of allylic mesitoates. New procedure for selective allylic cross coupling and allylcarbinol synthesis

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• Umlagerung cyclischer Allylcarbinyl‐Anionen: Ringverengung auf Grund von Stabilitätsunterschieden zwischen primären und sekundären Grignard‐Verbindungen

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• Neopentylallyllithium III. Effects of ether solvents on PMR and UV spectra

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• Bis(neopentylallyl)magnesium

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• Neopentylallithium : IV. Reactions in ether solvents

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• Addition von organomagnesium-verbindungen an nicht aktivierte CC-doppelbindungen. II

  1973cited by this paper
• Étude de la synthése, la structure et la réactivité d'un nouveau réactif organométallique résultant d'une réaction de dimérisation du bromure d'allyl-zinc

  1973cited by this paper
• Synthesis of (+-)-dihydro-.beta.-santalol

  1972cited by this paper
• Transposition des ethers allyliques sous l'action de l'allyl-lithium

  1972cited by this paper
• Metalation of limonene. Novel method for the synthesis of bisabolane sesquiterpenes

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• Photochemistry of an acyclic bis .beta.,.gamma.-unsaturated ketone

  1972cited by this paper
• 3-Vinylpentadienyl anions. Rearrangement of 3-vinyllheptadienyl anion to 2-ethylcycloheptadienyl anion

  1972cited by this paper
• 3-Neopentylallyllithium I. The 1,4-addition product of tert-butyllithium and 1,3-butadiene☆

  1972cited by this paper
• Stéréochimie des réactions d'organolithiens et organosodiques au niveau de l'atome de silicium d'un cyclosilane asymétrique

  1972cited by this paper
• 1,4-Addition of allylmagnesium chloride to 2-methylquinoline via 1,2-addition and subsequent rearrangement

  1972cited by this paper
• 3-Neopentylallyllithium II. Reactions in hydrocarbon media

  1972cited by this paper
• Nuclear magnetic resonance and 203Hg exchange studies of allylmercury systems: A comment on allylmercuric perchlorate

  1972cited by this paper
• Ag+-catalyzed rearrangements. XIII. Mechanistic aspects of the silver(I)-promoted rearrangements of tricyclo[4.1.0.02,7]heptane derivatives. Deuterium isotope effect studies and independent generation of argento carbonium ions

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• 1,1-Diphenylalkenes. Part II. Alkylation of 1,1-diphenylpropene carbanions. The principle of least motion

  1972cited by this paper
• Étude de l'addition des organozinciques α-éthyléniques aux amines éthyléniques, acétyléniques et alléniques

  1972cited by this paper
• Facile synthesis of (+-)-ar-artemisene via olefin metalation

  1972cited by this paper
• Alternative total synthesis of (±)-β-santalene, (±)-epi-β-santalene, (±)-α-santalene, (±)-copacamphor and (±)-ylangocamphor

  1972cited by this paper
• Photochemistry of substituted 1,5-hexadien-3-ones

  1972cited by this paper
• Nucleophilic reactivity of the carbon-carbon double bond. VI. Products from 5-hexenyl, cyclopentylmethyl, and cyclohexyl cations with different leaving groups

  1972cited by this paper
• Allyl‐Aluminium Compounds

  1972cited by this paper
• The reactions of grignard reagents with organic peroxides and disulphides

  1971cited by this paper
• Synthesis and reactions of 2,3-diphenyl-2,5-dihydro-2-furanol

  1971cited by this paper
• Addition conjuguee d'organomagnesiens a-insatures aux amides a-ethyleniques N,N-disubstitues

  1971cited by this paper
• New synthesis of .alpha.,.beta.-unsaturated aldehydes using 1,3-bis(methylthio)allyllithium

  1971cited by this paper
• The stereochemistry of additions of grignard reagents to alkynols

  1971cited by this paper
• The reaction between ketones and t-butylallyl magnesium bromide. A sensitive measure of steric hindrance in the neighbourhood of the carbonyl group.

  1971cited by this paper
• Cyclization of cis- and trans-2-(2-methoxycyclohexyl)ethanol to cis- and trans-perhydrobenzofurans

  1971cited by this paper
• The influence of steric and torsional strain on the steric course of additions to cyclohexanones. The reaction between 4-T-butylcyclohexanone and T-butylallyl magnesium bromide.

  1971cited by this paper
• Mecanisme de l'action des organometalliques sur l'imino-ether C6H5NCHOC2H5 - nouvelle methode de synthese des isonitriles.

  1971cited by this paper
• Thermal reactions of allylic mono- and dianions

  1971cited by this paper
• Synthetic Studies on Damascenones

  1971cited by this paper
• The Reaction of Diisoprene Dianion with Ketones

  1971cited by this paper
• Alkylation of allylic carbanions. Directive effects

  1971cited by this paper
• Reactions of trans-cinnamyltriethyl- and trans-cinnamyltriphenyltin with tribromoborane, preferential transfer of the cinnamyl group from tin to boron

  1971cited by this paper
• The Synthesis and Reactions of Yomogi Alcohol. Conversion of the artemisyl skeleton to the santolinyl skeleton by a 1,2-shift of a vinyl group. Synthesis of santolinatriene†

  1971cited by this paper
• Additions of the allyl grignard reagent to allenols

  1971cited by this paper
• Promotion by primary and tertiary amine functions of additions of grignard reagents to alkenes and alkynes

  1971cited by this paper
• The reactions of 1,3-diphenylalk-1-enes with butyl-lithium

  1971cited by this paper
• The Chemistry of Allyl and Crotyl Grignard Reagents

  1971cited by this paper
• Coupling reactions between Grignard reagents and silicon–hydrogen bonds, catalysed by a nickel(II) complex

  1970cited by this paper
• A non-stereospecific synthesis of (±)-davanone

  1970cited by this paper
• Kinetics and mechanism of the addition of allyl magnesium bromide to the double bond of cinnamyl alcohol. Catalysis by magnesium bromide.

  1970cited by this paper
• Cross-association of n-butyl-lithium with 1,3-diphenylbut-1-enyl-lithium

  1970cited by this paper
• The Addition of Grignard Reagents to Alkylidenemalonic Esters. IV. The Reactions of Isopropylidenemalonic Esters with Allylmagnesium Bromide and 2-Butenylmagnesium Bromide.

  1970cited by this paper
• Stereospecific displacements of p-toluenesulfonate and iodide ions with organolithium reagents

  1970cited by this paper
• Stereochimie de quelques reactions entre aldehydes et reactifs de Grignard satures et allyliques

  1970cited by this paper
• Competitive rate studies for some reactions involving the allyl, butenyl, αγ-dimethylallyl, and propyl Grignard reagents. the mechanism of the reactions of allylic Grignard reagents with electrophilic substrates.

  1970cited by this paper
• Mercury(II) derivatives of acetylacetone

  1970cited by this paper
• Phenyl isonitrile from the action of alkyllithiums on ethyl N-phenylformimidate. Addition of organolithiums to isonitriles

  1970cited by this paper
• Nuclear magnetic resonance evidence for ion pairing in alkali-metal salts of 1,3-diphenylpropene

  1970cited by this paper
• Alkylation of cyclohexa-1,4-diene

  1970cited by this paper
• Die addition von allylmagnesium-halogeniden an 1-alkene

  1970cited by this paper
• Reactions of some grignard reagents with 2,6-dichloropyridine

  1970cited by this paper
• Vapor phase acetylenic oxy-Cope reaction of 5-hexen-1-yn-3-ol. The chemistry of an allenol intermediate

  1970cited by this paper
• Proposed radical pathway for the additon of allyl grignard reagents to conjugated anils

  1970cited by this paper
• The properties of tetraallylsilane, -germane and -tin

  1970cited by this paper
• Stereospecific coupling reactions between organolithium reagents and secondary halides

  1970cited by this paper
• Addition of organolithium reagents to the double bond of allylic alcohols

  1969cited by this paper
• Prevalence of cis-addition products in the reaction of the butenyl Grignard reagent with sterically hindered ketones

  1969cited by this paper
• Allyl-lithium adducts from buta-1,3-diene and s- or t-butyl-lithium

  1969cited by this paper
• Synthesis of allylic halides and 1,5-dienes from allylic alcohols

  1969cited by this paper
• Nuclear magnetic resonance spectroscopy. Low temperature studies of diallylmagnesium

  1969cited by this paper
• Reaction of crotylmagnesium bromide with hindered ketones, First examples of the reversible Grignard reaction

  1969cited by this paper
• Ätherspaltungen mit magnesium: ein direkter zugang zu allylmagnesium-phenolaten☆

  1969cited by this paper
• Promotion by hydroxyl functions of additions of Grignard reagents to alkynes

  1969cited by this paper
• Intramolecular cyclization of an allenic grignard reagent

  1969cited by this paper
• Intramolecular coordinative assistance in the addition of Grignard reagents to unconjugated carbon-carbon unsaturation

  1969cited by this paper
• Ionic character of allyllithium

  1968cited by this paper
• Intramolecular cyclizations of acetylenic grignard reagents

  1968cited by this paper
• Torsional strain involving partial bonds. The steric course of the reaction between allyl magnesium bromide and 4-t-butyl-cyclohexanone

  1968cited by this paper
• α-Alcoylation d'allyl-thioethers: couplage queue-a-queue d'unites isopreniques

  1968cited by this paper
• Diene studies. IV. Preparation and protonation of pentadienyllithiums

  1967cited by this paper
• Beitrag zur kenntnis von allyl-zink-verbingungen II. Darstellung und eigenschaften von dimethallylzink und dicrotylzink

  1967cited by this paper
• Diene studies. V. Structures of and rotation barriers in pentadienyllithiums

  1967cited by this paper
• Vapor-phase thermolyses of 3-hydroxy-1,5-hexadienes. II. Effects of methyl substitution

  1967cited by this paper
• Reaction of Grignard reagents with arylthiomethylarylamines and with tris(phenylthiomethyl)amines

  1967cited by this paper
• The Geometric Stability of 1,3-Diphenylallyllithium

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• Reaction of Grignard reagents with N,N-dialkyl-N-(phenylthiomethyl)amines

  1967cited by this paper
• cis-trans-Isomerization of crotyllithium and crotyltrimethyltin

  1967cited by this paper
• Facile intramolecular cyclization of an olefinic grignard reagent

  1966cited by this paper
• Addition of grignard reagents to the double bond of allylic alcohols

  1966cited by this paper
• Synthesis and Reactions of 2-Cyclopenten-1-ylmagnesium Chloride.

  1966cited by this paper
• The Reaction of Δ2-Cyclohexenone with β-Methylallylmagnesium Chloride and Isobutylmagnesium Chloride. The Effect of Added Cuprous Chloride1

  1966cited by this paper
• Zur Umsetzung cyclischer Imide mit Allylmagnesiumbromid

  1965cited by this paper
• Fluoro Olefins. XII. The Reaction of Allylmagnesium Bromide with Fluoro Olefins1,2

  1965cited by this paper
• Allylic rearrangements in organoaluminum systems

  1965cited by this paper
• Addition of Allylmagnesium Bromide to Hindered Ketones1

  1965cited by this paper
• The stereochemical course of epoxide ring opening by allylic grignard reagents

  1965cited by this paper
• Facile Addition of a Grignard Reagent to an Unconjugated Ethylenic Linkage

  1965cited by this paper
• Darstellung und eigenschaften des diallylzinks

  1965cited by this paper
• The Addition of Trichloromethyl Radical to Substituted 3-Phenyl-1-propenes and 4-Phenyl-1-butenes

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• The Synthesis of Tetravinylmethane

  1964cited by this paper
• The preparation and properties of a series of olefinic tin compounds

  1964cited by this paper
• Kinetics of the Ring Opening of Cyclobutylmethyorganomagnesium Compounds

  1964cited by this paper

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  2018cites this paper
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  2016cites this paper
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  2015cites this paper
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  2015cites this paper
• Direct carboxylation of allylic halides with carbon dioxide in the presence of indium.

  2014cites this paper
• Cobalt-catalyzed carboxylation of propargyl acetates with carbon dioxide.

  2014cites this paper
• Ligand-controlled regiodivergent Ni-catalyzed reductive carboxylation of allyl esters with CO2.

  2014cites this paper
• Isoxazole-embedded allylic zinc reagent for the diastereoselective preparation of highly functionalized aldol-type derivatives bearing a stereocontrolled quaternary center.

  2014cites this paper
• Introduction of prenyl fragment into chalcones through α-regioselective 1,2-addition in THF

  2014cites this paper
• Structurally defined allyl compounds of main group metals: coordination and reactivity.

  2013cites this paper
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  2010cites this paper
• A shift in retrosynthetic paradigm.

  2008cites this paper
• Chapter 7. Carbometallation Reactions

  2007cites this paper
• Zinc and Cadmium

  2007cites this paper
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  2007cites this paper
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  2007cites this paper
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  2007cites this paper
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  2006cites this paper
• Iron-Catalyzed Allylation of Ketones.

  2006cites this paper
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  2005cites this paper
• Development of New Reagents Containing Silicon and Related Metals and Application to Practical Organic Syntheses

  2004cites this paper
• Hydroxyapatite supported copper catalyst for effective three-component coupling

  2004cites this paper
• Reactive barium-promoted Reformatsky-type reaction of α-chloroketones with aldehydes

  2004cites this paper
• Conjugate additions of carbon nucleophiles to cyclopentadienones.

  2003cites this paper
• Regio‐ and Stereoselective Carboxylation of Allylic Barium Reagents: (E)‐4,8‐Dimethyl‐3,7‐Nonadienoic Acid

  2003cites this paper
• Study of the regioselectivity and diastereoselectivity in the addition of 3-substituted-2-propenylmetal reagents to N , N ′-di[1( S )-phenylethyl]ethanediimine

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• Regioselectivity in the intramolecular allyl transfer reaction catalysed by electrogenerated nickel complexes: influence of metal ions

  2002cites this paper
• Asymmetric Addition of Allylic Stannanes to Aldehydes Catalyzed by BINAP•Ag(I) Complex

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• In-MEDIATED ALLYLATION OF α-KETO ESTERS WITH ALLYL HALIDES*

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  1997cites this paper
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• Cyclohexynes as intermediates in a novel endo-cyclization of alkynylzincates derived from 5-hexynyl tosylates

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• 1.1 – Allyl Organometallics

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  1990cites this paper
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• Acyclic stereocontrol via allylic organometallic compounds

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