Recent development of reactions with alpha-diazocarbonyl compounds as nucleophiles.

No abstract is available for this paper.

• Publication year

  2009

• Venue

  Chemical Communications

• Publication date

  2009-09-02

• Fields of study

  Medicine, Chemistry

• Identifiers
  DOI 10.1039/b908378bPMID 19724784
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Aldol-type coupling of aldehydes with ethyl diazoacetate catalyzed by supported ionic liquid

  2009cited by this paper
• Magnesium-catalyzed asymmetric direct aldol addition of ethyl diazoacetate to aromatic, aliphatic, and alpha,beta-unsaturated aldehydes.

  2009cited by this paper
• Catalytic homologation of cycloalkanones with substituted diazomethanes. Mild and efficient single-step access to alpha-tertiary and alpha-quaternary carbonyl compounds.

  2009cited by this paper
• Stereoselective construction of seven-membered rings with an all-carbon quaternary center by direct Tiffeneau-Demjanov-type ring expansion.

  2009cited by this paper
• Enantioselective aza-Darzens reaction catalyzed by a chiral phosphoric acid.

  2009cited by this paper
• Highly diastereoselective addition of the lithium enolate of alpha-diazoacetoacetate to N-sulfinyl imines: enantioselective synthesis of 2-oxo and 3-oxo pyrrolidines.

  2008cited by this paper
• Trans-selective asymmetric aziridination of diazoacetamides and N-Boc imines catalyzed by axially chiral dicarboxylic acid.

  2008cited by this paper
• Lewis acid promoted carbon-carbon bond cleavage of gamma-silyloxy-beta-hydroxy-alpha-diazoesters.

  2008cited by this paper
• Recent studies on the reactions of α-diazocarbonyl compounds

  2008cited by this paper
• Palladium-catalyzed reaction of allyl halides with alpha-diazocarbonyl compounds.

  2008cited by this paper
• Brønsted acid-catalyzed insertion of aryldiazoacetates to sp2 carbon-CHO bond: facile construction of chiral all-carbon quaternary center.

  2008cited by this paper
• Construction of highly functionalized diazoacetoacetates via catalytic Mukaiyama-Michael reactions.

  2008cited by this paper
• Catalysis in Water: Aldol-Type Reaction of Aldehydes and Imines with Ethyl Diazoacetate Catalyzed by Highly Basic Magnesium/Lanthanum Mixed Oxide

  2007cited by this paper
• DBU-catalyzed condensation of acyldiazomethanes to aldehydes in water and a new approach to ethyl β-hydroxy α-arylacrylates

  2007cited by this paper
• N,N'-ditosylhydrazine: a convenient reagent for facile synthesis of diazoacetates.

  2007cited by this paper
• Diazo preparation via dehydrogenation of hydrazones with "activated" DMSO.

  2007cited by this paper
• Design of axially chiral dicarboxylic acid for asymmetric Mannich reaction of arylaldehyde N-Boc imines and diazo compounds.

  2007cited by this paper
• Palladium-catalyzed cross-coupling of aryl or vinyl iodides with ethyl diazoacetate.

  2007cited by this paper
• Synthesis of α-diazo-β-hydroxyesters through a one-pot protocol by phase-transfer catalysis: application to enantioselective aldol-type reaction and diastereoselective synthesis of α-amino-β-hydroxyester derivatives

  2006cited by this paper
• Rhodium(II)-Catalyzed Reaction of Diazocompounds in the Service of Organic Synthesis of Natural and Non-Natural Products

  2006cited by this paper
• Constructing chiral diazoacetoacetates by enantioselective catalytic Mukaiyama aldol reactions

  2006cited by this paper
• New Approaches to Polysubstituted Pyrroles and γ-Lactams Based on Nucleophilic Addition of Ti(IV) Enolates Derived from α-Diazo-β-keto Carbonyl Compounds to N-Tosylimines

  2006cited by this paper
• CuSO4-catalyzed diazo decomposition in water: a practical synthesis of β-keto esters

  2006cited by this paper
• Facile transformation of benzocyclobutenones into 2,3-benzodiazepines via 4pi-8pi tandem electrocyclic reactions involving net insertion of diazomethylene compounds.

  2006cited by this paper
• New approaches to polysubstituted pyrroles and gamma-lactams based on nucleophilic addition of Ti(IV) enolates derived from alpha-diazo-beta-keto carbonyl compounds to N-tosylimines.

  2006cited by this paper
• 1,2-migration in rhodium(II) carbene transfer reaction: remarkable steric effect on migratory aptitude.

  2006cited by this paper
• Ligand-induced control of C-H versus aliphatic C-C migration reactions of Rh carbenoids.

  2006cited by this paper
• Catalytic addition methods for the synthesis of functionalized diazoacetoacetates and application to the construction of highly substituted cyclobutanones.

  2005cited by this paper
• 1,2-vinyl and 1,2-acetylenyl migration in Rh(II) carbene reaction: remarkable bystander effect.

  2005cited by this paper
• Organocatalytic asymmetric direct alkylation of alpha-diazoester via C-H bond cleavage.

  2005cited by this paper
• 1,2-Thio group migration in Rh(II) carbene reactions.

  2005cited by this paper
• A new method for the synthesis of 2-cyclopenten-1-one-5-carboxylic ester derivatives via Rh2(OAc)4-mediated intramolecular C–H insertion reaction of 4Z-β-vinyl-α-diazo β-ketoesters

  2005cited by this paper
• Copper, silver and gold-based catalysts for carbene addition or insertion reactions

  2005cited by this paper
• Organocatalytic Asymmetric Direct Alkylation of α-Diazoester via C−H Bond Cleavage

  2005cited by this paper
• Reactions of Organic Nitrogen Compounds with Carbenoids and Diarylketenes from Diazoalkanes and Diazocarbonyls

  2005cited by this paper
• The Brønsted acid-catalyzed direct aza-Darzens synthesis of N-alkyl cis-aziridines.

  2004cited by this paper
• Parallel synthesis of terminal alkynes using a ROMPgel-supported ethyl 1-diazo-2-oxopropylphosphonate.

  2004cited by this paper
• A general procedure for the esterification of carboxylic acids with diazoalkanes generated in situ by the oxidation of N-tert-butyldimethylsilylhydrazones with (difluoroiodo)benzene.

  2004cited by this paper
• One-pot synthesis of α-diazo-β-hydroxyesters under phase-transfer catalysis and application to the catalytic asymmetric aldol reaction

  2004cited by this paper
• A highly stereoselective addition of the anion derived from alpha-diazoacetamide to aromatic N-tosylimines.

  2004cited by this paper
• Reactions of Carbenoids and Ketenes from α-Diazocarbonyls and Their Applications in Natural Products Synthesis

  2003cited by this paper
• Direct catalytic asymmetric aldol-type reaction of aldehydes with ethyl diazoacetate.

  2003cited by this paper
• Unusual reaction of beta-hydroxy alpha-diazo carbonyl compounds with Cl3CCN/NaH and Rh(II)-catalyzed reaction of beta-trichloroacetylamino alpha-diazo carbonyl compounds.

  2003cited by this paper
• How nucleophilic are diazo compounds?

  2003cited by this paper
• Investigation of the transition-metal- and acid-catalyzed reactions of beta-(N-tosyl)amino diazo carbonyl compounds.

  2003cited by this paper
• Catalytic enantioselective C-H activation by means of metal-carbenoid-induced C-H insertion.

  2003cited by this paper
• Unusual Reaction of β-Hydroxy α-Diazo Carbonyl Compounds with Cl3CCN/NaH and Rh(II)-Catalyzed Reaction of β-Trichloroacetylamino α-Diazo Carbonyl Compounds

  2003cited by this paper
• An efficient synthesis of α-aryl β-(N-tosyl)amino phosphonate derivatives from α-diazophosphonate

  2003cited by this paper
• A novel approach to bicyclic fused cyclopentenone derivatives

  2003cited by this paper
• Further Improvements of the Synthesis of Alkynes from Aldehydes

  2003cited by this paper
• DBU-promoted condensation of acyldiazomethanes to aldehydes and imines under catalytic conditions

  2002cited by this paper
• Lewis acid controlled regioselective 1,2 and 1,4 reaction of alpha,beta-unsaturated carbonyl compounds with Ti(IV) enolates derived from alpha-diazo beta-keto carbonyl compounds.

  2002cited by this paper
• A new method for the preparation of silyl enol ethers from carbonyl compounds and (trimethylsilyl)diazomethane in a regiospecific and highly stereoselective manner.

  2002cited by this paper
• Lewis Acid Controlled Regioselective 1,2 and 1,4 Reaction of α,β‐Unsaturated Carbonyl Compounds with TiIV Enolates Derived from α‐Diazo β‐Keto Carbonyl Compounds

  2002cited by this paper
• Catalyst Selection for Metal Carbene Transformations

  2001cited by this paper
• Recent progress in asymmetric intermolecular CH activation by rhodium carbenoid intermediates

  2001cited by this paper
• β-Oxy-α-diazo-carbonyl compounds. Part 5: An improved synthesis of β-hydroxy-α-diazo esters derived from monosaccharides and synthetic applications in the chemistry of 3-deoxy-2-ulosonic acids

  2001cited by this paper
• Catalytic enantioselective rearrangements and cycloadditions involving ylides from diazo compounds

  2001cited by this paper
• 1,2-Aryl and 1,2-Hydride Migration in Transition Metal Complex Catalyzed Diazo Decomposition:  A Novel Approach to α-Aryl-β-enamino Esters

  2001cited by this paper
• 1,2-aryl and 1,2-hydride migration in transition metal complex catalyzed diazo decomposition: a novel approach to alpha-aryl-beta-enamino esters.

  2001cited by this paper
• Rhodium(II) mediated cyclizations of diazo alkynyl ketones

  2000cited by this paper
• De Novo Syntheses of Racemic Deoxy-C-nucleosides

  1999cited by this paper
• Orthoester condensation/CO insertion reaction sequence for the preparation of tetrahydrofurans

  1998cited by this paper
• Zinc Derivative of Ethyl Diazoacetate in the Synthesis of α-Diazo-β-hydroxy Esters

  1998cited by this paper
• Recent Advances in Asymmetric Catalytic Metal Carbene Transformations.

  1998cited by this paper
• Condensation of D-mannosaldehyde derivatives with ethyl diazoacetate. An easy and stereoselective chain elongation methodology for carbohydrates: Application to new syntheses for KDO and 2-deoxy-β-KDO

  1997cited by this paper
• Aldol-cyclization reaction sequence for the synthesis of tetrahydrofurans

  1997cited by this paper
• Cascade Processes of Metallo Carbenoids.

  1996cited by this paper
• Ligand Effects on the Chemoselectivity of Transition Metal Catalyzed Reactions of α‐Diazo Carbonyl Compounds

  1994cited by this paper
• Synthesis of .gamma.-unsubstituted .alpha.-acyl-.beta.-tetronic acids from aldehydes

  1994cited by this paper
• β-Oxy-α-diazo carbonyl compounds. III. Rh2(AcO)4 mediated decomposition of β-acetoxy-α-diazo esters. Application to the synthesis of natural 3-deoxy-2-keto aldonic acids (KDO and DAH)

  1994cited by this paper
• Organic Synthesis with .alpha.-Diazo Carbonyl Compounds

  1994cited by this paper
• Tin(II) chloride catalyzed addition of diazo sulfones, diazo phosphine oxides, and diazo phosphonates to aldehydes.

  1992cited by this paper
• Synthesis of 1,3-diketones using .alpha.-diazo ketones and aldehydes in the presence of tin(II) chloride

  1990cited by this paper
• A selective method for the direct conversion of aldehydes into .beta.-keto esters with ethyl diazoacetate catalyzed by tin(II) chloride

  1989cited by this paper
• Electrophilic Diazoalkane Substitution

  1985cited by this paper
• Catalyzed insertion reactions of substituted α-diazoesters. A new synthesis of cis-enoates

  1981cited by this paper
• Elaboration of aldehydes and ketones to alkynes: improved methodology

  1979cited by this paper
• One-step conversion of carbonyl compounds into acetylenes

  1973cited by this paper
• Novel diazo alkanes and the first carbene containing the dimethyl phosphite group

  1967cited by this paper
• Synthese von Ketonsäureäthern aus Aldehyden und Diazoessigäther

  1885cited by this paper

• Enantioselective Three-Component Radical Alkene Diazomethyl-Cyanation Enabled by Copper/Photoredox Dual Catalysis

  2026cites this paper
• Sequential oxidative dearomatization/asymmetric homologation: from simple naphthols to chiral benzocycloheptanes

  2025cites this paper
• Mechanistic Insights Into the B(C6F5)3-catalyzed Wolff Rearrangement/[2 + 2] and [4 + 2] Cascade Cyclization of α-Diazoketones With Imines.

  2025cites this paper
• Nucleophilic addition of sulfoxonium ylides to hypervalent iodine diazo compounds as N-terminal electrophiles: direct access to novel functionalized hydrazones

  2025cites this paper
• Reaction of Donor-Acceptor α-Diazo Esters and N,N-Dimethylformamide/γ-Lactams To Generate α-Amino-α-aroylethanoates.

  2025cites this paper
• A Tsuji-Trost Reaction Using Free Carbenes as Nucleophiles: Palladium-Catalyzed Photoinduced Coupling of Acylsilanes with Allylic Alcohol Derivatives.

  2025cites this paper
• Azirinyl-Substituted Nitrile Oxides: Generation and Use in the Synthesis of Isoxazole Containing Heterocyclic Hybrids

  2025cites this paper
• Synthesis of 2-Chlorocyclopropene-Tethered Diazocarbonyl Compounds and Their Cyclization to Form Poly-Substituted Phenols.

  2025cites this paper
• Visible Light-Induced Reactions of Diazo Compounds and Their Precursors.

  2024cites this paper
• Oxidative treatment of micropollutants present in wastewater: A special emphasis on transformation products, their toxicity, detection, and field-scale investigations.

  2024cites this paper
• Denitrogenative dismantling of heteroaromatics by nucleophilic substitution reactions with diazomethyl compounds

  2024cites this paper
• Base‐Catalyzed Nucleophilic Addition of Oxindoles to 3‐Diazo Oxindoles: An Efficient Approach for the Synthesis of Functionalized Isatin‐Hydrazones

  2024cites this paper
• O-H Insertion of Hydrogenphosphate Derivatives and α-Diazo Compounds.

  2024cites this paper
• Production of Phenyldiazene Derivatives Using the Biosynthetic Pathway of an Aromatic Diazo Group‐Containing Natural Product from an Actinomycete

  2024cites this paper
• Rhodium(I)-Catalyzed O-H Insertions on O-Protected α-Diazo-β-Hydroxyesters.

  2024cites this paper
• A visible light-induced photoredox-catalyzed assembly-point di/trifunctionalization of diazomethyl radicals

  2024cites this paper
• Chiral Magnesium Complex-Catalyzed Asymmetric Cyclization of Vinyl Diazo Compounds with Phenol Derivatives via Noncarbene Pathways

  2024cites this paper
• Ring-Opening Polymerization of α-Diazo Lactones: Access to Diazo-Containing Polyesters and Their Post-Polymerization Modifications

  2024cites this paper
• Copper-catalyzed strain-enabled reaction of bicyclobutanes with diazo compounds to synthesize penta-1,4-dienes.

  2024cites this paper
• Visible‐Light‐Induced Synthesis of Thioethers through Three‐Component Reactions of α‐Diazoesters, Thiols, and Cyclic Ethers

  2023cites this paper
• Synthesis of Hypervalent Iodine Diazo Compounds and Their Application in Organic Synthesis.

  2023cites this paper
• Divergent transformation of C,N-cyclic-N'-acyl azomethine imines by reaction with diazo compounds.

  2023cites this paper
• CuBr-mediated synthesis of 1,4-naphthoquinones via ring expansion of 2-aryl-1,3-indandiones.

  2023cites this paper
• Catalytic Asymmetric Formal C–C Bond Insertion Reaction of Aldehydes via 1,2-Acyl Shift: Construction of All-Carbon Quaternary Stereocenters with Three Carbonyl Groups

  2023cites this paper
• DBU-Promoted Tandem Cyclization of Ynones and Diazo Compounds: Direct Synthesis of Eight-Membered Cyclic Ethers.

  2023cites this paper
• Asymmetric formal C–C bond insertion into aldehydes via copper-catalyzed diyne cyclization

  2023cites this paper
• Photoredox-Enabled Self-(3+2) Cyclization of Vinyldiazo Reagents: Synthesis of Cyclopentenyl α-Diazo Compounds.

  2023cites this paper
• Enzyme-catalyzed addition of diazo compounds to in-situ generated imines

  2023cites this paper
• Synthesis of o ‐carboranyl‐acyl‐substituted diazo compounds from B(4)‐acylmethyl carboranes and 2‐azido ‐1, 3‐dimethylimidazolinium hexafluorophosphate

  2023cites this paper
• Regioselective Synthesis of N-Vinyl Pyrazoles from Vinyl Sulfonium Salts with Diazo Compounds.

  2023cites this paper
• Recent advances in transition-metal-catalyzed carbene insertion to C-H bonds.

  2022cites this paper
• Intramolecular One-Carbon Homologation of Unstrained Ketones via C-C Activation-Enabled 1,1-Insertion of Alkenes.

  2022cites this paper
• Asymmetric Catalytic Rearrangements with α-Diazocarbonyl Compounds.

  2022cites this paper
• Selective Synthesis of Azoloyl NH-1,2,3-Triazoles and Azolyl Diazoketones: Experimental and Computational Insights

  2022cites this paper
• Enantioselective construction of axially chiral cyclohexylidene scaffolds via Pd-catalyzed asymmetric coupling reaction

  2022cites this paper
• Metal-free visible-light-induced multi-component reactions of α-diazoesters leading to S-alkyl dithiocarbamates

  2022cites this paper
• Cu(II)-Catalyzed Synthesis of 4-(1,4,5,6-Tetrahydropyridin-3-yl)-1,4-dihydroisoquinolin-3-ones from 4-Diazoisoquinolin-3-ones.

  2022cites this paper
• Synthesis of Functionalized Indolobenzazepinones via Sc(OTf)3-Induced Ring Expansion/Annulation Reactions of 4-Diazoisoquinolin-3-ones with Isatins.

  2022cites this paper
• Acid-Catalyzed Decomposition of O-Silylated α-Diazo-β-hydroxy Esters: Access to Mixed Monosilyl Acetals.

  2022cites this paper
• 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Promoted Nucleophilic Addition of Two Molecules of Nitroalkanes to Diazo Compounds: Synthesis of Highly Functionalized Hydrazones and Tetrahydropyridazines

  2022cites this paper
• Lewis Acid Mediated Conjugate Addition of Isocyanides to β-Hydroxy-α-diazo Carbonyls: Synthesis of β-Carboxamido-α-diazo Carbonyl Compounds.

  2022cites this paper
• TfOH-catalyzed three-component synthesis of Dithiocarbamates from α-Diazoesters under continuous flow conditions

  2022cites this paper
• B(C6F5)3-catalyzed oxidation of α-diazoesters using DMF and molecular oxygen as oxygen sources

  2022cites this paper
• Synthesis of functionalized S-benzyl dithiocarbamates from diazo-compounds via multi-component reactions with carbon disulfide and secondary amines.

  2022cites this paper
• Exploiting the umpolung reactivity of diazo groups: direct access to triazolyl-azaarenes from azaarenes.

  2022cites this paper
• Transition-metal-free synthesis of 5-amino-1,2,3-triazoles via nucleophilic addition/cyclization of carbodiimides with diazo compounds

  2021cites this paper
• Visible Light‐Induced [3+2] Cyclization Reactions of Hydrazones with Hypervalent Iodine Diazo Reagents for the Synthesis of 1‐Amino‐1,2,3‐Triazoles

  2021cites this paper
• Synthesis of 5-trifluoromethyl-1,2,3-triazoles via base-mediated cascade annulation of diazo compounds with trifluoroacetimidoyl chlorides

  2021cites this paper
• Asymmetric catalytic 1,3-dipolar cycloaddition of α-diazoesters for synthesis of 1-pyrazoline-based spirochromanones and beyond

  2021cites this paper
• Catalytic Asymmetric Carbene Insertion Reactions into B−H Bonds Using a Ru(II)‐Pheox Complex

  2021cites this paper
• Asymmetric synthesis of dihydro-1,3-dioxepines by Rh(ii)/Sm(iii) relay catalytic three-component tandem [4 + 3]-cycloaddition

  2021cites this paper
• Time‐Economical Synthesis of Diarylacetates Enabled by TfOH‐Catalyzed Arylation of α‐Aryl‐α‐Diazoesters with Arenes

  2021cites this paper
• Recent advances in the synthesis of indole embedded heterocycles with 3-diazoindolin-2-imines

  2021cites this paper
• Construction of Protoberberine Alkaloid Core through Palladium Carbene Bridging C–H Bond Functionalization and Pyridine Dearomatization

  2021cites this paper
• Catalytic Asymmetric Homologation of Ketones with α-Alkyl α-Diazo Esters.

  2021cites this paper
• TIPS-Diazoacetone Aldol Addition: Mechanistic Aspects and Contribution to the Synthesis.

  2021cites this paper
• Diverse Reactions of Vinyl Diazo Compounds with Quinone Oxonium Ions, Quinone Imine Ketals, and Eschenmoser’s Salt

  2021cites this paper
• Catalyst-Free Formation of Nitrile Oxides and Their Further Transformations to Diverse Heterocycles.

  2021cites this paper
• Highly Regioselective Synthesis of Multisubstituted Pyrroles via Ag-Catalyzed [4+1C]insert Cascade

  2020cites this paper
• Stereoselective Bioreduction of α-diazo-β-keto Esters

  2020cites this paper
• Silver‐Catalyzed Three‐Component Coupling Reaction of Amines, 2‐Isocyanobenzaldehydes, and 2,2,2‐Trifluorodiazoethane and Synthesis of Trifluoromethyl‐Substituted Indolo[1,2‐ c ]quinazolines

  2020cites this paper
• Palladium-Catalyzed Three-Component Coupling Reaction of o-Bromobenzaldehyde, N-Tosylhydrazone, and Methanol.

  2020cites this paper
• Synthesis of 8-Alkoxy-5H-isochromeno[3,4-c]isoquinolines and 1-Alkoxy-4-arylisoquinolin-3-ols through Rh(III)-Catalyzed C-H Functionalization of Benzimidates with 4-Diazoisochroman-3-imines and 4-Diazoisoquinolin-3-ones.

  2020cites this paper
• Base Promoted Three-Component Annulation of 4-Diazoisochroman-3-imines with Dimethylsulfonium Ylides: Synthesis of Highly Functionalized Isochromeno[4,3-c]pyridazines.

  2020cites this paper
• Asymmetric synthesis of CF2-functionalized aziridines by combined strong Brønsted acid catalysis

  2020cites this paper
• A Modular Approach to Dibenzo‐fused ϵ‐Lactams: Palladium‐Catalyzed Bridging‐C−H Activation

  2020cites this paper
• Asymmetric acyl-Mannich reaction of isoquinolines with α-(diazomethyl)phosphonate and diazoacetate catalyzed by chiral Brønsted acids.

  2020cites this paper
• Chiral Primary Amine-Catalyzed Divergent Coupling of α-Substituted Acrylaldehydes with α-Diazoesters

  2020cites this paper
• Brønsted Acid Catalyzed Cyclization of Aminodiazoesters with Aldehydes to 3-Carboxylate-N-Heterocycles.

  2020cites this paper
• A Modular Approach to Dibenzo-fused ε-Lactams: Palladium Carbene Bridging C-H Activation and Its Synthetic Application.

  2020cites this paper
• Asymmetric Catalytic Synthesis of Epoxides via Three-Component Reaction of Diazoacetates, 2-Oxo-3-ynoates, and Nitrosoarenes.

  2020cites this paper
• Broadening the scope of biocatalytic C–C bond formation

  2020cites this paper
• Brønsted Acid Catalyzed Friedel-Crafts-type Coupling and Dedinitrogenation Reactions of Vinyldiazo Compounds.

  2020cites this paper
• An asymmetric hydrocyanation/Michael reaction of α-diazoacetates via Cu(i)/chiral guanidine catalysis.

  2020cites this paper
• Synthesis of β-triazolylenones via metal-free desulfonylative alkylation of N-tosyl-1,2,3-triazoles

  2020cites this paper
• Design and Synthesis of High‐Energy Strained Fuels

  2020cites this paper
• From reactive carbenes to chiral polyether macrocycles in two steps – synthesis and applications made easy?

  2020cites this paper
• One-pot Mukaiyama–Mannich reaction of aldehydes, amines and silyl enol diazoacetate catalyzed by MgI2 etherate

  2019cites this paper
• Deoxygenative Insertion of Carbonyl Carbon into a C(sp3)-H Bond: Synthesis of Indolines and Indoles.

  2019cites this paper
• Hantzsch Ester-Mediated Benzannulation of Diazo Compounds under Visible Light Irradiation.

  2019cites this paper
• Carbocation Lewis Acid TrBF4-Catalyzed 1,2-Hydride Migration: Approaches to (Z)-α,β-Unsaturated Esters and α-Branched β-Ketocarbonyls.

  2019cites this paper
• Chemodivergent and Stereoselective Construction of gem-Difluoroallylic Amines from Masked Difluorodiazo Reagents.

  2019cites this paper
• α-Heteroatom-substituted gem-Bisphosphonates: Advances in the Synthesis and Prospects for Biomedical Application

  2019cites this paper
• Mechanistic investigation-inspired activation mode of DBU and the function of the α-diazo group in the reaction of the α-amino ketone compound and EDA: [DBU-H]+-DMF-H2O and α-diazo as strong N-terminal nucleophiles

  2019cites this paper
• Rhodium-Catalyzed 1,1-Hydroacylation of Thioacyl Carbenes with Alkynyl Aldehydes and Subsequent Cyclization.

  2019cites this paper
• Zn(OAc)2-catalyzed tandem cyclization of isocyanides, α-diazoketones, and anhydrides: a general route to polysubstituted maleimides.

  2019cites this paper
• Structure Pattern Based Total Synthesis.

  2019cites this paper
• Rhodium-Catalyzed Coupling-Cyclization of Alkenyldiazoacetates with o-Alkenyl Arylisocyanides: A General Route to Carbazoles.

  2019cites this paper
• Fe(ii)-Catalyzed alkenylation of benzylic C-H bonds with diazo compounds.

  2019cites this paper
• Rh(III)-Catalyzed Annulation of Boc-Protected Benzamides with Diazo Compounds: Approach to Isocoumarins

  2019cites this paper
• A rhodium-catalyzed three-component reaction of arylisocyanides, trifluorodiazoethane, and activated methylene isocyanides or azomethine ylides: an efficient synthesis of trifluoroethyl-substituted imidazoles

  2019cites this paper
• Copper(i)-carbenes as key intermediates in the [3 + 2]-cyclization of pyridine derivatives with alkenyldiazoacetates: a computational study.

  2019cites this paper
• A General Catalytic Route to Enantioenriched Isoindolinones and Phthalides: Application in the Synthesis of ( S)-PD 172938.

  2019cites this paper
• One-Step Synthesis of Diaza Macrocycles by Rh(II)-Catalyzed [3 + 6 + 3 + 6] Condensations of Morpholines and α-Diazo-β-ketoesters.

  2019cites this paper
• Gram-Scale Total Synthesis of Sarpagine Alkaloids and Non-Natural Derivatives.

  2019cites this paper
• Functionalization of Diazo Groups by the Nucleophilic Addition of Two Molecules of a Dimethylsulfonium Ylide to α-Diazo-β-ketoesters/ketones: Synthesis of Highly Functionalized Hydrazones.

  2019cites this paper
• Displacement of Dinitrogen by Oxygen: A Methodology for the Catalytic Conversion of Diazocarbonyl Compounds to Ketocarbonyl Compounds by 2,6-Dichloropyridine-N-oxide.

  2018cites this paper
• α-Arylamino Diazoketones: Diazomethane-Loading Controlled Synthesis, Spectroscopic Investigations, and Structural X-ray Analysis.

  2018cites this paper
• Palladium-Catalyzed Intermolecular Acylation of Aryl Diazoesters with ortho-Bromobenzaldehydes.

  2018cites this paper
• DBU‐Catalyzed [3+3] and [3+2] Annulation Reactions of Azomethine Ylides with α‐Diazocarbonyls as N‐Terminal Electrophiles: Modular, Atom‐Economical Access to 1,2,4‐Triazine and 1,2,4‐Triazole Derivatives

  2018cites this paper