Allylbarium Reagents: Unprecedented Regio- and Stereoselective Allylation Reactions of Carbonyl Compounds

No abstract is available for this paper.

• Publication year

  1994

• Venue

  Journal of the American Chemical Society

• Publication date

  1994-07-01

• Fields of study

  Chemistry

• Identifiers
  DOI 10.1021/JA00093A010
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• No references are available for this paper.

• α-Amino bisphosphonate triazoles serve as GGDPS inhibitors.

  2024cites this paper
• Metalation and subsequent transformations of β-pinene.

  2024cites this paper
• Lewis acid mediated allylation of vinyl diazonium ions by allylstannanes.

  2024cites this paper
• Mechanochemical generation of aryl barium nucleophiles from unactivated barium metal

  2024cites this paper
• Catalytic prenyl conjugate additions for synthesis of enantiomerically enriched PPAPs

  2024cites this paper
• Highly Regioselective Propargylation/Allenylation of Organolanthanum Reagents with Aldehydes.

  2023cites this paper
• Ligand-Metal Cooperation Enables Net Ring-Opening C-C Activation / Difunctionalization of Cyclopropyl Ketones.

  2023cites this paper
• Opportunities with calcium Grignard reagents and other heavy alkaline-earth organometallics

  2023cites this paper
• RETRACTED: Periods 6 and 7 (including lanthanides and actinides)

  2021cites this paper
• One-Shot Deprotonative Metalation/Transmetalation/Polymerization of Halothiophenes Catalyzed by Nickel Complex for Polythiophene Synthesis

  2021cites this paper
• Synthesis of Quaternary Carbon Stereogenic Centers By Diastereoselective Conjugate Addition of Boron-Stabilized Allylic Nucleophiles to Enones.

  2020cites this paper
• Visible‐Light Photoredox‐Catalyzed α‐Regioselective Conjugate Addition of Allyl Groups to Activated Alkenes

  2020cites this paper
• Amides as bioisosteres of triazole-based geranylgeranyl diphosphate synthase inhibitors.

  2020cites this paper
• Silyl-Group-Directed Linear-Selective Allylation of Carbonyl Compounds with Trisubstituted Allylboronates Using a Copper(I) Catalyst

  2020cites this paper
• Allylation of (R)-2,3-O-Cyclohexylideneglyceraldehyde with Methyl 3-(Bromomethyl)but-3-enoate. Methyl 3-{(2S)-2-[(2R)-1,4-Dioxaspiro[4.5]dec-2-yl]-2-hydroxyethyl}but-3-enoate as a Convenient Universal Building Block for the Synthesis of Key Fragments of Bioactive Compounds

  2019cites this paper
• Asymmetric Catalytic Formal 1,4-Allylation of β,γ-Unsaturated α-Ketoesters via Allylboration/Oxy-Cope Rearrangement.

  2019cites this paper
• Formation of Nitriles, Carboxylic Acids, and Derivatives by Carbonylation, Carboxylation, and Related Reactions

  2018cites this paper
• Synthesis and Structural Characterization of Butadienylcalcium-based Heavy Grignard Reagents and a Ca4 [O] Inverse Crown Ether Complex.

  2017cites this paper
• Forging C–C Bonds with Hindered Nucleophiles and Carbonyl Electrophiles: Reactivity and Selectivity of Allylic Tin Reagents/n-BuLi

  2017cites this paper
• α-Regioselective Barbier Reaction of Carbonyl Compounds and Allyl Halides Mediated by Praseodymium.

  2016cites this paper
• Stereoselective Synthesis of Homoneryl and Homogeranyl Triazole Bisphosphonates.

  2016cites this paper
• Highly α-regioselective neodymium-mediated allylation of diaryl ketones

  2016cites this paper
• Diastereo- and Enantioselective Iridium-Catalyzed Allylation of Cyclic Ketone Enolates: Synergetic Effect of Ligands and Barium Enolates

  2014cites this paper
• Intramolecular C–F and C–H bond cleavage promoted by butadienyl heavy Grignard reagents

  2014cites this paper
• 3.01 Alkylations of Enols and Enolates

  2014cites this paper
• Synthesis of (+)-Luzofuran and (−)-Ancistrofuran

  2014cites this paper
• Highly regioselective and chemoselective titanocene mediated Barbier-type allylation reactions.

  2014cites this paper
• Chemistry and Biology of the Polycyclic Polyprenylated Acylphloroglucinol Hyperforin

  2014cites this paper
• Stereoselective synthesis of side chain-functionalized tetrahydropyrans from 5-hexenols

  2014cites this paper
• Construction of the basic skeleton of ophiobolin A and variecolin.

  2013cites this paper
• Zinc-mediated highly α-regioselective 1,4-addition of chalcones with prenyl bromide in THF.

  2013cites this paper
• Formation and evolution of chain-propagating species upon ethylene polymerization with neutral salicylaldiminato nickel(II) catalysts.

  2013cites this paper
• Enantioselective total synthesis of hyperforin.

  2013cites this paper
• Inversion of regioselectivity in the electrochemical prenylation of benzaldehyde on a graphite powder cathode

  2013cites this paper
• Synthesis of isoxazoles en route to semi-aromatized polyketides: dehydrogenation of benzonitrile oxide-para-quinone acetal cycloadducts.

  2012cites this paper
• Zinc-mediated highly α-regioselective prenylation of imines with prenyl bromide.

  2012cites this paper
• Copper-catalyzed oxaziridine-mediated oxidation of C-H bonds.

  2012cites this paper
• Copper-catalyzed regio- and stereoselective conjugate allylation of electron-deficient alkynes with allylboronates under mild conditions.

  2012cites this paper
• Tin mediated Barbier type allylation in ionic liquids

  2011cites this paper
• The truth about false unicorn (Chamaelirium luteum): total synthesis of 23R,24S-chiograsterol B defines the structure and stereochemistry of the major saponins from this medicinal herb.

  2011cites this paper
• Total synthesis and absolute stereochemistry of seragakinone A.

  2011cites this paper
• Advances in alkaline earth-nitrogen chemistry

  2011cites this paper
• Chiral zinc-catalyzed asymmetric α-alkylallylation and α-chloroallylation of aldehydes.

  2011cites this paper
• Allyl Calcium Compounds: Synthesis and Structure of Bis(η3-1-alkenyl)calcium

  2011cites this paper
• Reactivity and Selectivity of Organotin Reagents in Allylation and Arylation: Nucleophilicity Parameter as a Guide

  2011cites this paper
• Asymmetric Synthesis and in vivo Biological Inactivity of the Right‐Hand Terpenoid Fragment of Terpendole E

  2011cites this paper
• The Development of the New Synthetic Methods Using Metallic Strontium

  2010cites this paper
• Combined transition-metal- and organocatalysis: an atom economic C3 homologation of alkenes to carbonyl and carboxylic compounds.

  2010cites this paper
• Allyl complexes of the heavy alkaline-earth metals: molecular structure and catalytic behavior

  2010cites this paper
• Thermochemical Considerations of Metal Enolates

  2010cites this paper
• Ti-catalyzed Barbier-type allylations and related reactions.

  2009cites this paper
• Conjugate allylation reactions of alkylidene malononitriles mediated by NHC-ligated palladium catalysts

  2009cites this paper
• Synthesis and characterization of alkynyl complexes of groups 1 and 2.

  2009cites this paper
• Enantioselective and catalytic method for alpha-crotylation of aldehydes with a kinetic self-refinement of stereochemistry.

  2009cites this paper
• Some Synthetic Uses of Double‐Bonded Functional Groups

  2009cites this paper
• Alkaline Earth Organometallics

  2007cites this paper
• Isoxazole-directed pinacol rearrangement: stereocontrolled approach to angular stereogenic centers.

  2007cites this paper
• Regioselective Barbier reactions of 2-bromomethylcyclohexenone

  2007cites this paper
• Demonstration of promoted zinc Schlenk equilibria, their equilibrium values and derived reactivity.

  2007cites this paper
• New reaction and new catalyst—a personal perspective

  2007cites this paper
• 2.02 – Alkaline Earth Organometallics

  2007cites this paper
• Alkaline Earth Metals: Organometallic Chemistry

  2006cites this paper
• Additions of Silyl Enol Ethers to β‐Formyl Esters – a Chelate‐controlled Synthesis of the Pheromone (+)‐Eldanolide

  2006cites this paper
• Asymmetric Dihydroxylation of β,γ-Unsaturated Carboxylic Esterswith Trisubstituted C=C Bonds – Enantioselective Syntheses of Trisubstituted γ-Butyrolactones

  2006cites this paper
• Allylation of aldehydes promoted by the cerium(III) chloride heptahydrate/sodium iodide system: the dependence of regio- and stereocontrol on the reaction conditions

  2005cites this paper
• The Chemistry of Alkylstrontium Halide Analogues : Barbier-type Alkylation of Imines with Alkyl Halides

  2005cites this paper
• Mn(III)-based C-C bond formation : Regioselective α' -allylation of various α,β-unsaturated, α and β-alkoxy α,β-unsaturated ketones

  2005cites this paper
• The Chemistry of Alkylstrontium Halide Analogues, Part 2: Barbier‐Type Dialkylation of Esters with Alkyl Halides

  2005cites this paper
• Enantioselective Protonations: Fundamental Insights and New Concepts

  2004cites this paper
• Reactive barium-promoted Reformatsky-type reaction of α-chloroketones with aldehydes

  2004cites this paper
• The Barbier-Type Alkylation of Aldehydes with Alkyl Halides in the Presence of Metallic Strontium

  2004cites this paper
• Regio‐ and Stereoselective Carboxylation of Allylic Barium Reagents: (E)‐4,8‐Dimethyl‐3,7‐Nonadienoic Acid

  2003cites this paper
• Biosynthetic Inspirations: Cationic Approaches to Cyclopropane Formation

  2003cites this paper
• Synthesis of (−)-xialenon A by enantioselective α-deprotonation-rearrangement of a meso-epoxide

  2003cites this paper
• Regioselective allylation reactions using crotyl Grignard reagent–CeCl3 systems

  2003cites this paper
• 1,4-Conjugate addition of allyltrimethylsilane to α,β-unsaturated ketones

  2002cites this paper
• Mn(III)-mediated radical CC bond formation: regioselective α′-allylation of α,β-unsaturated ketones

  2002cites this paper
• Generation of organotantalum reagents and conjugate addition to enones.

  2002cites this paper
• Barbier reaction in the regime of metal oxide: the first example of carbonyl allylation mediated by tetragonal tin(II) oxide.

  2002cites this paper
• Barium Triphenylmethanide: An Examination of Anion Basicity.

  2001cites this paper
• Bariumtriphenylmethanid: Untersuchung der Anionenbasizität

  2001cites this paper
• A new mechanistic proposal for the origin of α-homoallylic alcohols in indium-mediated allylation reactions in water

  2001cites this paper
• Phosphazene bases and the anionic oxy-Cope rearrangement

  2000cites this paper
• Non-cyclopentadienyl organometallic compounds of calcium, strontium and barium

  2000cites this paper
• Synthese und Kristallstruktur des Bis(allyl)-Calciumkomplexes [Ca{C3(SiMe3)2H3}2(thf)2]

  1999cites this paper
• Calcium-, Strontium- und Bariumacetylid – neue Befunde für die gewinkelte Struktur von Derivaten der schweren Erdalkalimetalle

  1999cites this paper
• GENERATION OF ALLYLIC AND BENZYLIC ORGANOLITHIUM REAGENTS FROM THE CORRESPONDING ESTER, AMIDE, CARBONATE, CARBAMATE AND UREA DERIVATIVES

  1999cites this paper
• Bistrifluoromethanesulfonimide in the catalytic conjugate allylation of α,β-unsaturated carbonyl compounds

  1998cites this paper
• Direct catalytic asymmetric aldol reactions promoted by a novel barium complex

  1998cites this paper
• Simple, stereocontrolled syntheses of 24(S),25-epoxy-22(R)-hydroxycholesterol, 22(R),24(S)-dihydroxycholesterol and diastereomers, new ligands for binding and activation of LXRs

  1998cites this paper
• Convenient preparation of metals deposited on solid supports and their use in organic synthesis

  1998cites this paper
• Reductive free-radical alkylations and cyclisations mediated by 1-alkylcyclohexa-2,5-diene-1-carboxylic acids

  1998cites this paper
• Potency and inactivation rates of analogues of an irreversible inhibitor of vertebrate oxidosqualene cyclase

  1997cites this paper
• The preparation of synthetically useful carbonyl-protected δ- and ε-lithio ketones via reductive lithiation

  1997cites this paper
• Chelation-Controlled Regioselection in Palladium-Catalyzed Carbonyl Allylation by 4-Pentene-1,3-Diol or Its Cyclic Carbonate

  1997cites this paper
• Formation and Reactions of Stereochemically Homogeneous Allylic Metals

  1997cites this paper
• Regioselective Coupling Reaction of Allylic Barium Reagents with Epoxides.

  1997cites this paper
• Highly regioselective allylation of imines with allylic barium reagents

  1996cites this paper
• Schizostatin, a novel squalene synthase inhibitor produced by the mushroom, Schizophyllum commune. II. Structure elucidation and total synthesis.

  1996cites this paper
• Schizostatin, a novel squalene synthase inhibitor produced by the mushroom, Schizophyllum commune. I. Taxonomy, fermentation, isolation, physico-chemical properties and biological activities.

  1996cites this paper