Intramolecular Cycloaddition Reactions of ortho-Quinodimethanes in Organic Synthesis

No abstract is available for this paper.

• Publication year

  1978

• Venue

  Synthesis

• Publication date

  Unknown publication date

• Fields of study

  Chemistry

• Identifiers
  DOI 10.1055/S-1978-24895
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar

• No claims are published for this paper.

• No concepts are published for this paper.

• No references are available for this paper.

• Synthesis of thiopyran derivatives via [4 + 2] cycloaddition reactions

  2025cites this paper
• Research Progress and Applications of Benzocyclobutene‐Based Functional Polymers

  2024cites this paper
• Synthesis of pyrenocycloalkenes by using [2+2] photocycloaddition to pyrene and Diels-Alder reaction

  2023cites this paper
• Formal Catalytic Cleavage of C(sp2)–C(sp2) Bonds Enabled the Construction of Dihydropyran-Fused Indoles

  2023cites this paper
• Thermal Insolubilization of Electrically n-Doped Films Achieved Using 7-Alkoxy-Benzocyclobutene-Substituted Fullerene and Dopant Molecules.

  2022cites this paper
• Applications of Benzynes in Natural Product Synthesis

  2021cites this paper
• Construction of poly-N-heterocyclic scaffolds via the controlled reactivity of Cu-allenylidene intermediates

  2021cites this paper
• Bidirectional Synthesis, Photophysical and Electrochemical Characterization of Polycyclic Quinones Using Benzocyclobutenes and Benzodicyclobutenes as Precursors

  2021cites this paper
• Dehydrative Allylation of 2-Alkylbenzophenones with Allylic Alcohols

  2020cites this paper
• Cleavage of Carbon-Carbon σ-Bonds of Four-Membered Rings.

  2020cites this paper
• Facile o-quinodimethane formation from benzocyclobutenes triggered by the Staudinger reaction at ambient temperature.

  2019cites this paper
• Synthesis and Applications

  2019cites this paper
• A low temperature crosslinking benzocyclobutene based polymer dielectric for organic thin film transistors on plastic substrates.

  2019cites this paper
• Synthesis of polymethacrylate‐bearing benzocyclobutene structure and extension to networked polymer based on thermal isomerization

  2019cites this paper
• Recent advances in the application of Diels-Alder reactions involving o-quinodimethanes, aza-o-quinone methides and o-quinone methides in natural product total synthesis.

  2018cites this paper
• Aryne-based strategy in the total synthesis of naturally occurring polycyclic compounds.

  2018cites this paper
• Formation of Alkenes by Diels–Alder Reactions

  2018cites this paper
• Enantioselective Michael Addition of Photogenerated o-Quinodimethanes to Enones Catalyzed by Chiral Amino Acid Esters.

  2017cites this paper
• Thermal Hetero-Diels-Alder Reaction of Benzocyclobutenones with Isatins To Form 2-Oxindole Spirolactones.

  2017cites this paper
• A Photocatalyzed Synthesis of Naphthalenes by Using Aniline as a Traceless Directing Group in [4 + 2] Annulation of Amino-benzocyclobutenes with Alkynes

  2017cites this paper
• Thermally Induced Cross-Linking and Degradation Reactions of Benzocyclobutene-Based Polymers

  2017cites this paper
• Expedient Diels–Alder cycloadditions with ortho-quinodimethanes in a high temperature/pressure flow reactor

  2017cites this paper
• Diels–Alder Cycloaddition

  2016cites this paper
• Synthesis and Applications

  2016cites this paper
• Intramolecular Cross-Linking Methodologies for the Synthesis of Polymer Nanoparticles.

  2016cites this paper
• Photochemical Approaches to Complex Chemotypes: Applications in Natural Product Synthesis

  2016cites this paper
• Ruthenium-Catalyzed Carbonylative Synthesis of Heterocycles

  2015cites this paper
• 2,2′-Bis-substituted Biphenyls by the Addition of Nucleophiles to Benzyne Followed by In Situ Oxidative Homocoupling

  2015cites this paper
• Polymeric amphiphilic nanoparticles via intramolecular chain collapse using 1-functionalized vinylbenzocyclobutenes

  2015cites this paper
• Rh(I)-catalyzed benzo/[7+1] cycloaddition of cyclopropyl-benzocyclobutenes and CO by merging thermal and metal-catalyzed C-C bond cleavages.

  2015cites this paper
• Light-driven carboxylation of o-alkylphenyl ketones with CO2.

  2015cites this paper
• Construction of tetralin skeletons based on rhodium-catalysed site-selective ring opening of benzocyclobutenols.

  2015cites this paper
• The First Bidirectional [4+2] Cycloadditions of Benzo[1,2:4,5]dicyclobutenes: Synthesis of Benzo[1,2‐f:4,5‐f′]diisoindole‐1,3,7,9‐tetraones

  2015cites this paper
• ortho-Quinodimethane from anthracene epidioxide: Scope of the Diels–Alder reaction and mild preparation of naphthalene derivatives

  2014cites this paper
• Cobalt-catalyzed formal [4+2] cycloaddition of α,α'-dichloro-ortho-xylenes with alkynes.

  2014cites this paper
• Arynes double bond insertion/nucleophilic addition with vinylogous amides and carbodiimides.

  2014cites this paper
• Cycloaddition reactions of benzyne with olefins

  2014cites this paper
• A Short Asymmetric Synthesis of Octahydroindole Derivatives by Application of Catalytic C(sp3)–H Amination Reaction

  2014cites this paper
• The green and convergent paired Diels–Alder electro-synthetic reaction of 1,4-hydroquinone with 1,2-bis(bromomethyl)benzene

  2014cites this paper
• Proline-catalyzed asymmetric Diels–Alder reactions of an o -quinodimethane

  2014cites this paper
• Benz[c]indeno[2,1-a]fluorene: a 2,3-naphthoquinodimethane incorporated into an indenofluorene frame

  2014cites this paper
• Stereoselective approach to potential scaffold of A-nor B-aromatic OSW-1 analogues via [4+2] cycloaddition of o-quinodimethane

  2014cites this paper
• Part I: A synthesis of jiadifenolide; Part II: Efforts toward a synthesis of pleurotin

  2014cites this paper
• Gold-catalyzed cascade cycloisomerization of 1,7-diyn-3,6-bis(propargyl carbonate)s: stereoselective synthesis of naphtho[b]cyclobutenes.

  2013cites this paper
• (R/S)-BINOL-α-Phosphoryloxy Enecarbamate-Mediated and (R/S)-Titanium(IV) BINOLates-Catalyzed Enantioselective Intramolecular Heck/Aza-Diels–Alder Cycloaddition (IHADA): An Expedient Methodology

  2013cites this paper
• Reaction of arynes with vinylogous amides: nucleophilic addition to the ortho-quinodimethide intermediate.

  2013cites this paper
• Rhodium-catalyzed ring opening of benzocyclobutenols with site-selectivity complementary to thermal ring opening.

  2012cites this paper
• Synthesis of Six-Membered Rings and Inhibitors of Protein Kinases

  2012cites this paper
• Total syntheses of chelidonine and norchelidonine via an enamide-benzyne-[2 + 2] cycloaddition cascade.

  2012cites this paper
• Synthesis of low-temperature benzocyclobutene cross-linker and utilization

  2012cites this paper
• The photo-dehydro-Diels-Alder (PDDA) reaction.

  2011cites this paper
• Light-induced hetero-Diels-Alder cycloaddition: a facile and selective photoclick reaction.

  2011cites this paper
• Patterned surface derivatization using Diels-Alder photoclick reaction.

  2011cites this paper
• First total syntheses of (±)-3-aza-11-selena and (±)-3-aza-11-tellura steroids

  2011cites this paper
• An ortho-Quinodimethane Route to Lasofoxifene and U23469

  2011cites this paper
• An approach to the synthesis of [2]benzopyrano[3,4‐c]pyrroles; alternative dopaminergic molecules

  2010cites this paper
• Facile access to boryltetralins and borylnaphthalenes via a cycloaddition using o-quinodimethanes.

  2010cites this paper
• Aryne, ortho-Quinone Methide, and ortho-Quinodimethane: Synthesis of Multisubstituted Arenes Using the Aromatic Reactive Intermediates

  2010cites this paper
• Facile synthesis of octahydrobenzo[h]isoquinolines: novel and highly potent D1 dopamine agonists.

  2010cites this paper
• A three-component reaction between benzynes, the enolate of acetaldehyde, and unsaturated esters and dihydroisoquinolines

  2010cites this paper
• Ring-opening polymerization by lithium catalysts: an overview.

  2010cites this paper
• Intramolecular Cyclization of Dienes and Polyenes

  2009cites this paper
• An isolable o-quinodimethane and its fixation of molecular oxygen to give an endoperoxide.

  2009cites this paper
• First Total Synthesis of 11-Tellura Steroids

  2009cites this paper
• Synthesis of Conjugated Dienes and Polyenes

  2009cites this paper
• Synthesis of 3,4-dihydroisoquinolines by a C(sp3)-H activation/electrocyclization strategy: total synthesis of coralydine.

  2009cites this paper
• 1,3‐Dihydrobenzo[c]thiophene 2,2‐Dioxide

  2009cites this paper
• Recent advances in azasteroids chemistry.

  2008cites this paper
• Sequential pericyclic reaction of ene-diallene: synthesis of (±)-estrone

  2007cites this paper
• Syntheses of Anthracyclines and Fredericamycin A via Strong Base-Induced CycloadditionReaction of Homophthalic Anhydrides

  2007cites this paper
• Synthetic organic chemistry based on small ring compounds.

  2007cites this paper
• The Total Synthesis of Aromatic Steroids 1972–1981

  2007cites this paper
• Palladium‐Catalyzed Synthesis of Functional Tetralins via Benzylic Activation

  2007cites this paper
• Recent advances in oxasteroids chemistry.

  2007cites this paper
• Combinatorial synthesis of linearly condensed polycyclic compounds, including anthracyclinones, through tandem Diels-Alder additions

  2007cites this paper
• Tricyclo[3.3.0.02,8]octan-3-one: Photochemisch hergestellte Bausteine zur enantiospezifischen Totalsynthese cyclopentanoider Naturstoffe†

  2006cites this paper
• Recent advances in thiasteroids chemistry.

  2006cites this paper
• Palladium-catalyzed distannylation of ortho-quinodimethanes.

  2006cites this paper
• A novel generation of indole-2,3-quinodimethanes.

  2006cites this paper
• Synthetic studies on polycyclic indole alkaloids

  2006cites this paper
• Spezifikation des sterischen Verlaufs von asymmetrischen Synthesen

  2006cites this paper
• An unusual hydrogen addition of indolo-2,3-quinodimethanes to dimethylindoles in the presence of 1,3-azoles

  2006cites this paper
• Synthesis of 5,8-dimethoxynaphtho[2,3-c]furan-4(9H)-one

  2006cites this paper
• Mild generation of o-quinodimethanes via fluoride induced 1,4-elimination of α-(o-trimethylsilylmethyl)benzylesters: stereoselective synthesis of 19-nor steroids and RU486 precursors

  2006cites this paper
• Sequential pericyclic reaction of ene-diallenes: an efficient approach to the steroid skeleton.

  2006cites this paper
• A general carbometalation, three component coupling strategy for the synthesis of α,β-unsaturated γ-sultines including thio-rofecoxib, a selective COX-2 inhibitor

  2005cites this paper
• Efficient synthesis of new 11-thiasteroids and their oxides and dioxides

  2005cites this paper
• Occurence of abundant diradicaloid moieties in the insoluble organic matter from the Orgueil and Murchison meteorites : a fingerprint of its extraterrestrial origin ?

  2004cites this paper
• Diels–Alder cycloadditions of functionalized (Z)-1-benzylidene-2-methylene cyclohexanes: the beneficial effect of high pressure

  2004cites this paper
• The change of aromaticity along a Diels-Alder reaction path.

  2003cites this paper
• The use of arynes in organic synthesis

  2003cites this paper
• First [2+2]-cycloaddition of a 3,4-didehydropyridine and a ketene dialkyl acetal

  2002cites this paper
• The Synthesis of Naphthosultine and Benzodisultines and Their Pyrolysis with Dienophiles: Studies on o‐Naphthoquinodimethane and Bis‐o‐Quinodimethane

  2002cites this paper
• α,α′‐Dibromo‐o‐xylene

  2001cites this paper
• Polymerizations and polymers of quinonoid monomers

  2001cites this paper
• Der Stand der Totalsynthese zu Beginn des 21. Jahrhunderts

  2000cites this paper
• Diels–Alder Reactions of 1-Azadienes

  2000cites this paper
• Generation of o-quinodimethanes via the electrocyclic reaction of (4Z)-1,2,4,6,7-octapentaenes derived from the organoborate complexes and their subsequent reactions

  1999cites this paper
• Synthesis of a poly(vinyl ether) containing a benzocyclobutene moiety and its reaction with dienophiles

  1999cites this paper
• Polymerization ofo-quinodimethanes. III. Polymerization ofo-quinodimethanes bearing electron-withdrawing groups formedin situby thermal ring-opening isomerization of corresponding benzocyclobutenes

  1999cites this paper