Solar Synthesis: Prospects in Visible Light Photocatalysis

No abstract is available for this paper.

• Publication year

  2014

• Venue

  Science

• Publication date

  2014-02-28

• Fields of study

  Medicine, Chemistry, Environmental Science

• Identifiers
  DOI 10.1126/science.1239176PMID 24578578PMCID PMC4547527
• External record

  Open on Semantic Scholar

• Source metadata

  Semantic Scholar, PubMed

• No claims are published for this paper.

• No concepts are published for this paper.

• Visible-light sensitization of vinyl azides by transition-metal photocatalysis.

  2014cited by this paper
• External regulation of controlled polymerizations.

  2013cited by this paper
• Oxygen switch in visible-light photoredox catalysis: radical additions and cyclizations and unexpected C-C-bond cleavage reactions.

  2013cited by this paper
• Visible Light Photocatalysis: The Development of Photocatalytic Radical Ion Cycloadditions.

  2013cited by this paper
• Proton-coupled electron transfer with photoexcited metal complexes.

  2013cited by this paper
• Anti-Markovnikov hydroamination of alkenes catalyzed by an organic photoredox system.

  2013cited by this paper
• Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis.

  2013cited by this paper
• Photoredox Functionalization of C—H Bonds Adjacent to a Nitrogen Atom

  2013cited by this paper
• Photoredox transformations with dimeric gold complexes.

  2013cited by this paper
• Brønsted acid cocatalysts in photocatalytic radical addition of α-amino C-H bonds across Michael acceptors.

  2013cited by this paper
• Visible light photoredox catalysis: generation and addition of N-aryltetrahydroisoquinoline-derived α-amino radicals to Michael acceptors.

  2012cited by this paper
• Oxidative Coupling of Enolates, Enol Silanes and Enamines: Methods and Natural Product Synthesis.

  2012cited by this paper
• Functionally diverse nucleophilic trapping of iminium intermediates generated utilizing visible light.

  2012cited by this paper
• Direct α-functionalization of saturated cyclic amines.

  2012cited by this paper
• Photoredox functionalization of C-H bonds adjacent to a nitrogen atom.

  2012cited by this paper
• Shining light on photoredox catalysis: theory and synthetic applications.

  2012cited by this paper
• Visible light-mediated atom transfer radical addition via oxidative and reductive quenching of photocatalysts.

  2012cited by this paper
• Visible light photocatalysis of [2+2] styrene cycloadditions by energy transfer.

  2012cited by this paper
• Engaging unactivated alkyl, alkenyl and aryl iodides in visible-light-mediated free radical reactions

  2012cited by this paper
• Practical method for the Cu-mediated trifluoromethylation of arylboronic acids with CF3 radicals derived from NaSO2CF3 and tert-butyl hydroperoxide (TBHP).

  2012cited by this paper
• Crossed Intermolecular [2+2] Cycloaddition of Styrenes by Visible Light Photocatalysis.

  2012cited by this paper
• Control of a living radical polymerization of methacrylates by light.

  2012cited by this paper
• [Cu(dap)2Cl] as an efficient visible-light-driven photoredox catalyst in carbon-carbon bond-forming reactions.

  2012cited by this paper
• Accessing the Synthetic Chemistry of Radical Ions

  2012cited by this paper
• Proton-coupled electron transfer.

  2012cited by this paper
• Direct catalytic anti-markovnikov hydroetherification of alkenols.

  2012cited by this paper
• Photoredox catalysis: a mild, operationally simple approach to the synthesis of α-trifluoromethyl carbonyl compounds.

  2011cited by this paper
• Total synthesis of (+)-gliocladin C enabled by visible-light photoredox catalysis.

  2011cited by this paper
• Discovery of an α-Amino C–H Arylation Reaction Using the Strategy of Accelerated Serendipity

  2011cited by this paper
• Visible-light-induced oxidation/[3+2] cycloaddition/oxidative aromatization sequence: a photocatalytic strategy to construct pyrrolo[2,1-a]isoquinolines.

  2011cited by this paper
• Room-temperature C-H arylation: merger of Pd-catalyzed C-H functionalization and visible-light photocatalysis.

  2011cited by this paper
• [3+2] cycloadditions of aryl cyclopropyl ketones by visible light photocatalysis.

  2011cited by this paper
• Radical cation Diels-Alder cycloadditions by visible light photocatalysis.

  2011cited by this paper
• Photochemical reactions as key steps in natural product synthesis.

  2011cited by this paper
• Visible light photocatalysis as a greener approach to photochemical synthesis.

  2010cited by this paper
• A Biomolecule-Compatible Visible Light-Induced Azide Reduction from a DNA-Encoded Reaction Discovery System

  2010cited by this paper
• Visible light-mediated intermolecular C-H functionalization of electron-rich heterocycles with malonates.

  2010cited by this paper
• Development of efficient photocatalytic systems for CO2 reduction using mononuclear and multinuclear metal complexes based on mechanistic studies

  2010cited by this paper
• Enantioselective α-benzylation of aldehydes via photoredox organocatalysis.

  2010cited by this paper
• Visible-light photoredox catalysis: aza-Henry reactions via C-H functionalization.

  2010cited by this paper
• Simultaneous production of p-tolualdehyde and hydrogen peroxide in photocatalytic oxygenation of p-xylene and reduction of oxygen with 9-mesityl-10-methylacridinium ion derivatives.

  2010influential reference
• Crossed intermolecular [2+2] cycloadditions of acyclic enones via visible light photocatalysis.

  2009cited by this paper
• Intramolecular Anodic Olefin Coupling Reactions: Using Radical Cation Intermediates to Trigger New Umpolung Reactions

  2009cited by this paper
• Eco-Friendly Synthesis of Fine Chemicals

  2009cited by this paper
• Chapter 2:The Contribution of Photochemistry to Green Chemistry

  2009cited by this paper
• Enantioselective alpha-trifluoromethylation of aldehydes via photoredox organocatalysis.

  2009cited by this paper
• Efficient visible light photocatalysis of [2+2] enone cycloadditions.

  2008cited by this paper
• Photochemical reactions as key steps in organic synthesis.

  2008cited by this paper
• Photochemical conversion of solar energy.

  2008cited by this paper
• Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes

  2008cited by this paper
• Asymmetric enamine catalysis.

  2007cited by this paper
• Photocatalysis for the formation of the C-C bond.

  2007cited by this paper
• Proton-coupled electron transfer.

  2007cited by this paper
• Direct sp3 C-H bond activation adjacent to nitrogen in heterocycles.

  2007cited by this paper
• Development and Applications of Electron‐Transfer‐Initiated Cyclization Reactions

  2007cited by this paper
• Enantioselective Organocatalysis Using SOMO Activation

  2007cited by this paper
• The application of cathodic reductions and anodic oxidations in the synthesis of complex molecules.

  2006cited by this paper
• Enantioselective organocatalytic alpha-fluorination of aldehydes.

  2005cited by this paper
• Enantioselective Organocatalytic α-Fluorination of Aldehydes

  2005cited by this paper
• Samarium(II)-iodide-mediated cyclizations in natural product synthesis.

  2004cited by this paper
• Electron-transfer state of 9-mesityl-10-methylacridinium ion with a much longer lifetime and higher energy than that of the natural photosynthetic reaction center.

  2004influential reference
• Photocatalytic oxygenation of anthracenes and olefins with dioxygen via selective radical coupling using 9-mesityl-10-methylacridinium ion as an effective electron-transfer photocatalyst.

  2004cited by this paper
• The combinatorial synthesis of bicyclic privileged structures or privileged substructures.

  2003cited by this paper
• Metal-mediated reductive hydrodehalogenation of organic halides.

  2002cited by this paper
• Stereoselective Intermolecular [2 + 2]-Photocycloaddition Reactions and Their Application in Synthesis

  1998cited by this paper
• Understanding Reactivity Patterns of Radical Cations

  1997cited by this paper
• Redox induced radical and radical ionic carbon-carbon bond forming reactions

  1995cited by this paper
• The Photochemical Synthesis of Fine Chemicals with Sunlight

  1994cited by this paper
• Photocycloadditions: control by energy and electron transfer

  1993cited by this paper
• Photochemistry of polypyridine and porphyrin complexes

  1993cited by this paper
• Mechanistic and Synthetic Aspects of Amine‐Enone Single Electron Transfer Photochemistry

  1992cited by this paper
• Photocatalytic reduction of phenacyl halides by 9,10-dihydro-10-methylacridine: control between the reductive and oxidative quenching pathways of tris(bipyridine)ruthenium complex utilizing an acid catalysis

  1990cited by this paper
• Cation radical cycloadditions and related sigmatropic reactions

  1989cited by this paper
• Ru(II) polypyridine complexes: photophysics, photochemistry, eletrochemistry, and chemiluminescence

  1988cited by this paper
• Photophysics, photochemistry and solar energy conversion with tris(bipyridyl)ruthenium(II) and its analogues

  1982cited by this paper
• Photosensitization in Organic Synthesis

  1981cited by this paper
• Photochemical conversion of solar energy

  1978cited by this paper
• Solar radiation measurement: Techniques and instrumentation

  1976cited by this paper
• THE PHOTOCHEMISTRY OF THE FUTURE.

  1912cited by this paper
• Enantioselective Organocatalysis Using SOMO Activation

  year unknowncited by this paper

• Performance of CuTiO3 Photocatalytic Oxidation for Treating Organic Peroxide Production Wastewater Under Visible Light

  2026cites this paper
• Photoinitiated Enantioselective Cycloisomerization/Addition Cascades of 2-Acyl Benzaldehydes with α,β-Unsaturated Carbonyl Compounds.

  2026cites this paper
• Poly(arylene-ethynylene)s in Synthetic Heterogeneous Visible Light Photocatalysis: Structure–Reactivity Principles and Opportunities in Flow

  2026cites this paper
• Heterogeneous Photocatalysis for Late-Stage Functionalization: A Sustainable Frontier for Complex Molecule Synthesis.

  2026cites this paper
• Electron Transfer Mediator-Enabled Modular Control of 1O2 and O2 •- Generation in Porphyrin Supramolecular Frameworks for Selective Photosynthesis.

  2026cites this paper
• Cobalt-Backboned Oligomer for Record Photocatalytic CO2 Conversion to Ethanol.

  2026cites this paper
• Throwing Light on -O–O- Bond: Organic Peroxides in Visible-Light Photocatalysis

  2026cites this paper
• First-principles design of S-scheme Janus SWSe/ZnO heterojunction for efficient photocatalytic hydrogen evolution

  2026cites this paper
• Fallen-leaf-sensitized biosolar oxygenation of hydrocarbons

  2026cites this paper
• Electron Donor-Acceptor Complex-Driven Minisci Reactions of N-Heteroaromatic and Inert C(sp3)-H without Brønsted Acids and External Oxidants.

  2026cites this paper
• Jahn-Teller distortion controls electron transfer in photoexcited Cu(i) donor-acceptor systems.

  2026cites this paper
• Vacancy-interface coupling in nanomaterials for photocatalytic energy and environmental applications

  2026cites this paper
• The Coordination Microenvironment Tailoring in 2D MOFs for Enhancing Photocatalytic Acetylene Semi-Hydrogenation.

  2026cites this paper
• Enhanced photocatalytic aerobic organic transformations via immobilization of Ir(III) units into covalent organic framework

  2026cites this paper
• Electron Donor–Acceptor Complexes Without Preinstalled Sacrificial Leaving Groups: Applications in Synthesis

  2026cites this paper
• Vitamin-based nanohybrids for photo-induced organic transformations

  2026cites this paper
• Photoinduced Dearomative Oxyimination of Indoles Using Oxime Esters as Bifunctional Radical Precursors.

  2026cites this paper
• Photonic Crystal Integrated Photomicroreactors: Enabling Efficient Solar-to-Chemical Conversion via Wavelength-Selective Photon Management.

  2026cites this paper
• Sustainable and Scalable Flow Photochemical Conversions Using a Labile Ligand-Assembled Iron Complex.

  2026cites this paper
• Mechanisms of photodecarboxylations for alkane synthesis: a theoretical study

  2026cites this paper
• The promise of porous organic cages: Bridging fundamental insights and real-world impact in energy and beyond

  2026cites this paper
• Tailoring the work function at Mott-Schottky junction enables efficient charge separation in Bi2WO6 photoanodes for enhanced photoelectrocatalytic water splitting

  2026cites this paper
• Sensitizing Ketone Triplets Using Low-Toxicity Blue Quantum Dots for Multifunctional Energy-Demanding Applications.

  2026cites this paper
• Photocatalytic four-component reaction to access covalent organic frameworks for photocatalysis.

  2026cites this paper
• Independent Optimization of the Redox Reaction Sites for Simultaneous Production of Value-Added Organic Compounds and Hydrogen with High Activity and Selectivity

  2026cites this paper
• Recent Advances in Visible Light‐Promoted Ring Opening of Aryl Cyclopropanes

  2025cites this paper
• Irradiation of Bifunctional Masked Ketone Pro-Aromatics Unveils Autoinductive Autocatalysis via Electron Donor–Acceptor (EDA) Complexes

  2025cites this paper
• Intramolecular charge transfer state to suppress back electron transfer for singlet photoredox catalysis.

  2025cites this paper
• Iron-catalysed radical difunctionalization of alkenes

  2025cites this paper
• Two-step coupled photoelectrochemical chlorination and oxygenation of C(sp3)–H bonds mediated by chlorine radicals over a modified BiVO4 photoanode

  2025cites this paper
• Enantioselective Synthesis of Cyclobutane-fused Heterocycles via Lewis Acid-Catalyzed Dearomative [2+2] Photocycloaddition of Indoles, Benzofurans, and Benzothiophenes with Alkenes.

  2025cites this paper
• EDA photochemistry using continuous flow

  2025cites this paper
• Semiconductor Cluster with High Reduction Potential and Efficient Charge Transfer Enables Visible-Light-Driven Activation of Inert Organic Substrates.

  2025cites this paper
• Efficient photocatalytic synthesis of benzylhydrazine.

  2025cites this paper
• Iron‐Based Catalysts for the Removal of Microplastics

  2025cites this paper
• Interfacial polymer: plastic's solar hydrogen makeover.

  2025cites this paper
• Monofluoromethyl Radical Mediated Halogen-Atom Transfer

  2025cites this paper
• Breaking Kasha’s Rule to Enable Higher Reactivity in Photoredox Catalysis

  2025cites this paper
• Palladium(0) nanoparticles supported on Benzene Doped Graphitic Carbon Nitride: An efficient catalyst/photocatalyst for Suzuki-Miyaura C C coupling reaction

  2025cites this paper
• Photo-triggered tandem cyclization of arylethynyl quinazolin-4(3H)-one for difluoroalkylated quinolino[2,1-b]quinazolines.

  2025cites this paper
• Photocatalyst Design with an Electrical-Polarization-Ability Descriptor for Exclusive C-H Bond Activation in Methanol.

  2025cites this paper
• Cyclometallated phosphonium ylide-based iridium(III) photocatalysts.

  2025cites this paper
• Non‐Innocent Ligands as Mediators for Visible‐Light‐Initiated Element–Carbon Bond Homolysis in Main Group Chemistry

  2025cites this paper
• Enantioselective palladium photoredox catalysis.

  2025cites this paper
• Recent Advances in Photochemical Reactions Enabled by Triarylamine

  2025cites this paper
• Photoinduced EDA Complexes Enabled C(sp2)-OMe Bond Cleavage and Cyanation of Electron-Rich Arenes.

  2025cites this paper
• Enantioconvergent Radical-Radical Cross-Coupling via Magnesium-Mediated Charge-Transfer Photocatalysis.

  2025cites this paper
• Recent Progress on Coupling of Organic Oxidation and Hydrogen Production over CdS-Based Photocatalyst.

  2025cites this paper
• Accelerated Discovery of Energy Transfer-Catalyzed Dearomative Cycloadditions through a Data-Driven Three-Layer Screening Strategy.

  2025cites this paper
• Photoinduced Intramolecular [2 + 2] Cycloaddition Investigated with Transient Infrared Spectroscopy.

  2025cites this paper
• Chemo‐Biological Cascade Catalysis Assisted Semi‐Artificial Photosynthetic Systems for Improving the Synthesis of High‐Valued Chemicals

  2025cites this paper
• Two-dimensional porphyrin-based covalent organic frameworks for visible-light-driven oxidative coupling of benzylamines.

  2025cites this paper
• Convergent Synthesis of Functionalized Indolines from Alkyl Aryl Tertiary Amines and Diazoesters via Visible Light-Driven [4 + 1]-Annulation Approach.

  2025cites this paper
• Host-Guest Charge-Transfer Mediated Photoredox Catalysis Inside Water-Soluble Nanocages.

  2025cites this paper
• Se-Aryl-N-phenylphenoselenazinium salts: aryl radical precursors incorporating a photosensitizer unit.

  2025cites this paper
• Breaking activity-transport limits in photocatalysis: 3D cyanide-rich hydrogel membranes via radical polymerization for solar-powered wastewater purification

  2025cites this paper
• Design and synthesis of nickel-containing covalent organic frameworks for visible light induced directed ortho-trifluoromethylation of aromatic amides

  2025cites this paper
• Enhancing photoredox catalysis by suppressing back electron transfer with the aid of a spin catalyst

  2025cites this paper
• Theoretical Study on an Excited-State Copper-Catalyzed [4 + 1] Cyclization Reaction for the Construction of α,β-Unsaturated-γ-Lactams via an Oxidative Radical-Polar Crossover Mechanism.

  2025cites this paper
• Visible Light-Assisted Photocatalyst-Free Synthesis, Characterization, Theoretical, and Nonlinear Optical Performance of a New 1,3,4-Oxadiazole Derivative

  2025cites this paper
• A new synthetic method of [Ru(2,2′:6′,2″-terpyridine)(2,2′-bipyridine)Cl]+ complexes using cis-[Ru(2,2′:6′,2″-terpyridine)(NCCH3)2Cl]+ as an intermediate and comparison to a method using [Ru(benzene)(2,2′-bipyridine)Cl]+ intermediates

  2025cites this paper
• Operando interfacial kinetic study of H2O2 photoproduction over carbon dots stabilized gold nanoclusters

  2025cites this paper
• Efficient super-reducing organic photoredox catalysis with proton-coupled electron transfer mitigated back electron transfer.

  2025cites this paper
• Construction of supramolecular metal-halogen bonded organic frameworks for efficient solar energy conversion

  2025cites this paper
• Photocatalytic Approach Toward the Synthesis of Amides via S-C Cleavage: A Mild Approach.

  2025cites this paper
• Bichromophoric Ruthenium Complexes for Photocatalyzed Late-Stage Synthesis of Trifluoromethylated Indolizines

  2025cites this paper
• Assembling of N-phenylphenoxazine based metal-organic macrocycle for efficient photocatalytic reduction of aryl halides

  2025cites this paper
• Engineered Proteins and Chemical Tools to Probe the Cell Surface Proteome

  2025cites this paper
• Photocatalytic Iminothiolation of Alkenes via Monothiocarbonate Oxime Esters

  2025cites this paper
• Light-enabled intramolecular [2 + 2] cycloaddition via photoactivation of simple alkenylboronic esters

  2025cites this paper
• Homoisoflavones: Structural diversity, pharmacological activities, and photocatalytic synthesis strategies - A comprehensive review.

  2025cites this paper
• Charge-Transport Divergence in Ultrastable Heterometal-Oxo Clusters Exerting Significant Effect on Photoreactivity.

  2025cites this paper
• The formation reaction of a carbon-carbon bond promoted by Eosin-Y under visible light.

  2025cites this paper
• Visible light activated Zinc-Doped MIL-68(In)-Derived Indium oxide nanotubes for rapid and Ultra-Sensitive Room-Temperature NO2 detection

  2025cites this paper
• Host-Guest Approach to Enhancing Photocatalysis via Photoinduced Energy and Electron Transfer from a Photoactive Triphenylamine-Based Metal-Organic Cage to Bound Guests.

  2025cites this paper
• 3-Center-3-Electron σ-Adduct Enables Silyl Radical Transfer below the Minimum Barrier for Silyl Radical Formation

  2025cites this paper
• Diastereoselective 1,3-nitrooxygenation of bicyclo[1.1.0]butanes

  2025cites this paper
• Relay Photocatalyzed Reductive Cleavage of Csp2-I To Establish Radical Cyclization/Coupling between O-Tethered Iodoarenes with Cyanoarenes.

  2025cites this paper
• Tailoring Ultrashort Inter‐Fullerene Spacing in a Continuous Fullerene Stacking Array to Enhance Electron Transport for Boosting Solar‐Driven Hydrogen Production

  2025cites this paper
• Donor-Acceptor-π-Acceptor-Donor-Type Photosensitive Covalent Organic Framework for Effective Photocatalytic Aerobic Oxidation.

  2025cites this paper
• High entropy oxide (Er2Tm2Yb2Lu2Ho2O15) efficiently and stably degrades Congo red under visible light

  2025cites this paper
• Recent progress in the design and application of machine learning for the hydrogen evolution reaction in electrocatalysis and photocatalysis

  2025cites this paper
• Two is superior to one: Bi-metallic low-nuclearity catalysts for advanced catalytic applications

  2025cites this paper
• Electronically Mismatched α-Addition of Electron-Deficient Alkenes via Photoinduced Polarity Transduction.

  2025cites this paper
• Natural Sunlight-Driven Activation of Inert Aryl Halides Using Plasmonic Cu@CdS with Polysulfide Active Sites.

  2025cites this paper
• Red‐Light‐Mediated Generation of Radicals: Applications in Organic Synthesis, Small‐Molecule Activation, Polymerization, and Bio‐Related Fields

  2025cites this paper
• Photocatalytic Dual-Defluorination Thiolation of Trifluoromethyl Hydrazones.

  2025cites this paper
• Rational Design and Reaction Mechanism Study of the Photochemical Rearrangement of Fulvene Derivatives.

  2025cites this paper
• Photoinduced Electron Donor–Acceptor Complex‐Enabled Transformations Involving Boron‐Containing Compounds

  2025cites this paper
• Donor-acceptor semiconducting polymers as superior photocatalysts in the homogeneous phase and recycled via an antisolvent precipitation strategy.

  2025cites this paper
• Enantioselective Access to Chiral γ-Ketoamides via Photoredox Catalyzed Carbamoyl Radical Addition/Asymmetric Protonation

  2025cites this paper
• Propelling Chan‐Lam Cross‐Coupling Through Photocatalysis and Electrocatalysis: An Update

  2025cites this paper
• Polymeric stabilization at the gas–liquid interface for durable solar hydrogen production from plastic waste

  2025cites this paper
• Photodimerization of norbornenes and cyclohexenes catalyzed by Cu(I) complexes: mechanistic similarities and differences.

  2025cites this paper
• Light-Mediated Photoredox/Cobalt Dual Catalysis for Multisubstituted Enal Synthesis from Alkyne Feedstock

  2025cites this paper
• An aryl radical reservoir based on the activation of organoboronic acids by polytelluroxane

  2025cites this paper
• The Application of N-Aryl Glycines and Their Analogues in Visible-Light-Promoted Photoredox Catalysis.

  2025cites this paper
• Nickel-Based Photocatalyst: From Structure to Application.

  2025cites this paper
• Bromo-Substituted Phenylbenzothiazole Cyclometalating Ligands for the Development of Reverse Saturable Absorption Materials

  2025cites this paper
• Photoredox Autocatalysis: Towards a Library of Generally Applicable Reductive Photocatalysts.

  2025cites this paper